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3-(chloromethyl)-1-methyl-1H-1,2,4-Triazole hydrochloride

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3-(chloromethyl)-1-methyl-1H-1,2,4-Triazole hydrochloride Basic information
Synthesis
Product Name:3-(chloromethyl)-1-methyl-1H-1,2,4-Triazole hydrochloride
Synonyms:3-(Chloromethyl)-1-methyl-1H-1,2,4-triazole hydrochloride;3-Chloromethyl-1-methyl-1H-[1,2,4]triazole HCl;l)-1-methyl-1H-1,2,4-triazo;3-(Gymethyl)-1-methyl-11-1,2.4-triazole hydrochloride;1H-1,2,4-Triazole, 3-(chloromethyl)-1-methyl-, hydrochloride;3-(CHLOROMETHYL)-1-METHYL-1H-1,2,4-TRIAZOLE HYDROCHLORIDE N
CAS:135206-76-7
MF:C4H6ClN3
MW:131.56
EINECS:
Product Categories:S-217622
Mol File:135206-76-7.mol
3-(chloromethyl)-1-methyl-1H-1,2,4-Triazole hydrochloride Structure
3-(chloromethyl)-1-methyl-1H-1,2,4-Triazole hydrochloride Chemical Properties
Melting point >149°C (dec.)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility DMSO (Sparingly), Methanol (Slightly)
form Solid
color White to Off-White
Stability:Hygroscopic
InChIInChI=1S/C4H6ClN3.ClH/c1-8-3-6-4(2-5)7-8;/h3H,2H2,1H3;1H
InChIKeyKISIDCUHOLGEPR-UHFFFAOYSA-N
SMILESCl.C(C1N=CN(C)N=1)Cl
Safety Information
HazardClass IRRITANT
HS Code 2933998090
MSDS Information
3-(chloromethyl)-1-methyl-1H-1,2,4-Triazole hydrochloride Usage And Synthesis
SynthesisIn a dry 100 mL reaction flask, under nitrogen protection, (1-methyl-1H-1,2,4-triazol-3-yl)methanol (0.25 g, 2.2 mmol) was dissolved in 10 mL of thionyl chloride. The resulting reaction mixture was heated to reflux and stirred for 2 hours while maintaining reflux. After the reaction was complete, the resulting reaction mixture was cooled to room temperature and then concentrated to dryness under vacuum (toluene can be added to the reaction mixture for further concentration to remove residual thionyl chloride). The resulting white solid (0.2 g) is the target product 3-(chloromethyl)-1-methyl-1H-1,2,4-triazole hydrochloride, which requires no further purification. Synthetic route of 3-(chloromethyl)-1-methyl-1H-1,2,4-triazole hydrochloride" alt="Synthetic route of 3-(chloromethyl)-1-methyl-1H-1,2,4-triazole hydrochloride">

Figure 3-(chloromethyl)-1-methyl-1H-1,2,4-triazole hydrochloride

Chemical Properties3-(Chloromethyl)-1-methyl-1H-1,2,4-triazole hydrochloride is white or off-white solid at room temperature and pressure, with certain hygroscopicity and good chemical stability. It can be neutralized under alkaline conditions to release the corresponding triazole compounds, and the obtained triazole compounds have good chemical reaction activity and can participate in a variety of organic conversion reactions.
Uses3-(chloromethyl)-1-methyl-1H-1,2,4-triazole hydrochloride is a useful research chemical.
3-(chloromethyl)-1-methyl-1H-1,2,4-Triazole hydrochloride Preparation Products And Raw materials
Tag:3-(chloromethyl)-1-methyl-1H-1,2,4-Triazole hydrochloride(135206-76-7) Related Product Information
2-Methylindole Chlorotrimethylsilane p-Toluic acid Chloromethyl silane p-Toluidine Methylcyclohexane 7-(4-Chlorophenyl)-2-(trichloromethyl)[1,2,4]triazolo[1,5-a]pyridine-8-carbonitrile 7-Difluoromethyl-5-methyl-[1,2,4]triazolo[1,5-a]-pyrimidine-2-carbonyl chloride 3-(chloromethyl)-1-methyl-1H-1,2,4-Triazole hydrochloride