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Methyl 5-fluoro-2-methylbenzoate

CAS No.
175278-29-2
Chemical Name:
Methyl 5-fluoro-2-methylbenzoate
Synonyms
METHYL 5-FLUORO-2-METHYLBENZOATE;RARECHEM AL BF 0505;5-fluoro-2-methylbenzoate;METHYL 2-METHYL-5-FLUOROBENZOATE;Benzoic acid, 5-fluoro-2-methyl-, methyl ester
CBNumber:
CB0334796
Molecular Formula:
C9H9FO2
Molecular Weight:
168.16
MDL Number:
MFCD00221457
MOL File:
175278-29-2.mol
MSDS File:
SDS
Last updated:2026-05-27 17:37:24

Methyl 5-fluoro-2-methylbenzoate Properties

Boiling point 90-92°C 15mm
Density 1.137±0.06 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
form liquid
color Brown

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P271-P261-P280
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
Hazard Note  Irritant
HS Code  2916399090

Methyl 5-fluoro-2-methylbenzoate price More Price(47)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Apolloscientific PC5114D Methyl 5-fluoro-2-methylbenzoate ≥95% 175278-29-2 5g $21 2026-06-04 Buy
Apolloscientific PC5114D Methyl 5-fluoro-2-methylbenzoate ≥95% 175278-29-2 25g $28 2026-06-04 Buy
Apolloscientific PC5114D Methyl 5-fluoro-2-methylbenzoate ≥95% 175278-29-2 100g $82 2026-06-04 Buy
Activate Scientific AS33250 Methyl 5-fluoro-2-methylbenzoate 98% 175278-29-2 25g $26 2026-06-04 Buy
Activate Scientific AS33250 Methyl 5-fluoro-2-methylbenzoate 98% 175278-29-2 100g $52 2026-06-04 Buy
Product number Packaging Price Buy
PC5114D 5g $21 Buy
PC5114D 25g $28 Buy
PC5114D 100g $82 Buy
AS33250 25g $26 Buy
AS33250 100g $52 Buy

Methyl 5-fluoro-2-methylbenzoate Chemical Properties, Uses, Production

Uses

Methyl 5-fluoro-2-methylbenzoate was used for the preparation of derivatives of piperidinedione.

Synthesis

5-Fluoro-2-methylbenzoic acid

33184-16-6

Iodomethane

74-88-4

Methyl 5-fluoro-2-methylbenzoate

175278-29-2

5-Fluoro-2-methylbenzoic acid (2.3 g) was dissolved in tetrahydrofuran (THF, 50 ml). To the solution, iodomethane (0.95 ml) and N,N-diisopropylethylamine (3.2 ml) were added sequentially. The reaction mixture was stirred at room temperature for 2 hours. After completion of the reaction, the mixture was filtered and the filtrate concentrated to give methyl 5-fluoro-2-methylbenzoate (2.3 g; 90% yield).1H-NMR (CDCl3) δ: 2.6 (s, 3H), 3.9 (s, 3H), 7.0-7.2 (m, 2H), 7.6-7.7 (m, 1H).

References

[1] Bioorganic and Medicinal Chemistry Letters, 2010, vol. 20, # 17, p. 5286 - 5289
[2] Patent: WO2006/116157, 2006, A2. Location in patent: Page/Page column 83-84

Global Suppliers ( 119)
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J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Beijing Ouhe Technology Co., Ltd 13552068683 13522913783 2355560935@qq.com China 11775 60
JinYan Chemicals(ShangHai) Co.,Ltd. 13817811078 sales@jingyan-chemical.com China 9963 60
Shanghai Sinch Parmaceuticals Tech. Co. Ltd. +86-21-54098501 sales@sinch.com.cn China 11592 64
Changzhou Huanling Chemical Co., Ltd. 89803005 18206112582 info@huanlingchem.com China 983 68
Jia Xing Isenchem Co.,Ltd 0573-85285100 18627885956 isenchem@163.com China 9388 66
Adamas Reagent, Ltd. 4006009262 13023226327 hmj@titansci.com China 14098 59
Accela ChemBio Co.,Ltd. 4000665055 marketing@accelachem.com China 10972 64
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Tianjin Jinyuda Chemical Co., Ltd. 022-58013646 13011382049 sales@jinyudachem.com China 1976 55

View Latest Price from Methyl 5-fluoro-2-methylbenzoate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
METHYL 2-METHYL-5-FLUOROBENZOATE pictures 2020-02-14 METHYL 2-METHYL-5-FLUOROBENZOATE
175278-29-2
$7.00 1KG 99% 100KG Career Henan Chemical Co

Methyl 5-fluoro-2-methylbenzoate Spectrum

RARECHEM AL BF 0505 METHYL 2-METHYL-5-FLUOROBENZOATE METHYL 5-FLUORO-2-METHYLBENZOATE 5-fluoro-2-methylbenzoate Benzoic acid, 5-fluoro-2-methyl-, methyl ester 175278-29-2