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BORANE-DIPHENYLPHOSPHINE COMPLEX

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Products Intro: Product Name:BORANE-DIPHENYLPHOSPHINE COMPLEX
CAS:41593-58-2
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Products Intro: Product Name:BORANE-DIPHENYLPHOSPHINE COMPLEX
CAS:41593-58-2
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CAS:41593-58-2
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Products Intro: Product Name:Diphenylphosphine borane complex
CAS:41593-58-2
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BORANE-DIPHENYLPHOSPHINE COMPLEX manufacturers

BORANE-DIPHENYLPHOSPHINE COMPLEX Basic information
Product Name:BORANE-DIPHENYLPHOSPHINE COMPLEX
Synonyms:PHENYLPHOSPHINE BORANE COMPLEX;BORANE-DIPHENYLPHOSPHINE COMPLEX;DIPHENYLPHOSPHINE-BORANE COMPLEX;Borane diphenylphosphine;(Diphenylphosphine)borane;(Diphenylphosphine)trihydroboron;(T-4)-(Diphenylphosphine)trihydroboron;Borane-diphenylphosphine complex,94%
CAS:41593-58-2
MF:C12H14BP
MW:200.02
EINECS:
Product Categories:BoranesCatalysis and Inorganic Chemistry;Phosphorus Compounds;Phosphorus Precursors;Reduction;Synthetic Reagents
Mol File:41593-58-2.mol
BORANE-DIPHENYLPHOSPHINE COMPLEX Structure
BORANE-DIPHENYLPHOSPHINE COMPLEX Chemical Properties
Melting point 47-50 °C(lit.)
Boiling point 148-150 °C10 mm Hg(lit.)
storage temp. water-free area
form Solid
color White to off-white
Sensitive Moisture Sensitive
InChI1S/C12H11P.BH3/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10,13H;1H3
InChIKeyXUFGOLYVDOBYLK-UHFFFAOYSA-N
SMILESB.[H]P(c1ccccc1)c2ccccc2
Safety Information
Hazard Codes F
Risk Statements 15
Safety Statements 43
RIDADR UN 2813 4.3/PG 2
WGK Germany 3
HazardClass 4.3
HS Code 29310099
Storage Class4.3 - Hazardous materials which set free flammable gases upon contact with water
Hazard ClassificationsWater-react 2
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
BORANE-DIPHENYLPHOSPHINE COMPLEX Usage And Synthesis
Chemical Propertieswhite to off-white powder or crystals
UsesReactant for:
  • Nucleophilic addition reactions (anion)
  • Catalytic dehydrogenation in the presence of ruthenium bidentate phosphine compelxes
  • Deprotonation reactions
  • Catalytic coupling with alkynyl bromides
  • Catalyst-free Staudinger ligation for indirect 18F-radiolabeling
  • Preparation of chiral phosphine-phosphite bidentate ligands with biphenyl backbone
  • Reactions with frustrated lewis pair combinations of group 14 triflates and sterically hindered nitrogen bases
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Reductions
reagent type: reductant
BORANE-DIPHENYLPHOSPHINE COMPLEX Preparation Products And Raw materials
Tag:BORANE-DIPHENYLPHOSPHINE COMPLEX(41593-58-2) Related Product Information
TRIPHENYLBORANE-TRIPHENYLPHOSPHINE COMPLEX Tetraphenylphosphonium tetrafluoroborate BORANE-TRIPHENYLPHOSPHINE COMPLEX TETRAPHENYLPHOSPHONIUM TETRAPHENYLBORATE (R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE 1-CARBETHOXYCYCLOPROPYLTRIPHENYLPHOSPHONIUM TETRAFLUOROBORATE Bis-(triphenylphosphino)-cuprous borohydride BENZYLTRIPHENYLPHOSPHONIUM TETRAFLUOROBORATE BORANE-DIPHENYLPHOSPHINE COMPLEX (BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE BIS(TRIPHENYLPHOSPHINE)IMINIUM BOROHYDRIDE CHLORO(HYDROTRIS(PYRAZOL-1-YL)BORATO)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) ETHANOL ADDUCT [1,4-BIS(DIPHENYLPHOSPHINO)BUTANE](1,5-CYCLOOCTADIENE)RHODIUM(I) TETRA-FLUOROBORATE 4-CHLOROBENZYLTRIPHENYLPHOSPHONIUM TETRAFLUOROBORATE, 98 BENZYLTRIPHENYLPHOSPHONIUM BOROHYDRIDE 1,2-BIS(DIPHENYLPHOSPHINO)ETHANE NORBORNADIENE RHODIUM TETRAFLUOROBORATE 1,3-Benzodithiol-2-yltriphenyl phosphonium tetrafluoroborate AURORA KA-510

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