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| | 1-ACETOXY-1-CYANOETHYLENE Basic information |
| | 1-ACETOXY-1-CYANOETHYLENE Chemical Properties |
| Boiling point | 80-82 °C30 mm Hg(lit.) | | density | 1.061 g/mL at 20 °C(lit.) | | vapor pressure | 30 mm Hg ( 80 °C) | | refractive index | n20/D 1.426(lit.) | | Fp | 147 °F | | storage temp. | Sealed in dry,2-8°C | | solubility | sol most organic solvents other than pure hydrocarbons. | | form | clear liquid | | color | Colorless to Light yellow | | BRN | 1751158 | | CAS DataBase Reference | 3061-65-2(CAS DataBase Reference) |
| Hazard Codes | T | | Risk Statements | 23/24/25-41-37/38 | | Safety Statements | 36/37/39-45-26 | | RIDADR | UN 3276 6.1/PG 2 | | WGK Germany | 3 | | RTECS | AG4550000 | | HS Code | 2926.90.5050 | | HazardClass | 6.1(a) | | PackingGroup | II | | Toxicity | skn-rbt 10 mg/24H open MLD AIHAAP 23,95,62 |
| | 1-ACETOXY-1-CYANOETHYLENE Usage And Synthesis |
| Reactivity Profile |
1-cyanovinyl acetate is a ketene equivalent for use in the Diels-Alder reaction; undergoes other cycloaddition reactions; reacts with nucleophiles and radicals[1].
| | Safety Profile | Poison by inhalation, ingestion, andskin contact. A skin irritant. Whenheated to decomposition it emits toxic fumes of NOx andCN-. | | storage |
Handling, Storage, and Precautions: highly toxic; use only in a fume hood. Reagent can be absorbed through the skin. Always wear gloves when handling this reagent.
| | References |
1. Ranganathan, S.; Ranganathan, D.; Mehrotra, A. K. S 1977, 289.
2. Brown, D. S.; Paquette, L. A. JOC 1992, 57, 4512.
3. Nowak, R. M. JOC 1963, 28, 1182.
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| | 1-ACETOXY-1-CYANOETHYLENE Preparation Products And Raw materials |
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