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Butoxyethyl (2,4-dichlorophenoxy)acetate

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Butoxyethyl (2,4-dichlorophenoxy)acetate Basic information
Product Name:Butoxyethyl (2,4-dichlorophenoxy)acetate
Synonyms:(2,4-Dichlorophenoxy)acetic acid 2-butoxyethyl ester;(2,4-Dichlorophenoxy)acetic acid butoxyethanol ester;(2,4-dichlorophenoxy)-aceticaci2-butoxyethylester;(2,4-dichlorophenoxy)-aceticacibutoxyethylester;2,4-D Butoxyethanol ester;2,4-d,butoxyethanolester;2,4-dbee;2,4-D-BEE
CAS:1929-73-3
MF:C14H18Cl2O4
MW:321.2
EINECS:217-680-1
Product Categories:
Mol File:1929-73-3.mol
Butoxyethyl (2,4-dichlorophenoxy)acetate Structure
Butoxyethyl (2,4-dichlorophenoxy)acetate Chemical Properties
Boiling point 436.81°C (rough estimate)
density 1.2320
refractive index 1.5110 (estimate)
OdorMay have odor of fuel oil.
BRN 1996617
Henry's Law Constant6.2×101 mol/(m3Pa) at 25℃, Duchowicz et al. (2020)
NIST Chemistry Reference2-Butoxyethyl (2,4-dichlorophenoxy)acetate(1929-73-3)
EPA Substance Registry System2,4-D 2-butoxyethyl ester (1929-73-3)
Safety Information
Hazard Codes Xn;N,N,Xn
Risk Statements 22-43-50/53
Safety Statements 26-29-36/37-46-60-61
RIDADR UN 3082
WGK Germany 3
RTECS AG7700000
HazardClass 6.1(b)
PackingGroup III
Hazardous Substances Data1929-73-3(Hazardous Substances Data)
MSDS Information
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Butoxyethyl (2,4-dichlorophenoxy)acetate English
Butoxyethyl (2,4-dichlorophenoxy)acetate Usage And Synthesis
Chemical Properties2,4-Dichlorophenoxyacetic acid is a white to yellow crystalline powder with a slight phenolic odor.
Uses2,4-D-Butylglycol Ester is a reagent used in the preparation of fungicides, herbicides and insecticides.Environmental toxin on US EPA Toxic Release Inventory list (TRI) list.
Production MethodsThe commercial production of 2,4-D-butotylester begins with purified 2,4-D acid, obtained via the standard phenoxyacetic acid route. The free acid is dissolved in water or a mixed solvent and then neutralised with butotyl alcohol (a branched C4-C6 alcohol blend used historically in specialty esters) under controlled pH and temperature, forming the ester.
Health HazardRecommended Personal Protective Equipment: Face shield or goggles; rubber gloves; Symptoms Following Exposure: Contact with eyes may cause mild irritation; General Treatment for Exposure: INGESTION: if large amounts are swallowed, induce vomiting and get medical help. EYES: flush with plenty of water and see a doctor. SKIN: flush with water, wash with soap and water; Toxicity by Inhalation (Threshold Limit Value): Data not available; Short-Term Exposure Limits: Data not available; Toxicity by Ingestion: Grade 2 or 3:LD50 = 320-617 mg/kg; Late Toxicity: Data not available; Vapor (Gas) Irritant Characteristics: Data not available; Liquid or Solid Irritant Characteristics: Data not available; Odor Threshold: Data not available.
Chemical ReactivityReactivity with Water No reaction; Reactivity with Common Materials: May attack some forms ofplastics; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.
Mechanism of actionSelective, systemic, absorbed through roots and increases biosynthesis and production of ethylene causing uncontrolled cell division and so damages vascular tissue. Synthetic auxin.
Potential Exposure2,4-Dichlorophenoxyacetic acid, was introduced as a plant growth-regulator in 1942. It is registered in the United States as a herbicide for control of broadleaf plants and as a plant growth-regulator. Thus, workers engaged in manufacture, formulation or application are affected, as may be citizens in areas of application. The Vietnam war era defoliant, Agent Orange, was a mixture of 2,4-D and 2,4,5-T.
ShippingUN3345 Phenoxyacetic acid derivative pesticide, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. A DOT regulated marine pollutant.
IncompatibilitiesA weak acid, incompatible with bases. Decomposes in sunlight or heat, forming hydrogen chloride and phosgene. Contact with strong oxidizers may cause fire and explosions.
Waste DisposalIncineration of phenoxys is effective in 1 second @ 982 C, using a straight combustion process or @ 482℃ using catalytic combustion. Over 99% decomposition was reported when small amounts of 2,4-D were burned in a polyethylene bag. See “References” for additional detail. In accordance with 40CFR165, follow (31); recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by follow- ing (100) Package (2) label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Consult with environ- mental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regu- lations governing storage, transportation, treatment, and waste disposal.
Pesticide TypeHerbicide
Butoxyethyl (2,4-dichlorophenoxy)acetate Preparation Products And Raw materials
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