2-[(3-chlorophenyl)Methyl]-4,4,5,5-tetraMethyl-1,3,2-dioxaborolane

Request For Quotation
2-[(3-chlorophenyl)Methyl]-4,4,5,5-tetraMethyl-1,3,2-dioxaborolane Suppliers list
Company Name: Shanghai Topbiochem Technology Co., Ltd  
Tel: 021-58170097
Email: info@topbiochem.com
Company Name: Shanghai Topbiochem Technology Co., Ltd  
Tel: +86-21-60341587
Email: sales@topbiochem.com
Company Name: Nanjing Credit Trading Co.,Ltd  
Tel: 025-52164950
Email: Googlexu_0114@sina.com
Company Name: Shanghai ShiXian Chemical Technology Co., Ltd.  
Tel: 13764359345
Email: 990877971@qq.com
Company Name: Shanghai Balmxy Pharmaceutical Co., Ltd  
Tel: 021-24206007 13764915196
Email: sales@balmxy.com

2-[(3-chlorophenyl)Methyl]-4,4,5,5-tetraMethyl-1,3,2-dioxaborolane manufacturers
2-[(3-chlorophenyl)Methyl]-4,4,5,5-tetraMethyl-1,3,2-dioxaborolane Basic information
Product Name:2-[(3-chlorophenyl)Methyl]-4,4,5,5-tetraMethyl-1,3,2-dioxaborolane
Synonyms:2-[(3-chlorophenyl)Methyl]-4,4,5,5-tetraMethyl-1,3,2-dioxaborolane;2-(3-Chlorobenzyl);(3-CHLOROBENZYL)BORONIC ACID PINACOL ESTER;1,3,2-Dioxaborolane, 2-[(3-chlorophenyl)methyl]-4,4,5,5-tetramethyl-
CAS:517920-59-1
MF:C13H18BClO2
MW:252.54
EINECS:
Product Categories:
Mol File:517920-59-1.mol
2-[(3-chlorophenyl)Methyl]-4,4,5,5-tetraMethyl-1,3,2-dioxaborolane Structure
2-[(3-chlorophenyl)Methyl]-4,4,5,5-tetraMethyl-1,3,2-dioxaborolane Chemical Properties
Boiling point 298.8±23.0 °C(Predicted)
density 1.08±0.1 g/cm3(Predicted)
storage temp. 2-8°C
AppearanceColorless to light yellow Liquid
Safety Information
HS Code 2931900090
MSDS Information
2-[(3-chlorophenyl)Methyl]-4,4,5,5-tetraMethyl-1,3,2-dioxaborolane Usage And Synthesis
Synthesis
4-Chlorobenzyl chloride

104-83-6

Bis(pinacolato)diboron

73183-34-3

2-[(3-chlorophenyl)Methyl]-4,4,5,5-tetraMethyl-1,3,2-dioxaborolane

517920-59-1

Example 5: Magnesium chips (16.8 mg, 0.7 mmol) were added to the reaction system as an activator under argon protection. Catalyst Fe(acac)3 (3.5 mg, 0.010 mmol, 2 mol%), p-chlorobenzyl chloride (157 μl, 1.35 mmol) and bis(pinacolato)borate (127.0 mg, 0.5 mmol) were added sequentially to tetrahydrofuran (1 ml). The reaction was carried out at -10 °C for 5 h, followed by addition of water to terminate the reaction. The reaction mixture was extracted with ethyl acetate and the product was analyzed by gas chromatography in 81% yield.

References[1] Chemistry Letters, 2002, # 8, p. 780 - 781
[2] Patent: CN107903281, 2018, A. Location in patent: Paragraph 0026
[3] Journal of the American Chemical Society, 2012, vol. 134, # 25, p. 10693 - 10697
[4] Journal of the American Chemical Society, 2014, vol. 136, # 27, p. 9521 - 9523
2-[(3-chlorophenyl)Methyl]-4,4,5,5-tetraMethyl-1,3,2-dioxaborolane Preparation Products And Raw materials
Raw materials4-Chlorobenzyl bromide-->Pinacol-->4-Chlorobenzyl chloride-->Bis(pinacolato)diboron-->4-Chlorophenylboronic acid-->Pinacolborane-->(Trimethylsilyl)diazomethane-->Magnesium-->Ferric acetylacetonate-->Tetrahydrofuran
Tag:2-[(3-chlorophenyl)Methyl]-4,4,5,5-tetraMethyl-1,3,2-dioxaborolane(517920-59-1) Related Product Information
(2-Bromomethylphenyl)boronic acid, pinacol ester 4-(4,4,5,5-Tetramethyl-[1,3,2]dioxaborolan-2-yl)cyclohex-3-ene-1-carboxylic acid ethyl ester 4-Isoxazoleboronic acid pinacol ester 4-Chloro-3-methoxyphenylboronic acid pinacolester Ethyl 2-Methyl-3-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)benzoate methyl 2-methyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate 2-(2,5-DibroMophenyl)-4,4,5,5-tetraMethyl-1,3,2-dioxaborolane 3-Methoxybenzylboronic acid pinacol ester