cis-3-Hexenyl formate
- CAS No.
- 33467-73-1
- Chemical Name:
- cis-3-Hexenyl formate
- Synonyms
- FEMA 3353;(Z)-3-HEXENYL FORMATE;FORMIC ACID CIS-3-HEXEN-1-YL ESTER;C3 HEXENYL FORMATE;3Z-Hexenyl Formate;HEXENYLFORMIAT-CIS-3;Formicacidhexenester;Leaf alcohol formate;(Z)-Hex-3-enylformiat;(Z)-3-HEXENOL FORMATE
- CBNumber:
- CB0190859
- Molecular Formula:
- C7H12O2
- Molecular Weight:
- 128.17
- MDL Number:
- MFCD00036490
- MOL File:
- 33467-73-1.mol
- MSDS File:
- SDS
| Melting point | -62.68°C (estimate) |
|---|---|
| Boiling point | 72 °C/40 mmHg (lit.) |
| Density | 0.91 g/mL at 25 °C(lit.) |
| FEMA | 3353 | CIS-3-HEXENYL FORMATE |
| refractive index |
n |
| FLAVIS Number | 09.240 | Hex-3(cis)-enyl formate |
| Flash point | 113 °F |
| solubility | Almost insoluble in water, soluble in alcohol, Propylene glycol and oils. |
| form | liquid |
| Specific Gravity | 0.92 |
| color | Colorless |
| Odor | at 10.00 % in dipropylene glycol. fresh green waxy sweet vegetable grassy sharp |
| Odor Type | green |
| biological source | synthetic |
| JECFA Number | 1272 |
| Major Application | flavors and fragrances |
| Cosmetics Ingredients Functions | PERFUMING |
| InChI | 1S/C7H12O2/c1-2-3-4-5-6-9-7-8/h3-4,7H,2,5-6H2,1H3/b4-3- |
| InChIKey | XJHQVZQZUGLZLS-ARJAWSKDSA-N |
| SMILES | [H]C(=O)OCC\C([H])=C(\[H])CC |
| LogP | 2.10 |
| CAS DataBase Reference | 33467-73-1(CAS DataBase Reference) |
| Substances Added to Food (formerly EAFUS) | CIS-3-HEXENYL FORMATE |
| EWG's Food Scores | 1 |
| FDA UNII | E34OB83TYM |
| NIST Chemistry Reference | 3-Hexen-1-ol, formate, (z)-(33467-73-1) |
| EPA Substance Registry System | 3-Hexen-1-ol, formate, (3Z)- (33467-73-1) |
| UNSPSC Code | 12164502 |
| NACRES | NA.21 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() ![]() GHS02,GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H226-H315-H319 |
| Precautionary statements | P210-P302+P352-P305+P351+P338 |
| PPE | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter |
| Hazard Codes | Xi |
| Risk Statements | 10-36/38 |
| Safety Statements | 16-26-36 |
| RIDADR | UN 3272 3/PG 3 |
| WGK Germany | 2 |
| RTECS | MP8550000 |
| TSCA | TSCA listed |
| Storage Class | 3 - Flammable liquids |
| Hazard Classifications | Eye Irrit. 2 Flam. Liq. 3 Skin Irrit. 2 |
cis-3-Hexenyl formate price More Price(5)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| aablocks | AA003OVV | cis-3-Hexenyl formate ≥97% | 33467-73-1 | 5g | $21 | 2026-05-28 | Buy |
| aablocks | AA003OVV | cis-3-Hexenyl formate ≥97% | 33467-73-1 | 25g | $68 | 2026-05-28 | Buy |
| aablocks | AA003OVV | cis-3-Hexenyl formate ≥97% | 33467-73-1 | 100g | $149 | 2026-05-28 | Buy |
| American Custom Chemicals Corporation | FFG0000089 | CIS-3-HEXENYL FORMATE 95.00% | 33467-73-1 | 100G | $2488.56 | 2021-12-16 | Buy |
| American Custom Chemicals Corporation | FFG0000089 | CIS-3-HEXENYL FORMATE 95.00% | 33467-73-1 | 1KG | $7090.95 | 2021-12-16 | Buy |
cis-3-Hexenyl formate Chemical Properties,Uses,Production
Description
cis-3-Hexenyl formate has a light topnote and a fruity fresh odor.
Chemical Properties
cis-3-Hexneyl formate has a light top note and a fruity fresh odor.
Chemical Properties
(Z)-3-Hexenyl Formate has been identified in tea. It possesses a green, fruity odor and is used in perfumery and flavor compositions to impart fruity, green notes.
Occurrence
Reported found in raspberry, corn mint oil, black tea, mango, corn oil and black chokeberry.
Uses
cis-3-Hexenyl formate finds some use in perfumery as part of various topnote complexes. It blends very well with Galbanum and with many herbaceous oils. Styrax is a good fixative, and supporting fixation and blending can be achieved with Cinnamates. The ester could constitute the main part of the green theme in Hyacinth when suitably incorporated. In flavors, it forms an excellent combination with Nonadienal and Nonadienol in Cucumber compositions and other vegetable, juicygreen flavor types. It is furthermore a generally refreshing modifier for the higher esters of the series.
Preparation
from cis-3-Hexenol and Formic acid, e. g. in presence of Acetic arrhydride in cold Formulation.
Definition
ChEBI: Cis-3-Hexenyl formate is a carboxylic ester.
Taste threshold values
Taste characteristics at 20 ppm: green, waxy, fresh, vegetable, fruity, apple, guava and green banana
General Description
cis-3-Hexenyl formate is a flavor and fragrance ester mainly used for its green notes. It occurs naturally in gardenia and zinchoge flowers.
cis-3-Hexenyl formate Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| 3B Pharmachem (Wuhan) International Co.,Ltd. | 18930552037 | 3bsc@sina.com | China | 15813 | 69 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| jiliang chemicals | 21-62165282 | bidingchem@163.com | China | 1395 | 60 |
| Beijing Isomersyn Technology CO;LTD | 010-82954736 13391601435 | sales@isomersyn.com | China | 3294 | 57 |
| Syntechem Co.,Ltd | info@syntechem.com | China | 12973 | 57 | |
| Sichuan Kulinan Technology Co., Ltd | 400-1166-196 18981987031 | cdhxsj@163.com | China | 11674 | 57 |
| Chengdu Ai Keda Chemical Technology Co., Ltd. | 4008-755-333 18080918076 | 800078821@qq.com | China | 9706 | 55 |
| Shanghai Meishui Chemical Technology Co., Ltd | 021-60549325 18616193163 | China | 4518 | 56 | |
| Shanghai JONLN Reagent Co., Ltd. | 400-0066400 13621662912 | 422131432@qq.com | China | 9970 | 55 |
View Lastest Price from cis-3-Hexenyl formate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2025-05-23 | cis-3-Hexenyl formate
33467-73-1
|
$60.00 | 1kg | 99% | 20 tons | Hebei Zhuanglai Chemical Trading Co Ltd | |
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2024-07-22 | cis-3-Hexenyl formate
33467-73-1
|
1kg | 98% | 10ton | JINING XINHE CHEMICAL CO., LTD | ||
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2021-08-12 | cis-3-Hexenyl formate
33467-73-1
|
$10.00-15.00 | 1KG | 99%+ HPLC | Zhuozhou Wenxi import and Export Co., Ltd |
-

- cis-3-Hexenyl formate
33467-73-1
- $60.00
- 99%
- Hebei Zhuanglai Chemical Trading Co Ltd
-

- cis-3-Hexenyl formate
33467-73-1
- 98%
- JINING XINHE CHEMICAL CO., LTD
-

- cis-3-Hexenyl formate
33467-73-1
- $10.00-15.00
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
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