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Silver heptafluorobutyrate

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Silver heptafluorobutyrate Basic information
Product Name:Silver heptafluorobutyrate
Synonyms:Silver(I) heptafluorobutanoate 97%;Silver(I) heptafluorobutyrate, Heptafluorobutyric acid, silver(I) salt;heptafluormaselnanstribrny;heptafluoro-butanoicacisilver(1++)salt;heptafluoro-butanoicacisilversalt;heptafluoro-butyricacisilver(1+)salt;silverheptafluorobutanoate;silverperfluorobutanoate
CAS:3794-64-7
MF:C4AgF7O2
MW:320.9
EINECS:223-266-1
Product Categories:
Mol File:3794-64-7.mol
Silver heptafluorobutyrate Structure
Silver heptafluorobutyrate Chemical Properties
Melting point 292-294 °C (lit.)
solubility probably soluble in a range of solvents, e.g. CHCl3, CH2Cl2, MeCN, alcohol, THF.
form powder
color white
Sensitive Light Sensitive
InChI1S/C4HF7O2.Ag/c5-2(6,1(12)13)3(7,8)4(9,10)11;/h(H,12,13);/q;+1/p-1
InChIKeyGPNIJXACCBKBEP-UHFFFAOYSA-M
SMILESFC(F)(F)C(F)(F)C(F)(F)C(=O)O[Ag]
CAS DataBase Reference3794-64-7(CAS DataBase Reference)
EPA Substance Registry SystemSilver heptafluorobutyrate (3794-64-7)
Safety Information
Hazard Codes Xi,T
Risk Statements 41
Safety Statements 26-37/39
WGK Germany 2
RTECS EK7875000
Hazard Note Toxic
TSCA TSCA listed
HS Code 2843290000
Storage Class11 - Combustible Solids
Hazard ClassificationsEye Dam. 1
Toxicityrat,LD50,oral,2140mg/kg (2140mg/kg),"Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha, Czechoslovakia, 1972Vol. -, Pg. 8, 1972.
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Silver heptafluorobutyrate Usage And Synthesis
UsesSilver(I) Heptafluorobutanoate has also been used in combination with the lanthanide agent Ln([2H9]fod)3 as an NMR shift reagent for alkenes.[1]
storageSilver(I) Heptafluorobutanoate should be handled in a fume hood with rubber gloves and safety glasses; avoided skin contact and inhalation. Store in a tight container in a cool place. Light sensitive. Severe eye irritant with an obnoxious smell. The toxicology of this compound has not been fully evaluated.
References1. Evans, D. F.; Tucker, J. N.; de Vellardi, G. C. CC 1975, 205.
Silver heptafluorobutyrate Preparation Products And Raw materials
Tag:Silver heptafluorobutyrate(3794-64-7) Related Product Information
Sodium Butyrate Heptafluorobutyric anhydride 3,3,4,4,4-Pentafluorobutan-1-ol 2,2,3,4,4,4-Hexafluoro-1-butanol Heptafluorobutyraldehyde hydrate, tech. Silver fluoroacetate Silver heptafluorobutyrate Silver Silver acetate 2,2,3,3,4,4,4-Heptafluoro-1-butanol Heptafluorobutyric acid