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Methyl 5-fluoro-2-methylbenzoate

Methyl 5-fluoro-2-methylbenzoate structure

CAS No.: 175278-29-2

Chemical Name:: Methyl 5-fluoro-2-methylbenzoate

Synonyms: METHYL 5-FLUORO-2-METHYLBENZOATE;RARECHEM AL BF 0505;5-fluoro-2-methylbenzoate;METHYL 2-METHYL-5-FLUOROBENZOATE;Benzoic acid, 5-fluoro-2-methyl-, methyl ester

CBNumber:: CB0334796

Molecular Formula:: C9H9FO2

Molecular Weight:: 168.16

MDL Number:: MFCD00221457

MOL File:: 175278-29-2.mol

MSDS File:: SDS

Last updated:2025-08-08 17:45:00

Product description	Number	Pack Size	Price
Methyl5-Fluoro-2-MethylBenzoate	M219378	10mg	$45
Methyl 5-fluoro-2-methylbenzoate 95+%	075697	1g	$70
Methyl5-fluoro-2-methylbenzoate	X2218	5g	$83
Methyl 5-fluoro-2-methylbenzoate 97%	2723-3-25	25g	$85
Methyl5-fluoro-2-methylbenzoate	PC5114D	25g	$85
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Methyl 5-fluoro-2-methylbenzoate Properties

Boiling point	90-92°C 15mm
Density	1.137±0.06 g/cm3(Predicted)
storage temp.	Sealed in dry,Room Temperature
form	liquid
color	Brown

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H302-H315-H319-H335
Precautionary statements	P271-P261-P280
Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36
Hazard Note	Irritant
HS Code	2916399090

Methyl 5-fluoro-2-methylbenzoate price More Price(31)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
TRC	M219378	Methyl5-Fluoro-2-MethylBenzoate	175278-29-2	10mg	$45	2021-12-16	Buy
Matrix Scientific	075697	Methyl 5-fluoro-2-methylbenzoate 95+%	175278-29-2	1g	$70	2021-12-16	Buy
AK Scientific	X2218	Methyl5-fluoro-2-methylbenzoate	175278-29-2	5g	$83	2021-12-16	Buy
SynQuest Laboratories	2723-3-25	Methyl 5-fluoro-2-methylbenzoate 97%	175278-29-2	25g	$85	2021-12-16	Buy
Apolloscientific	PC5114D	Methyl5-fluoro-2-methylbenzoate	175278-29-2	25g	$85	2021-12-16	Buy

Product number	Packaging	Price	Buy
M219378	10mg	$45	Buy
075697	1g	$70	Buy
X2218	5g	$83	Buy
2723-3-25	25g	$85	Buy
PC5114D	25g	$85	Buy

Methyl 5-fluoro-2-methylbenzoate Chemical Properties,Uses,Production

Uses

Methyl 5-fluoro-2-methylbenzoate was used for the preparation of derivatives of piperidinedione.

Synthesis

33184-16-6

74-88-4

175278-29-2

5-Fluoro-2-methylbenzoic acid (2.3 g) was dissolved in tetrahydrofuran (THF, 50 ml). To the solution, iodomethane (0.95 ml) and N,N-diisopropylethylamine (3.2 ml) were added sequentially. The reaction mixture was stirred at room temperature for 2 hours. After completion of the reaction, the mixture was filtered and the filtrate concentrated to give methyl 5-fluoro-2-methylbenzoate (2.3 g; 90% yield).1H-NMR (CDCl3) δ: 2.6 (s, 3H), 3.9 (s, 3H), 7.0-7.2 (m, 2H), 7.6-7.7 (m, 1H).

References

[1] Bioorganic and Medicinal Chemistry Letters, 2010, vol. 20, # 17, p. 5286 - 5289
[2] Patent: WO2006/116157, 2006, A2. Location in patent: Page/Page column 83-84

Methyl 5-fluoro-2-methylbenzoate Preparation Products And Raw materials

Raw materials

Methanol 5-Fluoro-2-methylbenzoic acid Iodomethane N,N-Diisopropylethylamine Tetrahydrofuran

Preparation Products

6-Fluoro-1H-indole-4-carboxylic acid methyl ester methyl 3-bromo-5-fluoro-2-methylbenzoate

Methyl 5-fluoro-2-methylbenzoate Suppliers

Global( 123)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Capot Chemical Co.,Ltd.	+86-（0）57185586718; +8613336195806	sales@capot.com	China	29735	60
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	33024	60
Changzhou Ansciep Chemical Co., Ltd.	+86 519 86305871	sales@ansciepchem.com	CHINA	4241	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49977	58
career henan chemical co	+86-0371-86658258 +8613203830695	factory@coreychem.com	China	29796	58
Fuxin Pharmaceutical	+86-021-021-50872116 +8613122107989	contact@fuxinpharm.com	China	9999	58
SIMAGCHEM CORP	+86-5922680277 +86-13806087780	sale@simagchem.com	China	17346	58
Win-Win chemical CO., Limited	+86-0086-577-64498589 +86-15355981851	sales@win-winchemical.com	China	14358	58
Hefei Hirisun Pharmatech Co., Ltd	+8615056975894	shawn@hirisunpharm.com	CHINA	9911	58

Supplier	Advantage
Capot Chemical Co.,Ltd.	60
ATK CHEMICAL COMPANY LIMITED	60
Changzhou Ansciep Chemical Co., Ltd.	58
Alchem Pharmtech,Inc.	58
CONIER CHEM AND PHARMA LIMITED	58
career henan chemical co	58
Fuxin Pharmaceutical	58
SIMAGCHEM CORP	58
Win-Win chemical CO., Limited	58
Hefei Hirisun Pharmatech Co., Ltd	58

View Lastest Price from Methyl 5-fluoro-2-methylbenzoate manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2020-02-14	METHYL 2-METHYL-5-FLUOROBENZOATE 175278-29-2	US $7.00 / KG	1KG	99%	100KG	Career Henan Chemical Co

METHYL 2-METHYL-5-FLUOROBENZOATE
175278-29-2
US $7.00 / KG
99%
Career Henan Chemical Co

Methyl 5-fluoro-2-methylbenzoate Spectrum

Methyl 5-fluoro-2-methylbenzoate(175278-29-2)¹HNMR

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RARECHEM AL BF 0505 METHYL 2-METHYL-5-FLUOROBENZOATE METHYL 5-FLUORO-2-METHYLBENZOATE 5-fluoro-2-methylbenzoate Benzoic acid, 5-fluoro-2-methyl-, methyl ester 175278-29-2