BIS(PHENYLTHIO)METHANE

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BIS(PHENYLTHIO)METHANE Basic information
Product Name:BIS(PHENYLTHIO)METHANE
Synonyms:BIS(PHENYLTHIO)METHANE;1-(methylthio)-2-(phenylthio)benzene;1,1'-(Methanediyldisulfanediyl)dibenzene;1-([(PHENYLTHIO)METHYL]THIO)BENZENE;DIPHENYLTHIOMETHANE;FORMALDEHYDE DIPHENYL MERCAPTAL;1,1'-(METHYLENEBIS(THIO))BISBENZENE;[methylenebis(thio)]bisbenzene
CAS:3561-67-9
MF:C13H12S2
MW:232.36
EINECS:222-624-4
Product Categories:Sulfur Compounds (for Synthesis);Synthetic Organic Chemistry
Mol File:3561-67-9.mol
BIS(PHENYLTHIO)METHANE Structure
BIS(PHENYLTHIO)METHANE Chemical Properties
Melting point 34-37 °C(lit.)
Boiling point 194 °C8 mm Hg(lit.)
density 1.2633 (rough estimate)
refractive index 1.6210 (estimate)
Fp >230 °F
storage temp. Sealed in dry,Room Temperature
form powder to crystal
color White to Light yellow
Water Solubility Insoluble in water.
BRN 1874146
InChI1S/C13H12S2/c1-3-7-12(8-4-1)14-11-15-13-9-5-2-6-10-13/h1-10H,11H2
InChIKeyZHUPZVIALZHGGP-UHFFFAOYSA-N
SMILESC(Sc1ccccc1)Sc2ccccc2
CAS DataBase Reference3561-67-9(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
RIDADR UN 3335
WGK Germany 3
F 13
HazardClass STENCH
HS Code 29309090
Storage Class11 - Combustible Solids
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
BIS(PHENYLTHIO)METHANE Usage And Synthesis
Chemical Propertieslight yellow crystalline powder
UsesBis(phenylthio)methane (PhSCH2SPh) may be used in the synthesis of the following:
  • dihydroxy thioethers
  • [Cu4I4{μ-PhS2CH2SPh}2]n
  • [(η5-C5Me5)MCl2(η1-(PhS)2CH2)] (M=Rh, Ir ; C5Me5= pentamethylcyclopentadienyl)
  • 6-deoxy-1,2:3,4-di-O-isopropylidene-α-D-galactoheptodialdo-1,5-pyranose diphenyl dithioacetal
Synthesis Reference(s)Synthetic Communications, 19, p. 31, 1989 DOI: 10.1080/00397918908050949
Synthesis, p. 447, 1975 DOI: 10.1055/s-1975-23797
General DescriptionBis(phenylthio)methane (PhSCH2SPh) is a dithioether ligand. It forms coordination complex with silver(I) salts. It participates in the synthesis of (-)-rasfonin.
BIS(PHENYLTHIO)METHANE Preparation Products And Raw materials
Raw materialsThiophenol-->Diiodomethane-->SODIUM THIOPHENOXIDE
Preparation Products7-TRIDECANOL-->Biphenyl-4,4'-dithiol
Tag:BIS(PHENYLTHIO)METHANE(3561-67-9) Related Product Information
DICYCLOHEXYLDICHLOROSILANE BIS(4-CHLOROPHENYLTHIO)METHANE BIS(PHENYLSULFONYL)METHANE TRIPHENYL TRITHIOORTHOFORMATE BIS(PHENYLTHIO)METHANE BIS-(TOLUENE-4-SULFONYL)-METHANE Probucol ELSIBUCOL 4-[4-[2-(4-hydroxy-3,5-ditert-butyl-phenyl)sulfanylpropan-2-ylsulfanyl]-2,6-ditert-butyl-phenoxy]-4-oxo-butanoic acid BIS(P-TOLUENESULFONYL)DIAZOMETHANE 1,1,3-TRIS(PHENYLTHIO)-1-PROPENE BIS(2-CHLOROPHENYL) CYANOCARBONIMIDODITHIOATE CAMOBUCOL BIS[(4-CHLOROPHENYL)THIOMETHYLENE]BIPHOSPHONIC ACID, TETRAISOPROPYL ESTER 1,1-BIS(PHENYLSULFONYL)ETHYLENE SALOR-INT L147877-1EA 1,1,1-TRIFLUORO-4,4-BIS(PHENYLTHIO)BUT-3-EN-2-ONE 1-([2-METHYL-1-(PHENYLTHIO)PROPYL]THIO)BENZENE