4-Iodo-N,N-dimethyl-Benzenamine

4-Iodo-N,N-dimethyl-Benzenamine Suppliers list

Company Name:	Shanghai alkynechem Co., Ltd. Gold
Tel:	086-021-15821262312 15821262312
Email:	info@alkynechem.com

4-Iodo-N,N-dimethyl-Benzenamine Basic information

Product Name:	4-Iodo-N,N-dimethyl-Benzenamine
Synonyms:	4-Iodo-N,N-dimethyl-Benzenamine;1-DIMETHYLAMINO-4-IODOBENZENE;4-(N,N-DIMETHYLAMINO)IODOBENZENE;N,N-DIMETHYLAMINO-4-IODOANILINE;Benzenamine, 4-iodo-N,N-dimethyl-;4-Iodo-N,N-dimethylanilin
CAS:	698-70-4
MF:	C8H10IN
MW:	247.08
EINECS:
Product Categories:
Mol File:	698-70-4.mol

4-Iodo-N,N-dimethyl-Benzenamine Chemical Properties

Melting point	79.5 °C
Boiling point	263.7±23.0 °C(Predicted)
density	1.652±0.06 g/cm3(Predicted)
storage temp.	Keep in dark place,Sealed in dry,Store in freezer, under -20°C
solubility	Chloroform (Slightly), Ethyl Acetate (Slightly)
form	Solid
pka	4.14±0.12(Predicted)
color	Very Dark Blue to Very Dark Purple

Safety Information

MSDS Information

4-Iodo-N,N-dimethyl-Benzenamine Usage And Synthesis

Uses	4-Iodo-N,N-dimethylaniline is a useful reactant for organic reactions and the synthesis of various compounds.
Synthesis	121-69-7 698-70-4 General procedure for the synthesis of 4-N,N-dimethylaminoiodobenzene from N,N-dimethylaniline: to a stirred solution of N,N-dimethylaniline (1 mmol) in dichloromethane (CH2Cl2) or 1,2-dichloroethane ((CH2Cl)2) (0.1 M) was added sequentially Ph3PAuNTf2 (0.025 mmol, 19 mg; if using the 2:1 complex of Ph3PAuNTf2 with toluene) and N-iodosuccinimide (NIS, 1.1 mmol, 248 mg). The reaction mixture was stirred at room temperature or reacted under reflux conditions until complete conversion of the feedstock was shown by thin layer chromatography (TLC) monitoring. Upon completion of the reaction, the solvent was evaporated under reduced pressure and the resulting crude product was purified by fast column chromatography using different ratios of hexane and ethyl acetate (EtOAc) as eluents, resulting in pure 4-N,N-dimethylaminoiodobenzene.
References	[1] RSC Advances, 2014, vol. 4, # 12, p. 6267 - 6274 [2] Journal of Organic Chemistry, 1993, vol. 58, # 8, p. 2058 - 2060 [3] Tetrahedron Letters, 2005, vol. 46, # 32, p. 5421 - 5423 [4] Tetrahedron, 2005, vol. 61, # 49, p. 11657 - 11663 [5] Helvetica Chimica Acta, 2007, vol. 90, # 11, p. 2087 - 2095

4-Iodo-N,N-dimethyl-Benzenamine Preparation Products And Raw materials

Raw materials	[p-(dimethylamino)phenyl]lithium-->4-Chloro-N,N-dimethylaniline-->1-Iodo-4-nitrobenzene-->tert-Butyl N-(4-iodophenyl)carbamate-->4-(Dimethylamino)phenylboronic acid-->2-iodo-N,N-dimethyl-aniline-->N,N-Dimethylaniline hydrochloride-->1-Hexene-->Dimethyl sulfoxide-->Iodomethane-->Formaldehyde-->4-Bromo-N,N-dimethylaniline-->4-Iodoaniline
Preparation Products	4'-Dimethylaminophenyl acetylene-->4-Iodo-N-methylaniline

Tag:4-Iodo-N,N-dimethyl-Benzenamine(698-70-4) Related Product Information

sodium metrizoate Metrizamide Iohexol 1-(5-Iodoindolin-1-yl)ethanone N-(4-Iodophenyl)succinimide 1-(4-Iodophenyl)-1H-pyrrole-2,5-dione 4-Iodo-N,N-dimethyl-Benzenamine AKOS AUF0217 3-[(4-chlorophenyl)sulfanyl]-1-(4-iodophenyl)dihydro-1H-pyrrole-2,5-dione N-(2,4-dimethoxybenzyl)-N-(4-iodophenyl)-N'-phenylthiourea 2-(4-iodophenyl)-2,3-dihydro-1H-isoindol-1-imine methylglucamine metrizoate 1-(4-Iodophenyl)-3-[(4-methylphenyl)sulfanyl]dihydro-1H-pyrrole-2,5-dione 1-Amino-4-(4-iodophenyl)piperazine-2,5-dione 1-(4-Iodophenyl)-3-piperidinodihydro-1H-pyrrole-2,5-dione 1-(4-Iodophenyl)-3-morpholinodihydro-1H-pyrrole-2,5-dione N-(2,4-Dimethoxybenzyl)-N-(4-iodophenyl)-N'-methylthiourea N'-Benzyl-N-(2,4-dimethoxybenzyl)-N-(4-iodophenyl)thiourea

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