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Isopropyl 2,4-dichlorophenoxyacetate

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Isopropyl 2,4-dichlorophenoxyacetate manufacturers

Isopropyl 2,4-dichlorophenoxyacetate Basic information
Product Name:Isopropyl 2,4-dichlorophenoxyacetate
Synonyms:amchemweedkiller650[qr];barber’sweedkiller(esterformulation)[qr];bridgeportspotweedkiller[qr];chemicalinsecticide’sisopropylesterof2,4-dliquidconcentrate[qr];croprider3.34d[qr];croprider3-34d-2[qr];Esteron 44;esteron44
CAS:94-11-1
MF:C11H12Cl2O3
MW:263.12
EINECS:202-305-6
Product Categories:Alpha sort;D;DAlphabetic;DIO - DIZEnvironmental Standards;Herbicides;MetabolitesPesticides&Metabolites;Pesticides&Metabolites;Phenoxy structure
Mol File:94-11-1.mol
Isopropyl 2,4-dichlorophenoxyacetate Structure
Isopropyl 2,4-dichlorophenoxyacetate Chemical Properties
Melting point 5°C
Boiling point 371.18°C (rough estimate)
density 1.2600
refractive index 1.5209 (estimate)
storage temp. 0-6°C
Water Solubility 27.36mg/L(temperature not stated)
Henry's Law Constant4.6×100 mol/(m3Pa) at 25℃, Duchowicz et al. (2020)
NIST Chemistry ReferenceIsopropyl (2,4-dichlorophenoxy)acetate(94-11-1)
EPA Substance Registry System2,4-D isopropyl ester (94-11-1)
Safety Information
Hazard Codes Xn,N
Risk Statements 22-41-50/53-43
Safety Statements 26-39-61-60-46-36/37-29
RIDADR 3348
RTECS AG8750000
HazardClass 6.1(b)
PackingGroup III
Hazardous Substances Data94-11-1(Hazardous Substances Data)
MSDS Information
Isopropyl 2,4-dichlorophenoxyacetate Usage And Synthesis
Chemical Properties2,4-Dichlorophenoxyacetic acid is a white to yellow crystalline powder with a slight phenolic odor.
Production MethodsCommercial production of 2,4-D-isopropyl would have followed the same industrial pathway used for other ester derivatives of 2,4-D, although specific data for this variant are limited. Production begins with large scale synthesis of 2,4-D acid, which is then reacted with isopropanol under controlled temperature and solvent conditions to form the compound.
Mechanism of actionSelective, systemic, absorbed through roots and increases biosynthesis and production of ethylene causing uncontrolled cell division and so damages vascular tissue. Synthetic auxin.
Potential Exposure2,4-Dichlorophenoxyacetic acid, was introduced as a plant growth-regulator in 1942. It is registered in the United States as a herbicide for control of broadleaf plants and as a plant growth-regulator. Thus, workers engaged in manufacture, formulation or application are affected, as may be citizens in areas of application. The Vietnam war era defoliant, Agent Orange, was a mixture of 2,4-D and 2,4,5-T.
ShippingUN3345 Phenoxyacetic acid derivative pesticide, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. A DOT regulated marine pollutant.
IncompatibilitiesA weak acid, incompatible with bases. Decomposes in sunlight or heat, forming hydrogen chloride and phosgene. Contact with strong oxidizers may cause fire and explosions.
Waste DisposalIncineration of phenoxys is effective in 1 second @ 982 C, using a straight combustion process or @ 482℃ using catalytic combustion. Over 99% decomposition was reported when small amounts of 2,4-D were burned in a polyethylene bag. See “References” for additional detail. In accordance with 40CFR165, follow (31); recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by follow- ing (100) Package (2) label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Consult with environ- mental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regu- lations governing storage, transportation, treatment, and waste disposal.
Pesticide TypeHerbicide
Isopropyl 2,4-dichlorophenoxyacetate Preparation Products And Raw materials
Preparation Products2-(2,4-Dichlorophenoxy)ethanol
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