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| | TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Basic information |
| | TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Chemical Properties |
| Melting point | 105.8-106.4 °C | | Boiling point | 35.00°C | | density | 1.04 | | Fp | -40°C | | storage temp. | Flammables + water-Freezer (-20°C)e area | | solubility | Sol ethereal solvents; reacts with protic solvents. | | form | Low Melting Solid | | Specific Gravity | 0.912 | | color | Clear colorless to yellow to greenish | | Sensitive | Air & Moisture Sensitive | | Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents | | BRN | 3587255 | | InChI | 1S/C4H11Si.ClH.Mg/c1-5(2,3)4;;/h1H2,2-4H3;1H;/q;;+1/p-1 | | InChIKey | NAQATMJWCJCHOZ-UHFFFAOYSA-M | | SMILES | C[Si](C)(C)C[Mg]Cl | | CAS DataBase Reference | 13170-43-9(CAS DataBase Reference) |
| Hazard Codes | F+,C,F | | Risk Statements | 12-14-22-34-66-67-19-11 | | Safety Statements | 16-26-36/37/39-43-45 | | RIDADR | UN 3399 4.3/PG 1 | | WGK Germany | 1 | | F | 10 | | TSCA | No | | HazardClass | 8 | | PackingGroup | II | | HS Code | 29319090 | | Storage Class | 4.3 - Hazardous materials which set free flammable gases upon contact with water | | Hazard Classifications | Acute Tox. 4 Oral
Eye Dam. 1
Flam. Liq. 2
Skin Corr. 1B
STOT SE 3 |
| | TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Usage And Synthesis |
| Chemical Properties | Grey liquid | | Uses | Trimethylsilylmethylmagnesium
Chloride is used in the methylenation of carbonyl compounds; provides a variety of
methods to prepare allylsilanes.It participates in the reactions of Peterson Alkenation, Reaction with Carboxylic Acid Derivatives, Reaction with Alkyl Halides, Reaction with Sulfur Compounds, Reaction with Other Electrophiles, Cross-coupling Reactions, Carbometalation, and as a Generator of Alkyl Radicals from Alkyl Halides in
the Presence of Cobalt Catalysts etc. | | Uses | Reagent used in a variety of nickel catalyzed reactions including alkenation of dithioacetals, cross-coupling with aryl triflates and carbamates, and cross-coupling with vinyl selenides. | | Preparation | From (chloromethyl)trimethylsilane and
magnesium in an ethereal solvent. | | reaction suitability | reaction type: Grignard Reaction |
| | TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Preparation Products And Raw materials |
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