(S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine

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(S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine manufacturers

(S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine Basic information
Product Name:(S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine
Synonyms:(2S)-1-[(1S)-1-(Dimethylamino)ethyl]-1',2-bis(diphenylphosphino)ferrocene;(S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine,95%;(+)-(S)-N,N-Dimethyl-1-[(R)-1;(+)-(S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine 95%;(+)-(S)-N,N-DIMETHYL-1-[(R)-1',2-BIS(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE;(+)-(S)-N,N-dimethyl-1-((R)-1',2-bis(di-phenylpho;(S,R)-1-(1-dimethylaminoethyl)-1,2-*bis(diphenyl;(S,R)-1-(1-DIMETHYLAMINOETHYL)-1',2-BIS( DIPHENYLPH
CAS:55650-59-4
MF:C38H37FeNP210*
MW:625.5
EINECS:
Product Categories:Chiral Phosphine;Asymmetric Synthesis;Classes of Metal Compounds;Fe (Iron) Compounds;Ferrocenes;Metallocenes;Phosphine Ligands;Synthetic Organic Chemistry;Transition Metal Compounds;Asymmetric Synthesis;Chiral Catalysts, Ligands, and Reagents;Other Chiral Ligands
Mol File:55650-59-4.mol
(S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine Structure
(S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine Chemical Properties
Melting point 138-142 °C(lit.)
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
form solid
color Light yellow to Brown
Optical Rotation[α]20/D +350°, c = 0.5 in chloroform
InChIKeyVUJPTJYMSBMZOZ-RMRYJAPISA-N
SMILES[Fe].[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.C[C@@H]([C]4[CH][CH][CH][C]4P(c5ccccc5)c6ccccc6)N(C)C
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-36/37/38
Safety Statements 26-36
WGK Germany 3
HS Code 29319090
Storage Class11 - Combustible Solids
Hazard ClassificationsAcute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
(S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine Usage And Synthesis
UsesLigand used in the asymmetric hydrogenation of (Z)-α-amido-cinnamic acids
(S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine Preparation Products And Raw materials
Tag:(S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine(55650-59-4) Related Product Information
1.1'-Binaphthyl-2.2'-diphemyl phosphine (alphaS,alphaS)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(R,R)-,2'-bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]ferrocene (alphaS,alphaS)-1,1'-Bis-[alpha-(dimethylamino)benzyl]-(R,R)-2,2'-bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]ferrocene (alphaS,alphaS)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(R,R)-2,2'-bis[bis(2-methylphenyl)phosphino]ferrocene (S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine (R)-(S)-BPPFA (-)-(R)-N,N-DIMETHYL-1-[(R)-1',2-BIS(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE (ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE (ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS(DIPHENYLPHOSPHINO)FERROCENE