(4S,5R)-(-)-cis-4,5-Diphenyl-2-oxazolidinone

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(4S,5R)-(-)-cis-4,5-Diphenyl-2-oxazolidinone Basic information
Product Name:(4S,5R)-(-)-cis-4,5-Diphenyl-2-oxazolidinone
Synonyms:(4S,5R)-(-)-CIS-4,5-DIPHENYL-2-OXAZOLIDI;(4S,5R)-45-diphenyloxazolidin-2-one;(-)-cis-4,5-Diphenyl-2-oxazolidinone;(4S,5R)-(-)-cis-Diphenyl-2-oxazolidinone;(4S-cis)-4,5-Diphenyl-2-oxazolidinone;(4S,5R)-cis-4,5-Diphenyloxazolidin-2-one;(4S,5R)-4,5-Diphenyl-2-oxazolidinone;(4S,5R)-4,5-Diphenyl-2-oxazolidinone,99%e.e.
CAS:23204-70-8
MF:C15H13NO2
MW:239.27
EINECS:
Product Categories:Asymmetric Synthesis;Chiral Auxiliaries;Oxazolidinone Derivatives
Mol File:23204-70-8.mol
(4S,5R)-(-)-cis-4,5-Diphenyl-2-oxazolidinone Structure
(4S,5R)-(-)-cis-4,5-Diphenyl-2-oxazolidinone Chemical Properties
Melting point 227-232 °C(lit.)
Boiling point 466.6±45.0 °C(Predicted)
density 1.192±0.06 g/cm3(Predicted)
storage temp. Refrigerator
solubility Chloroform (Slightly)
pka11.56±0.60(Predicted)
form Solid
color White to Off-White
Optical Rotation[α]23/D 57±4°, c = 2 in chloroform (or methanol)
InChI1S/C15H13NO2/c17-15-16-13(11-7-3-1-4-8-11)14(18-15)12-9-5-2-6-10-12/h1-10,13-14H,(H,16,17)/t13-,14+/m0/s1
InChIKeyLTENIVFVXMCOQI-UONOGXRCSA-N
SMILESO=C1N[C@H]([C@H](O1)c2ccccc2)c3ccccc3
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
Storage Class11 - Combustible Solids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
(4S,5R)-(-)-cis-4,5-Diphenyl-2-oxazolidinone Usage And Synthesis
Uses(4S,5R)-(-)-cis-Diphenyl-2-oxazolidinone is used as a catalyst in the enantioselective synthesis of chiral phthalides.
UsesVersatile chiral auxiliary used in a variety of highly diastereoselective reactions such as Michael additions, Diels-Alder reactions, cyclopropanations, and allylations.
(4S,5R)-(-)-cis-4,5-Diphenyl-2-oxazolidinone Preparation Products And Raw materials
Tag:(4S,5R)-(-)-cis-4,5-Diphenyl-2-oxazolidinone(23204-70-8) Related Product Information
(4S,5R)-(-)-cis-4,5-Diphenyl-2-oxazolidinone (4S,5R)-(-)-3-Butoxycarbonyl-methyl-4,5-diphenyl-2-oxazolidinone S-4-Phenyl-2-oxazolidonone (4S,5R)-(-)-4-Methyl-5-phenyl-2-oxazolidinone 4-Phenyloxazolidin-2-one (S)-4,5,5-TRIPHENYL-2-OXAZOLIDINONE Resedine (1R,2S)-2-Amino-1,2-diphenylethanol