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| | Dichloro(di-μ-chloro)bis[1,3-bis(2,6-di-I-propylphenyl)imidazol-2-ylidene]dipalladium (II) Basic information | | Reaction |
| Product Name: | Dichloro(di-μ-chloro)bis[1,3-bis(2,6-di-I-propylphenyl)imidazol-2-ylidene]dipalladium (II) | | Synonyms: | Dichloro[1,3-bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene]palladium(II) dimer;Dichloro[1,3-bis(diisopropylphenyl)-2-imidazolidinylidene]palladium(II) dimer;0.0.;DICHLORO(DI-MU-CHLORO)BIS[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]DIPALLADIUM (II);Dichloro(di-mu-chloro)bis[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]dipalladium(II),97%;DICHLORO-[1,3-BIS(DIISOPROPYLPHENYL)IMIDAZOLE-2-YLIDENE]PALLADIUM(II)-DIMER;Dichloro(di-mu-chloro)bis[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]
dipalladium (II), 97%;[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]-dichloro-palla dium | | CAS: | 444910-17-2 | | MF: | 2C27H36Cl2N2Pd | | MW: | 1131.84 | | EINECS: | | | Product Categories: | Pd;organometallic complex | | Mol File: | 444910-17-2.mol | ![Dichloro(di-μ-chloro)bis[1,3-bis(2,6-di-I-propylphenyl)imidazol-2-ylidene]dipalladium (II) Structure](CAS/GIF/444910-17-2.gif) |
| | Dichloro(di-μ-chloro)bis[1,3-bis(2,6-di-I-propylphenyl)imidazol-2-ylidene]dipalladium (II) Chemical Properties |
| Melting point | 0°C | | Boiling point | 0°C | | Fp | 0°C | | storage temp. | 2-8°C | | form | Powder | | color | orange to tan | | InChIKey | TXCXGICCIUAGJY-UHFFFAOYSA-J | | SMILES | CC(C)c1cccc(C(C)C)c1N2C=CN(c3c(cccc3C(C)C)C(C)C)\C2=[Pd](\Cl)Cl.CC(C)c4cccc(C(C)C)c4N5C=CN(c6c(cccc6C(C)C)C(C)C)\C5=[Pd](\Cl)Cl |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26 | | WGK Germany | 3 | | HS Code | 28439000 | | Storage Class | 11 - Combustible Solids | | Hazard Classifications | Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| | Dichloro(di-μ-chloro)bis[1,3-bis(2,6-di-I-propylphenyl)imidazol-2-ylidene]dipalladium (II) Usage And Synthesis |
| Reaction |
- Catalyst used for the intramolecular, direct arylation reaction with aryl chlorides.
- Catalyst used for aerobic oxidative kinetic resolution of secondary alcohols.
- Catalyst used for aryl amination.
- Highly active catalyst for the Mizoroki-Heck reaction.
- Highly efficient catalytic hydrodehalogenation of polychlorinated biphenyls.
| | Chemical Properties | Orange solid | | reaction suitability | core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst |
| | Dichloro(di-μ-chloro)bis[1,3-bis(2,6-di-I-propylphenyl)imidazol-2-ylidene]dipalladium (II) Preparation Products And Raw materials |
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