(R)-(S)-BPPFA

(R)-(S)-BPPFA Suppliers list
Company Name: J & K SCIENTIFIC LTD.  
Tel: 18210857532 18210857532
Email: jkinfo@jkchemical.com
Company Name: Meryer (Shanghai) Chemical Technology Co., Ltd.  
Tel: 4006356688 18621169109
Email: market03@meryer.com
Company Name: TCI (Shanghai) Development Co., Ltd.  
Tel: 021-67121386
Email: Sales-CN@TCIchemicals.com
Company Name: Energy Chemical  
Tel: 400-0056266
Email: sales8178@energy-chemical.com
Company Name: Shanghai Longsheng chemical Co.,Ltd.  
Tel: 58099637 13585536065
Email: sales@shlschem.com

(R)-(S)-BPPFA manufacturers

  • (R)-(S)-BPPFA
  • (R)-(S)-BPPFA pictures
  • $1.00
  • 2020-01-09
  • CAS:74311-56-1
  • Min. Order: 1KG
  • Purity: 99%
  • Supply Ability: 100KG
(R)-(S)-BPPFA Basic information
Product Name:(R)-(S)-BPPFA
Synonyms:(R)-(S)-BPPFA;(-)-(R)-N,N-DIMETHYL-1-[(S)-1',2-BIS(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE;(-)-(R)-N,N-dimethyl-1-((S)-1',2-bis(di-phenylpho;(-)-(R)-N,N-DIMETHYL-1-((S)-1',2-BIS(DI- PHENYLPHOSPHINO)FERROCENYL)ET-AMIN,95%;(R)-N,N-Dimethyl-1-((S)-1',2-bis(diphenylphosphino;[r,r]-1-[1-dimethylaminoethyl]-1',2-bis[diphenylphosphino]ferrocene;N,N-dimethyl-1-[1,2-bis(diphenylphosphino)ferrocenyl]ethyl;(2S)-1-[(1R)-1-(Dimethylamino)ethyl]-1',2-bis(diphenylphosphino)ferrocene
CAS:74311-56-1
MF:C38H37FeNP210*
MW:625.5
EINECS:
Product Categories:Chiral Phosphine;Asymmetric Synthesis;Classes of Metal Compounds;Fe (Iron) Compounds;Ferrocenes;Metallocenes;Phosphine Ligands;Synthetic Organic Chemistry;Transition Metal Compounds
Mol File:74311-56-1.mol
(R)-(S)-BPPFA Structure
(R)-(S)-BPPFA Chemical Properties
Melting point 143-144 °C(lit.)
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
form solid
color Light yellow to Brown
Optical Rotation[α]20/D 350°, c = 0.5 in chloroform
InChIKeyVUJPTJYMSBMZOZ-ZEECNFPPSA-N
SMILES[Fe].[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.C[C@H]([C]4[CH][CH][CH][C]4P(c5ccccc5)c6ccccc6)N(C)C
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-36/37/38
Safety Statements 26-36
WGK Germany 3
HS Code 2931.90.6000
Storage Class11 - Combustible Solids
Hazard ClassificationsAcute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
(R)-(S)-BPPFA Usage And Synthesis
UsesLigand used in the enantioselective silylation of allylic chlorides.
Uses(-)-(R)-(S)-BPPFA is an electron-rich bulky ligand used in amination reactions of aryl halides and tosylates. Homogeneous catalyst.
(R)-(S)-BPPFA Preparation Products And Raw materials
Tag:(R)-(S)-BPPFA(74311-56-1) Related Product Information
Cinchonidine (S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine (alphaR,alphaR)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(S,S)-2,2'-bis(diphenylphosphino)ferrocene (alphaR,alphaR)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(S,S)-,2'-bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]ferrocene (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE (R)-(S)-BPPFA (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(2-METHYLPHENYL)PHOSPHINO]FERROCENE