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2-Amino-5-ethylpyrazine

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Company Name: Pure Chemistry Scientific Inc.  
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2-Amino-5-ethylpyrazine manufacturers

2-Amino-5-ethylpyrazine Basic information
Product Name:2-Amino-5-ethylpyrazine
Synonyms:5-Ethyl-pyrazin-2-ylamine;5-ethylpyrazin-2-aMine;2-Pyrazinamine, 5-ethyl-;2-Amino-5-ethylpyrazine
CAS:13535-07-4
MF:C6H9N3
MW:123.16
EINECS:
Product Categories:
Mol File:13535-07-4.mol
2-Amino-5-ethylpyrazine Structure
2-Amino-5-ethylpyrazine Chemical Properties
Boiling point 250.2±35.0 °C(Predicted)
density 1.109±0.06 g/cm3(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
pka3.50±0.10(Predicted)
Safety Information
HS Code 2933998090
MSDS Information
2-Amino-5-ethylpyrazine Usage And Synthesis
Synthesis
5-ethynylpyrazin-2-aMine

457099-42-2

2-AMINO-5-ETHYLPYRAZINE

13535-07-4

Step 1: Hydrogenation reaction. 5-Ethynyl-2-aminopyrazine (18 mg, 0.151 mmol) was dissolved in ethyl acetate (500 μL) under stirring conditions and triethylamine (63 μL, 0.45 mmol) and Pd(OH)2/carbon catalyst (0.01 mmol, 20% wt on carbon) were added sequentially. The reaction system was placed in a hydrogen atmosphere at 45 psi and the reaction was shaken for 6 hours. Upon completion of the reaction, the catalyst was removed by filtration and the filtrate was concentrated under reduced pressure to afford the off-white solid product 2-amino-5-ethylpyrazine in 84% yield.

References[1] Patent: US2003/69284, 2003, A1
2-Amino-5-ethylpyrazine Preparation Products And Raw materials
Raw materials5-ethynylpyrazin-2-aMine-->2-Amino-5-bromopyrazine-->2-Pyrazinamine, 5-ethenyl--->Diethylzinc-->Ethyl acetate-->Triethylamine
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