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cis-3-Hexenyl formate

CAS No.
33467-73-1
Chemical Name:
cis-3-Hexenyl formate
Synonyms
FEMA 3353;(Z)-3-HEXENYL FORMATE;FORMIC ACID CIS-3-HEXEN-1-YL ESTER;C3 HEXENYL FORMATE;3Z-Hexenyl Formate;HEXENYLFORMIAT-CIS-3;Formicacidhexenester;Leaf alcohol formate;(Z)-Hex-3-enylformiat;(Z)-3-HEXENOL FORMATE
CBNumber:
CB0190859
Molecular Formula:
C7H12O2
Molecular Weight:
128.17
MDL Number:
MFCD00036490
MOL File:
33467-73-1.mol
MSDS File:
SDS
Last updated:2026-05-27 17:21:32

cis-3-Hexenyl formate Properties

Melting point -62.68°C (estimate)
Boiling point 72 °C/40 mmHg (lit.)
Density 0.91 g/mL at 25 °C(lit.)
FEMA 3353 | CIS-3-HEXENYL FORMATE
refractive index n20/D 1.426(lit.)
FLAVIS Number 09.240 | Hex-3(cis)-enyl formate
Flash point 113 °F
solubility Almost insoluble in water, soluble in alcohol, Propylene glycol and oils.
form liquid
Specific Gravity 0.92
color Colorless
Odor at 10.00 % in dipropylene glycol. fresh green waxy sweet vegetable grassy sharp
Odor Type green
biological source synthetic
JECFA Number 1272
Major Application flavors and fragrances
Cosmetics Ingredients Functions PERFUMING
InChI 1S/C7H12O2/c1-2-3-4-5-6-9-7-8/h3-4,7H,2,5-6H2,1H3/b4-3-
InChIKey XJHQVZQZUGLZLS-ARJAWSKDSA-N
SMILES [H]C(=O)OCC\C([H])=C(\[H])CC
LogP 2.10
CAS DataBase Reference 33467-73-1(CAS DataBase Reference)
Substances Added to Food (formerly EAFUS) CIS-3-HEXENYL FORMATE
EWG's Food Scores 1
FDA UNII E34OB83TYM
NIST Chemistry Reference 3-Hexen-1-ol, formate, (z)-(33467-73-1)
EPA Substance Registry System 3-Hexen-1-ol, formate, (3Z)- (33467-73-1)
UNSPSC Code 12164502
NACRES NA.21

SAFETY

Risk and Safety Statements

Symbol(GHS)  Flame (GHS02)Exclamation Mark (GHS07)
GHS02,GHS07
Signal word  Warning
Hazard statements  H226-H315-H319
Precautionary statements  P210-P302+P352-P305+P351+P338
PPE Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  Xi
Risk Statements  10-36/38
Safety Statements  16-26-36
RIDADR  UN 3272 3/PG 3
WGK Germany  2
RTECS  MP8550000
TSCA  TSCA listed
Storage Class 3 - Flammable liquids
Hazard Classifications Eye Irrit. 2
Flam. Liq. 3
Skin Irrit. 2

cis-3-Hexenyl formate price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
aablocks AA003OVV cis-3-Hexenyl formate ≥97% 33467-73-1 5g $21 2026-05-28 Buy
aablocks AA003OVV cis-3-Hexenyl formate ≥97% 33467-73-1 25g $68 2026-05-28 Buy
aablocks AA003OVV cis-3-Hexenyl formate ≥97% 33467-73-1 100g $149 2026-05-28 Buy
American Custom Chemicals Corporation FFG0000089 CIS-3-HEXENYL FORMATE 95.00% 33467-73-1 100G $2488.56 2021-12-16 Buy
American Custom Chemicals Corporation FFG0000089 CIS-3-HEXENYL FORMATE 95.00% 33467-73-1 1KG $7090.95 2021-12-16 Buy
Product number Packaging Price Buy
AA003OVV 5g $21 Buy
AA003OVV 25g $68 Buy
AA003OVV 100g $149 Buy
FFG0000089 100G $2488.56 Buy
FFG0000089 1KG $7090.95 Buy

cis-3-Hexenyl formate Chemical Properties,Uses,Production

Description

cis-3-Hexenyl formate has a light topnote and a fruity fresh odor.

Chemical Properties

cis-3-Hexneyl formate has a light top note and a fruity fresh odor.

Chemical Properties

(Z)-3-Hexenyl Formate has been identified in tea. It possesses a green, fruity odor and is used in perfumery and flavor compositions to impart fruity, green notes.

Occurrence

Reported found in raspberry, corn mint oil, black tea, mango, corn oil and black chokeberry.

Uses

cis-3-Hexenyl formate finds some use in perfumery as part of various topnote complexes. It blends very well with Galbanum and with many herbaceous oils. Styrax is a good fixative, and supporting fixation and blending can be achieved with Cinnamates. The ester could constitute the main part of the green theme in Hyacinth when suitably incorporated. In flavors, it forms an excellent combination with Nonadienal and Nonadienol in Cucumber compositions and other vegetable, juicygreen flavor types. It is furthermore a generally refreshing modifier for the higher esters of the series.

Preparation

from cis-3-Hexenol and Formic acid, e. g. in presence of Acetic arrhydride in cold Formulation.

Definition

ChEBI: Cis-3-Hexenyl formate is a carboxylic ester.

Taste threshold values

Taste characteristics at 20 ppm: green, waxy, fresh, vegetable, fruity, apple, guava and green banana

General Description

cis-3-Hexenyl formate is a flavor and fragrance ester mainly used for its green notes. It occurs naturally in gardenia and zinchoge flowers.

cis-3-Hexenyl formate Preparation Products And Raw materials

Global( 162)Suppliers
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
3B Pharmachem (Wuhan) International Co.,Ltd. 18930552037 3bsc@sina.com China 15813 69
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
jiliang chemicals 21-62165282 bidingchem@163.com China 1395 60
Beijing Isomersyn Technology CO;LTD 010-82954736 13391601435 sales@isomersyn.com China 3294 57
Syntechem Co.,Ltd info@syntechem.com China 12973 57
Sichuan Kulinan Technology Co., Ltd 400-1166-196 18981987031 cdhxsj@163.com China 11674 57
Chengdu Ai Keda Chemical Technology Co., Ltd. 4008-755-333 18080918076 800078821@qq.com China 9706 55
Shanghai Meishui Chemical Technology Co., Ltd 021-60549325 18616193163 China 4518 56
Shanghai JONLN Reagent Co., Ltd. 400-0066400 13621662912 422131432@qq.com China 9970 55

View Lastest Price from cis-3-Hexenyl formate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
cis-3-Hexenyl formate pictures 2025-05-23 cis-3-Hexenyl formate
33467-73-1
$60.00 1kg 99% 20 tons Hebei Zhuanglai Chemical Trading Co Ltd
cis-3-Hexenyl formate pictures 2024-07-22 cis-3-Hexenyl formate
33467-73-1
1kg 98% 10ton JINING XINHE CHEMICAL CO., LTD
cis-3-Hexenyl formate pictures 2021-08-12 cis-3-Hexenyl formate
33467-73-1
$10.00-15.00 1KG 99%+ HPLC Zhuozhou Wenxi import and Export Co., Ltd

cis-3-Hexenyl formate Spectrum

BETA, GAMMA-HEXENYL METHANOATE C3 HEXENYL FORMATE FORMIC ACID CIS-3-HEXEN-1-YL ESTER CIS-3-HEXEN-1-YL FORMATE CIS-3-HEXENYL FORMATE (Z)-3-HEXENOL FORMATE 3-Hexen-1-ol, formate, (3Z)- (Z)-Hex-3-enylformiat HEXENYLFORMIAT-CIS-3 CIS-3-HEXENYL FORMATE NATURAL (Z)-3-Hexene-1-ol formate Formic acid (Z)-3-hexenyl ester Formic acid cis-3-hexenyl ester (Z)-3-hexen-1-yl formate (Z)-hex-3-en-1-yl forMate Natural cis-3-Hexenyl formate (3Z)-3-Hexenyl formate (Z)-Hex-3-enyl formate cis-.beta.-Hexenylformate cis-3-Hexen-1-ol formate cis-3-Hexen-1-olformate cis-beta-Hexenyl Formate formate,(z)-3-hexen-1-o formate,(Z)-3-Hexen-1-ol FORMIC ACID CIS-3-HEXEN-1-YL ESTER 90+% Formicacidhexenester CIS-3-HEXENYL FORMATE 94+% 3-Hexen-1-ol, 1-formate, (3Z)- cis-3-Hexenyl formate USP/EP/BP cis-3-Hexenyl formate(kosher) 3Z-Hexenyl Formate (3Z)-3-Hexen-1-yl formate cis-3-Hexenyl formate Leaf alcohol formate (Z)-3-HEXENYL FORMATE FEMA 3353 3-Hexen-1-ol, formate, (Z)- 33467-73-1 HCO2CH2CH2CHCHC2H5 Alphabetical Listings Flavors and Fragrances G-H