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| | Bromomethyl methyl ether Basic information |
| | Bromomethyl methyl ether Chemical Properties |
| Boiling point | 87 °C (lit.) | | density | 1.531 g/mL at 25 °C (lit.) | | refractive index | n20/D 1.456(lit.) | | Fp | 80 °F | | storage temp. | 2-8°C | | solubility | Chloroform (Soluble), Methanol (Slightly) | | form | clear liquid | | color | Colorless to Light yellow to Light orange | | Specific Gravity | 1.531 | | Water Solubility | Sparingly soluble in water. | | Sensitive | Moisture Sensitive | | BRN | 1730853 | | InChI | 1S/C2H5BrO/c1-4-2-3/h2H2,1H3 | | InChIKey | JAMFGQBENKSWOF-UHFFFAOYSA-N | | SMILES | COCBr | | CAS DataBase Reference | 13057-17-5(CAS DataBase Reference) | | NIST Chemistry Reference | Bromomethyl methyl ether(13057-17-5) | | EPA Substance Registry System | Methane, bromomethoxy- (13057-17-5) |
| Hazard Codes | Xn | | Risk Statements | 10-20/21/22-36/37/38-40 | | Safety Statements | 26-36/37 | | RIDADR | UN 1992 3/PG 3 | | WGK Germany | 3 | | TSCA | TSCA listed | | HazardClass | 6.1 | | PackingGroup | II | | HS Code | 29091990 | | Storage Class | 3 - Flammable liquids | | Hazard Classifications | Acute Tox. 4 Dermal
Carc. 2
Eye Irrit. 2
Flam. Liq. 3
Skin Irrit. 2
STOT SE 3 |
| | Bromomethyl methyl ether Usage And Synthesis |
| Chemical Properties | Colorless liquid | | Uses | Bromomethyl methyl ether is used as reagent for protection of OH groups as their methoxymethyl (MOM) ethers. It is used in enantiocontrolled synthesis of intermediate containing carbons 18 to 35 of the macrocyclic immunosuppressant FK-506. It was used in the synthesis of 1-methoxymethyl-4-tritylthio-2-azetidinone. | | Uses | Bromomethyl methyl ether was used in enantiocontrolled synthesis of intermediate containing carbons 18 to 35 of the macrocyclic immunosuppressant FK-506. It was used in the synthesis of 1-methoxymethyl-4-tritylthio-2-azetidinone. | | storage | Bromomethyl Methyl Ether (BMME) is a lachrymator, possible carcinogen, handle with care. Extremely
destructive to tissue of mucous membranes, eyes, and skin. Wear respirator, chemical-resistant gloves, and
safety goggles. |
| | Bromomethyl methyl ether Preparation Products And Raw materials |
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