(S)-7-Methoxy-1-methyl-1,2,3,4-tetrahydro-isoquinolin-6-ol

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(S)-7-Methoxy-1-methyl-1,2,3,4-tetrahydro-isoquinolin-6-ol Basic information
Product Name:(S)-7-Methoxy-1-methyl-1,2,3,4-tetrahydro-isoquinolin-6-ol
Synonyms:KBioGR_002385;KBioSS_001943;NCGC00095326-01;Oprea1_746478;SBB007369;SDCCGMLS-0066795.P001;SPBio_000559;SpecPlus_000614
CAS:101467-40-7
MF:C11H15NO2
MW:193.24
EINECS:
Product Categories:
Mol File:101467-40-7.mol
(S)-7-Methoxy-1-methyl-1,2,3,4-tetrahydro-isoquinolin-6-ol Structure
(S)-7-Methoxy-1-methyl-1,2,3,4-tetrahydro-isoquinolin-6-ol Chemical Properties
Melting point 221°
alpha D20 +34.5° (c = 1 in 0.1N HCl)
Boiling point 336.7±42.0 °C(Predicted)
density 1.106±0.06 g/cm3(Predicted)
pka9.32±0.40(Predicted)
Safety Information
MSDS Information
(S)-7-Methoxy-1-methyl-1,2,3,4-tetrahydro-isoquinolin-6-ol Usage And Synthesis
DescriptionA further isoquinoline alkaloid which occurs in Salsola Richteri, the base is obtained in the form of a microcrystalline powder which is readily soluble in CHC13 or EtOH but only sparingly so in C6H6 or H20. The alkaloid is soluble in aqueous alkalies but insoluble in petroleum ether. The hydrochloride crystallizes as the sesquihydrate in colourless needles, m.p. 14l-152°C. The N-benzoyl derivative has m.p. 172-4° and the O,N-dibenzoyl compound, m.p. 166-8°C. Treatment with CH2N2 gives Salsolidine (q.v.). The structure, 1:2:3:4-tetrahydro6-hydroxy-7-methoxy-l-methylisoquinoline has been confirmed by synthesis.
UsesSalsoline (cas# 89-31-6) was identified as an analyte component in Tibetan Medicine via HPLC-Q-TOF/MS.
ReferencesOrekhov, Proskurnina., Ber., 66,841 (1933)
Orekhov, Proskurnina., ibid, 67,878 (1934)
Spath, Orekhov, Kuffner., ibid, 67, 1214 (1934)
(S)-7-Methoxy-1-methyl-1,2,3,4-tetrahydro-isoquinolin-6-ol Preparation Products And Raw materials
Tag:(S)-7-Methoxy-1-methyl-1,2,3,4-tetrahydro-isoquinolin-6-ol(101467-40-7) Related Product Information
Boldine dimethyl ether Noscapine hydrochloride Isoquinolin-6-ol Boldine Narcotine (+)-BULBOCAPNINE Emetine D-TUBOCURARINE CHLORIDE Emetine dihydrochloride (-)-STYLOPINE Isocorydine hydrochloride Isocorydine hydrochloride 1,2,3,4-Tetrahydro-isoquinolin-6-ol Bulbocapnine hydrochloride PAVINE HCL (-)-BICUCULLINE METHOCHLORIDE L-Tetrandrine ESCHSCHOLTZINE HCL