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(alphaS,alphaS)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(R,R)-2,2'-bis[di(3,5-xylyl)phosphino]ferrocene

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(alphaS,alphaS)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(R,R)-2,2'-bis[di(3,5-xylyl)phosphino]ferrocene Basic information
Reactions
Product Name:(alphaS,alphaS)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(R,R)-2,2'-bis[di(3,5-xylyl)phosphino]ferrocene
Synonyms:(S,S)-1,1'-BIS[(S)-ALPHA-(DIMETHYLAMINO)-PHENYLMETHYL]-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE;(R,R)-(+)-2,2'-BIS[(S)-(N,N-DIMETHYLAMINO)(PHENYL)METHYL]-1,1'-BIS(DI(3,5-DIMETHYLPHENYL)PHOSPHINO)FERROCENE;MANDYPHOS SL-M009-2;(aS,aS)-1,1#-Bis[-(dimethylamino)benzyl]-(R,R)-2,2#-bis[di(3,5-xylyl)phos;(R,R)-(+)-2,2'-Bis[(S)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(di(3,5-dimethylphenyl)phosphino)ferrocene,min.97%;(s,s)-1,1'-bis[(s)-α-(dimethylamino)-phenylmethyl]-2,2'-bis[di(3,5-xylyl)phosphino]ferrocene (acc to cas);(αs,αs)-1,1'-bis[α-(dimethylamino)benzyl]-(r,r)-2,2'-bis[di(3,5-xylyl)phosphino]ferrocene;(RP,RμP)-1,1μ-Bis[(S)-α-(dimethylamino)benzyl]-2,2μ-bis[di(3,5-xylyl)phosphino]ferrocene
CAS:847997-73-3
MF:C60H64FeN2P2
MW:932.97
EINECS:
Product Categories:Chiral Phosphine;Ferrocene Series;Mandyphos Series
Mol File:847997-73-3.mol
(alphaS,alphaS)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(R,R)-2,2'-bis[di(3,5-xylyl)phosphino]ferrocene Structure
(alphaS,alphaS)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(R,R)-2,2'-bis[di(3,5-xylyl)phosphino]ferrocene Chemical Properties
alpha +164°
storage temp. 2-8°C, protect from light, stored under nitrogen
form Powder
color orange
Stability:store cold
Safety Information
WGK Germany 3
HS Code 29319090
MSDS Information
(alphaS,alphaS)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(R,R)-2,2'-bis[di(3,5-xylyl)phosphino]ferrocene Usage And Synthesis
Reactions
  1. Ligand for Rh-catalyzed asymmetric hydrogenation of α-acetamidoacrylates.
  2. Ligand for Rh-catalyzed hydrogenation of α- and β-enamides, acrylic acid derivatives, itaconates, β-ketoesters and 1,3-diketones.
  3. Ligand for Rh-catalyzed asymmetric hydrogenation of furyl-substituted (Z)-dehydroamino acid derivatives.
  4. Ligand for Ir-catalyzed asymmetric transfer hydrogenation of ketones.
  5. Ligand for Cu-catalyzed enantioselective hydroboration of α- and β-unsaturated esters and nitriles. 
Reactions of 847997-73-3
Chemical PropertiesOrange powder
General Descriptionsold in collaboration with Solvias AG
(alphaS,alphaS)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(R,R)-2,2'-bis[di(3,5-xylyl)phosphino]ferrocene Preparation Products And Raw materials
Tag:(alphaS,alphaS)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(R,R)-2,2'-bis[di(3,5-xylyl)phosphino]ferrocene(847997-73-3) Related Product Information
(alphaS,alphaS)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(R,R)-2,2'-bis[di(3,5-xylyl)phosphino]ferrocene (S)-N,N-Dimethyl-1-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine (+/-)-N,N-Dimethyl-1-ferrocenylethylamine 1,1'-Dimethylferrocene (alphaS,alphaS)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(R,R)-,2'-bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]ferrocene (alphaS,alphaS)-1,1'-Bis-[alpha-(dimethylamino)benzyl]-(R,R)-2,2'-bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]ferrocene (S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine (S)-(-)-N,N-Dimethyl-1-ferrocenylethylamine 1,1'-Diethylferrocene Ferrocene N,N-Dimethylaminomethylferrocene 1,1'-Bis(diphenylphosphino)ferrocene