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| | 2-Iodo-4-methoxy-1-nitrobenzene Basic information |
| Product Name: | 2-Iodo-4-methoxy-1-nitrobenzene | | Synonyms: | 3-IODO-4-NITROANISOLE;4-NITRO-3-IODOANISOLE;3-Iodo-4-nitroanisole,97%;2-Iodo-4-Methoxy-1-nitrobenzene;3-Iodo-4-nitroanisole, 97% 5GR;2-Iodo-4-methoxy-1-nitrobenzene, 3-Iodo-4-nitrophenyl methyl ether;3-Iodo-4-nitroanisol;Benzene, 2-iodo-4-methoxy-1-nitro- | | CAS: | 214279-40-0 | | MF: | C7H6INO3 | | MW: | 279.03 | | EINECS: | | | Product Categories: | Aromatic Ethers | | Mol File: | 214279-40-0.mol |  |
| | 2-Iodo-4-methoxy-1-nitrobenzene Chemical Properties |
| Melting point | 68-73 °C | | Boiling point | 352.1±27.0 °C(Predicted) | | density | 1.9259 (estimate) | | storage temp. | Keep in dark place,Sealed in dry,Room Temperature | | form | Crystals or Crystalline Powder | | color | Yellow to orange-brown | | InChI | InChI=1S/C7H6INO3/c1-12-5-2-3-7(9(10)11)6(8)4-5/h2-4H,1H3 | | InChIKey | NLTAHTYBZZSCIT-UHFFFAOYSA-N | | SMILES | C1([N+]([O-])=O)=CC=C(OC)C=C1I |
| Hazard Codes | Xn | | Risk Statements | 36-33-20/21/22 | | Safety Statements | 36/37-22 | | WGK Germany | WGK 3 | | HS Code | 29093090 | | Storage Class | 11 - Combustible Solids |
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ACROS
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| | 2-Iodo-4-methoxy-1-nitrobenzene Usage And Synthesis |
| Chemical Properties | yellow to orange-brown crystals or | | Synthesis | Silak reaction tube equipped with a magnetic stirrer was charged with 6.2 mg of silver sulfate,21.8 mg of copper acetate, 12.5 mg of 2,9-dimethyl-1,10-o-phenanthroline,39.4 mg of 2-nitro-5-methoxybenzoic acid and 45 mg of sodium iodide4 mL of dimethyl sulfoxide. The reaction was heated at 160 ° C for 24 hours with oxygen. After the reaction, distilled water was added to quench the reaction. Extraction with ethyl acetate 3 times, each time 10mL. The combined organic phases are concentrated; 35.2 mg of 2-Iodo-4-methoxy-1-nitrobenzene was obtained in a yield of 63 percent. | | References | [1] Patent: CN107325002, 2017, A. Location in patent: Paragraph 0133
[2] Organic and Biomolecular Chemistry, 2018, vol. 16, # 30, p. 5416 - 5421
[3] Journal of Organic Chemistry, 2016, vol. 81, # 7, p. 2794 - 2803 |
| | 2-Iodo-4-methoxy-1-nitrobenzene Preparation Products And Raw materials |
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