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1073-67-2

1073-67-2 Structure

1073-67-2 Structure
IdentificationMore
[Name]

4-Chlorostyrene
[CAS]

1073-67-2
[Synonyms]

4-CHLOROSTYRENE
4-VINYLCHLOROBENZENE
CHLOROSTYRENE-4
P-CHLOROSTYRENE
1-chloro-4-ethenyl-benzen
1-chloro-4-ethenylbenzene
1-Chloro-4-vinylbenzene
4-chloro-styren
Benzene, 4-chloro-1-ethenyl-
benzene,1-chloro-4-ethenyl-
Parachlorostyrene
para-chlorostyrene
p-chloro-styren
Styrene, p-chloro-
styrene,p-chloro-
4-Chlorostyrene, stabilized, 99%
4-CHLOROSTYRENE , STABILIZED WITH 0.1% 4-TERT-BUTYLCATECHOL
4-CHLOROSTYRENE Stabilised with 0.1% 4-tert-butylcatechol
4-CHLOROSTYRENE, 99%, STAB.
4-Chlorostyrene (stabilized with TBC)
[EINECS(EC#)]

214-028-8
[Molecular Formula]

C8H7Cl
[MDL Number]

MFCD00000632
[Molecular Weight]

138.59
[MOL File]

1073-67-2.mol
Chemical PropertiesBack Directory
[Appearance]

CLEAR COLOURLESS TO SLIGHTLY YELLOW LIQUID
[Melting point ]

-16 °C
[Boiling point ]

192 °C(lit.)
[density ]

1.155 g/mL at 25 °C(lit.)
[vapor pressure ]

0.68 mm Hg ( 20 °C)
[refractive index ]

n20/D 1.565(lit.)
[Fp ]

140 °F
[storage temp. ]

2-8°C
[form ]

Liquid
[color ]

Clear colorless to slightly yellow
[Specific Gravity]

1.155
[Water Solubility ]

Immiscible with water.
[BRN ]

1098859
[CAS DataBase Reference]

1073-67-2(CAS DataBase Reference)
[NIST Chemistry Reference]

Benzene, 1-chloro-4-ethenyl-(1073-67-2)
[EPA Substance Registry System]

1073-67-2(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)Environment (GHS09)
GHS07,GHS09
[Signal word ]

Warning
[Hazard statements ]

H315-H411
[Precautionary statements ]

P264-P273-P280-P302+P352-P332+P313-P362+P364
[Hazard Codes ]

Xi,F
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S24/25:Avoid contact with skin and eyes .
S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[RIDADR ]

1993
[WGK Germany ]

3
[RTECS ]

CZ0533000
[TSCA ]

T
[HazardClass ]

3
[PackingGroup ]

III
[HS Code ]

29036990
[Hazardous Substances Data]

1073-67-2(Hazardous Substances Data)
[Toxicity]

LD50 orally in Rabbit: 5200 mg/kg
Raw materials And Preparation ProductsBack Directory
[Raw materials]

3-Buten-2-one, 4-(4-chlorophenyl)-, (3E)--->2-(4-Chlorophenyl)oxirane-->1-Chloro-4-(1,2-dibromoethyl)benzene-->4-Chlorocinnamic acid-->4-Chlorobenzyl bromide-->4-Chlorobenzyl chloride-->Benzeneethanesulfonylazide, 4-chloro--->6-Chloroindole-->5H-Cyclopenta[b]pyridine, 4-chloro-6,7-dihydro--->6-Chloro-2,3-dihydro-1H-indole
[Preparation Products]

3-[2-chloro-2-(4-chlorophenyl)ethenyl]-2,2-dimethyl cyclopropane carboxylic acid-->4-Chlorophenethylamine-->Diphenyl(p-vinylphenyl)phosphine-->p-Trimethylsilyl styrene-->3-(4-Chlorophenyl)propan-1-ol
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

p-Chlorostyrene(1073-67-2).msds
Hazard InformationBack Directory
[Chemical Properties]

CLEAR COLOURLESS TO SLIGHTLY YELLOW LIQUID
[Uses]

4-Chlorostyrene was used in the following studies:
  • Study of chemical and biochemical properties of the vinyl group of styrene by the development of structure activity relationships (SAR).
  • Preparation of new bis(pyrazolyl)borato olefin complexes of copper(I).
  • To investigate the regioselectivity in the cationic Heck reaction of 4-substituted styrenes.
[Uses]

4-Chlorostyrene is used in the preparation of new bis(pyrazolyl)borato olefin complexes of copper(I). It is also employed in the investigation of regioselectivity in the cationic Heck reaction of 4-substituted styrenes. Further, it plays an important role in the preparation of 4-[(4-chloro-phenyl)-thioacetyl]-morpholine.
[Preparation]

Synthesis of 4-chlorostyrene: carry out catalytic dehydration reaction by 4-chlorophenethylalcohol at 280°C, the used catalyst is a modified aluminum silicate catalyst, and the yield is 80%.
[Synthesis Reference(s)]

Journal of the American Chemical Society, 69, p. 852, 1947 DOI: 10.1021/ja01196a033
Tetrahedron Letters, 31, p. 5061, 1990 DOI: 10.1016/S0040-4039(00)97806-7
[General Description]

4-Chlorostyrene is a para-halogenated styrene derivative. It undergoes graft copolymerization with acrylonitrile (AN) onto ethylene-propylene-diene terpolymer (EPDM) in the presence of benzoyl peroxide (initiator).
Spectrum DetailBack Directory
[Spectrum Detail]

4-Chlorostyrene(1073-67-2)MS
4-Chlorostyrene(1073-67-2)1HNMR
4-Chlorostyrene(1073-67-2)13CNMR
4-Chlorostyrene(1073-67-2)IR1
4-Chlorostyrene(1073-67-2)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

4-Chlorostyrene, stabilized, 99%(1073-67-2)
[Alfa Aesar]

4-Chlorostyrene, 99%, stab.(1073-67-2)
[Sigma Aldrich]

1073-67-2(sigmaaldrich)
[TCI AMERICA]

4-Chlorostyrene  (stabilized with TBC),>98.0%(GC)(1073-67-2)
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