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o-Xylylenebis(triphenylphosphonium bromide)

o-Xylylenebis(triphenylphosphonium bromide) Suppliers list
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o-Xylylenebis(triphenylphosphonium bromide) Basic information
Product Name:o-Xylylenebis(triphenylphosphonium bromide)
Synonyms:O-XYLENE BIS(TRIPHENYLPHOSPONIUM BROMIDE);[1,2-phenylenebis(methylene)]bis[triphenylphosphonium] dibromide;O-XYLYLENEBIS(TRIPHENYLPHOSPHONIUM BROMIDE), 98+%;(o-Phenylenedimethylene)bis[triphenylphosphonium bromide];1,2-Bis(triphenylphosphoniomethyl)benzene dibromide;NSC 665614;NSC 78589;triphenyl-[[2-(triphenylphosphaniumylmethyl)phenyl]methyl]phosphanium:dibromide
CAS:1519-46-6
MF:C44H38BrP2+
MW:708.64
EINECS:216-183-7
Product Categories:C-C Bond Formation;Olefination;Wittig Reagents
Mol File:1519-46-6.mol
o-Xylylenebis(triphenylphosphonium bromide) Structure
o-Xylylenebis(triphenylphosphonium bromide) Chemical Properties
Melting point >300 °C (lit.)
storage temp. Store at room temperature, keep dry and cool
AppearanceWhite to off-white Solid
Sensitive Hygroscopic
BRN 4121635
InChIKeyMXCBXCYGWQAOSN-UHFFFAOYSA-L
SMILES[Br-].[Br-].C(c1ccccc1C[P+](c2ccccc2)(c3ccccc3)c4ccccc4)[P+](c5ccccc5)(c6ccccc6)c7ccccc7
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
RIDADR 3278
WGK Germany 3
HazardClass 6.1
PackingGroup III
Storage Class11 - Combustible Solids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
o-Xylylenebis(triphenylphosphonium bromide) Usage And Synthesis
UsesReactant for:
  • Synthesis of [6.8]3cyclacene and polyunsaturated [23] and [24]metacyclophanes
  • Selective inclusion of equatorial isomers of cyclohexane-polyols in phosphonium salt hosts
  • Photoactive platinum(II) DNA intercalator synthesis
  • Preparation of (pheynlenedivinylene)bis[pyrrole] derivatives
  • The reaction with sodium hexamethyldisilazide to form acyclic, ring, and cage AS,C compounds
  • Synthesis of styryl substituted annelated furan derivatives
reaction suitabilityreaction type: C-C Bond Formation
o-Xylylenebis(triphenylphosphonium bromide) Preparation Products And Raw materials
Tag:o-Xylylenebis(triphenylphosphonium bromide)(1519-46-6) Related Product Information
p-Xylylenebis(triphenylphosphonium bromide) 1,2-Bis(diphenylphosphinomethyl)benzene para-Xylylenebis-(triphenylphosphonium 2-Methylbenzyl triphenylphosphonium bromide o-Xylylenebis(triphenylphosphonium bromide) Triphenylphosphine O-XYLYLENEBIS(TRIPHENYLPHOSPHONIUM BROMIDE) Benzyltriphenylphosphonium bromide