ChemicalBook--->CAS DataBase List--->33467-73-1

33467-73-1

33467-73-1 Structure

33467-73-1 Structure
IdentificationMore
[Name]

cis-3-Hexenyl formate
[CAS]

33467-73-1
[Synonyms]

BETA, GAMMA-HEXENYL METHANOATE
C3 HEXENYL FORMATE
CIS-3-HEXEN-1-YL FORMATE
CIS-3-HEXENYL FORMATE
FEMA 3353
FORMIC ACID CIS-3-HEXEN-1-YL ESTER
(Z)-3-HEXENOL FORMATE
(Z)-3-HEXENYL FORMATE
(3Z)-3-Hexenyl formate
(Z)-Hex-3-enyl formate
cis-.beta.-Hexenylformate
cis-3-Hexen-1-ol formate
cis-3-Hexen-1-olformate
cis-beta-Hexenyl Formate
formate,(z)-3-hexen-1-o
formate,(Z)-3-Hexen-1-ol
Formicacidhexenester
CIS-3-HEXENYL FORMATE 94+%
FORMIC ACID CIS-3-HEXEN-1-YL ESTER 90+%
3-Hexen-1-ol, formate, (3Z)-
[EINECS(EC#)]

251-532-7
[Molecular Formula]

C7H12O2
[MDL Number]

MFCD00036490
[Molecular Weight]

128.17
[MOL File]

33467-73-1.mol
Chemical PropertiesBack Directory
[Melting point ]

-62.68°C (estimate)
[Boiling point ]

72 °C/40 mmHg (lit.)
[density ]

0.91 g/mL at 25 °C(lit.)
[FEMA ]

3353
[refractive index ]

n20/D 1.426(lit.)
[Fp ]

113 °F
[solubility ]

Almost insoluble in water, soluble in alcohol, Propylene glycol and oils.
[form ]

liquid
[color ]

Colorless
[Specific Gravity]

0.92
[Odor]

at 10.00 % in dipropylene glycol. fresh green waxy sweet vegetable grassy sharp
[biological source]

synthetic
[Odor Type]

green
[JECFA Number]

1272
[Major Application]

flavors and fragrances
[Cosmetics Ingredients Functions]

PERFUMING
[InChI]

1S/C7H12O2/c1-2-3-4-5-6-9-7-8/h3-4,7H,2,5-6H2,1H3/b4-3-
[InChIKey]

XJHQVZQZUGLZLS-ARJAWSKDSA-N
[SMILES]

[H]C(=O)OCC\C([H])=C(\[H])CC
[LogP]

2.10
[CAS DataBase Reference]

33467-73-1(CAS DataBase Reference)
[NIST Chemistry Reference]

3-Hexen-1-ol, formate, (z)-(33467-73-1)
[EPA Substance Registry System]

33467-73-1(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R10:Flammable.
R36/38:Irritating to eyes and skin .
[Safety Statements ]

S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[RIDADR ]

UN 3272 3/PG 3
[WGK Germany ]

2
[RTECS ]

MP8550000
[TSCA ]

TSCA listed
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Eye Irrit. 2
Flam. Liq. 3
Skin Irrit. 2
Raw materials And Preparation ProductsBack Directory
[Raw materials]

(-)-Menthyl chloroformate-->Leaf alcohol
[Preparation Products]

2(3H)-Furanone, dihydro-3-propyl-
Hazard InformationBack Directory
[Description]

cis-3-Hexenyl formate has a light topnote and a fruity fresh odor.
[Chemical Properties]

(Z)-3-Hexenyl Formate has been identified in tea. It possesses a green, fruity odor and is used in perfumery and flavor compositions to impart fruity, green notes.
[Chemical Properties]

cis-3-Hexneyl formate has a light top note and a fruity fresh odor.
[Occurrence]

Reported found in raspberry, corn mint oil, black tea, mango, corn oil and black chokeberry.
[Uses]

cis-3-Hexenyl formate finds some use in perfumery as part of various topnote complexes. It blends very well with Galbanum and with many herbaceous oils. Styrax is a good fixative, and supporting fixation and blending can be achieved with Cinnamates. The ester could constitute the main part of the green theme in Hyacinth when suitably incorporated. In flavors, it forms an excellent combination with Nonadienal and Nonadienol in Cucumber compositions and other vegetable, juicygreen flavor types. It is furthermore a generally refreshing modifier for the higher esters of the series.
[Definition]

ChEBI:Cis-3-Hexenyl formate is a carboxylic ester.
[Preparation]

from cis-3-Hexenol and Formic acid, e. g. in presence of Acetic arrhydride in cold Formulation.
[Taste threshold values]

Taste characteristics at 20 ppm: green, waxy, fresh, vegetable, fruity, apple, guava and green banana
[General Description]

cis-3-Hexenyl formate is a flavor and fragrance ester mainly used for its green notes. It occurs naturally in gardenia and zinchoge flowers.
Spectrum DetailBack Directory
[Spectrum Detail]

cis-3-Hexenyl formate(33467-73-1)FT-IR
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

33467-73-1(sigmaaldrich)
[TCI AMERICA]

Formic Acid cis-3-Hexen-1-yl Ester,>90.0%(GC)(33467-73-1)
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