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alpha-Methylbenzyl alcohol

alpha-Methylbenzyl alcohol Suppliers list
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alpha-Methylbenzyl alcohol manufacturers

alpha-Methylbenzyl alcohol Basic information
Product Name:alpha-Methylbenzyl alcohol
Synonyms:PHENYLMETHYLCARBINOL;PHENYLETHANOL,1-;SEC-PHENETHYL ALCOHOL;STYRENE ALCOHOL;METHYL PHENYL CARBINEL;DL-1-PHENYLETHANOL;DL-1-PHENYLETHYL ALCOHOL;DL-2-METHYL PHENYL METHANOL
CAS:13323-81-4
MF:C8H10O
MW:122.16
EINECS:236-361-8
Product Categories:
Mol File:13323-81-4.mol
alpha-Methylbenzyl alcohol Structure
alpha-Methylbenzyl alcohol Chemical Properties
Melting point 19-20 °C(lit.)
Boiling point 204 °C745 mm Hg(lit.)
density 1.012 g/mL at 25 °C(lit.)
vapor density 4.21 (vs air)
vapor pressure 0.1 mm Hg ( 20 °C)
refractive index n20/D 1.527(lit.)
Fp 185 °F
Dielectric constant7.6(90℃)
CAS DataBase Reference13323-81-4(CAS DataBase Reference)
Safety Information
Hazard Codes Xn
Risk Statements 22-38-41
Safety Statements 26-39
RIDADR UN 3438
WGK Germany 1
RTECS DO9275000
HazardClass 6.1
PackingGroup III
toxicityThe acute oral LD50 in rats was reported as 400 mg/kg (Smyth & Carpenter, 1944). The acute dermal LD50 value in rabbits exceeded 2.5 g/kg (Moreno, 1973).
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
alpha-Methylbenzyl alcohol Usage And Synthesis
Chemical PropertiesColorless liquid
OccurrenceHas apparently not been reported to occur in nature.
PreparationBy hydrogenation or reduction of acetophenone; or from methyl magnesium chloride plus benzaldehyde by a Grignard-type reaction (Bedoukian, 1967).
DefinitionChEBI: 1-phenylethanol is an aromatic alcohol that is ethanol substituted by a phenyl group at position 1. It has a role as a mouse metabolite.
MetabolismStyrallyl alcohol is converted in rabbits into hippuric acid and methylphenylcarbinyl glucuronide, both optical forms of the carbinol behaving similarly. A small proportion (1-2%) is excreted as mandelic acid (Wjlliams, 1959).
Purification MethodsPurify the alcohol via its hydrogen phthalate. [See Houssa & Kenyon J Chem Soc 2260 1930.] Shake it with a solution of ferrous sulfate, and th
alpha-Methylbenzyl alcohol Preparation Products And Raw materials
Preparation ProductsFEMA 2686-->1-Phenylethyl chloroformate-->4-Methoxy-2-(1-phenyl-ethyl)-phenol-->1-Phenylethan-1,2,2,2-d4-ol-->3-(3-Methylphenyl)propiophenone
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