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Benzoximate

CAS No.
29104-30-1
Chemical Name:
Benzoximate
Synonyms
na-53;NA 53M;ARTABAN;azomate;CITRAZON;Aazomate;ACARMATE;Citrastar;BENZOMATE;BENZOXIMATE
CBNumber:
CB0348313
Molecular Formula:
C18H18ClNO5
Molecular Weight:
363.79
MDL Number:
MFCD00055458
MOL File:
29104-30-1.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-07-31 15:25:14

Benzoximate Properties

Melting point 73℃
Boiling point 483.3±55.0 °C(Predicted)
Density 1.21
storage temp. 0-6°C
solubility DMSO (Slightly), Methanol, (Slightly)
form Solid
color White to Off-White
Water Solubility 30.26mg/L(temperature not stated)
Henry's Law Constant 1.8×102 mol/(m3Pa) at 25℃, Duchowicz et al. (2020)
CAS DataBase Reference 29104-30-1
FDA UNII 32TAI9ZK5N
EPA Substance Registry System Benzomate (29104-30-1)

SAFETY

Risk and Safety Statements

Hazard statements  H412
Precautionary statements  P273-P501
RTECS  DF9700000
HS Code  29280000

Benzoximate price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC B207755 Benzoximate 29104-30-1 25mg $155 2021-12-16 Buy
American Custom Chemicals Corporation AGR0000123 BENZOMATE 95.00% 29104-30-1 5MG $499.27 2021-12-16 Buy
Product number Packaging Price Buy
B207755 25mg $155 Buy
AGR0000123 5MG $499.27 Buy

Benzoximate Chemical Properties, Uses, Production

Description

Benzoximate is an acaricide used to control all stages of spider mites on pome fruit, stone fruit, citrus fruit, vines and ornamentals. It was commercialized in Japan in 1971 but discontinued there in 1998 and is currently registered only in Italy, South Korea, South Africa and Switzerland.

Chemical Properties

Pure product is white crystal. m.p. 73℃, vapor pressure <1.33×10-2Pa (4.53×10-4Pa (25℃). solubility at 20℃: benzene 650g/L, dimethylformamide 1460g/L, xylene 710g/L (1296g/L), ethanol 70g/L (93g/L), hexane 8g/L, acetone 980g /L (1440g/L); almost insoluble in water. Stable to acid, easy to decompose in strong alkali medium, decomposition or isomerization at about 80℃.

Uses

Benzoximate is an acaricide that inhibits fruit tree red spider mite Panonychys ulmi (Koch)[1].

Production Methods

While detailed production steps are not widely published for benzoximate due to its obsolete status, its synthesis generally involves constructing a bridged diphenyl structure with functional groups that confer contact and stomach toxicity to mites. The molecule includes a chlorinated aromatic ring and ester functionalities, suggesting that its production likely involves electrophilic aromatic substitution, esterification, and condensation reactions to form the final active compound.

Mode of action

The mode of action of benzoximate is not known. Resistance has been reported in citrus red mite, European red mite and twospotted spider mite.

Toxicity evaluation

Benzoximate is relatively non-toxic to mammals and fish, but is moderately toxic to predatory mites.

References

[1] Kim YJ, et al. Multiple resistance and biochemical mechanisms of pyridaben resistance in Tetranychus urticae (Acari: Tetranychidae). J Econ Entomol. 2006 Jun;99(3):954-8. DOI:10.1603/0022-0493-99.3.954

Pesticide Type

Acaricide; Miticide

Benzoximate Preparation Products And Raw materials

Raw materials

Preparation Products

Benzoximate Suppliers

Global Suppliers ( 79)
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Sichuan Kulinan Technology Co., Ltd 400-1166-196 18981987031 cdhxsj@163.com China 11674 57
Nanjing Sunlida Biological Technology Co., Ltd. 025-57798810 18652991625 sales@sunlidabio.com China 3223 55
Shanghai JONLN Reagent Co., Ltd. 400-0066400 13621662912 422131432@qq.com China 9970 55
Alta Scientific Co., Ltd. 022-6537-8550 15522853686 sales@altasci.com.cn China 4508 55
Shanghai Xilong Biochemical Technology Co., Ltd. 021-52907766-8042 China 9928 58
Shanghai YuanYe Biotechnology Co., Ltd. 15026964105 2881489226@qq.com China 89667 60
Shandong Xiya Chemical Co., Ltd. 4009903999 13395398332 sales@xiyashiji.com China 20788 60
Raw material medicin reagent co.,Ltd sales@njromanme.com China 4511 58
Shandong Ono Chemical Co., Ltd. 0539-6362799 20) China 10007 58

View Latest Price from Benzoximate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Benzoximate pictures 2020-04-28 Benzoximate
29104-30-1
1KG 99.0% 500 tons Shaanxi Dideu Medichem Co. Ltd
BENZOXIMATE pictures 2020-01-01 BENZOXIMATE
29104-30-1
$1.00 1KG 95-99% 1ton Career Henan Chemical Co
  • Benzoximate pictures
  • Benzoximate
    29104-30-1
  • 99.0%
  • Shaanxi Dideu Medichem Co. Ltd
  • BENZOXIMATE pictures
  • BENZOXIMATE
    29104-30-1
  • $1.00
  • 95-99%
  • Career Henan Chemical Co
ETHYL-O-BENZOYL-3-CHLORO-2,6-DIMETHOXY-BENZOHYDROXIMATE CITRAZON 3-chloro-2,6-dimethoxyl-α-ethoxyimino benzyl benzoate Benzoic acid 3-chloro-α-ethoxyimino-2,6-dimethoxybenzyl Benzoic acid 3-chloro-α-ethoxyimino-2,6-dimethoxybenzyl ester 3-CHLORO-ALPHA-ETHOXYIMINO-2,6-DIMETHOXYBENZYLBENZOATE Benzomate standard Aazomate Benzoic acid anhydride with 3-chloro-N-ethoxy-2,6-dimethoxybenzenecarboximidic acid Ethyl O-benzoyl-3-chloro-2,6-dimethoxybenzohydroxamate Benzoximate Solution, 1000ppm BENZOXIMATE PESTANAL(3-CHLORO-A-ETHOXIM& benzomate (jmaf) benzoximate (bsi,iso) Citrastar NA 53M BENZOMATE BENZOXIMATE ARTABAN azomate benzoic3-chloro-n-ethoxy-2,6-dimethoxybenzimidicanhydride benzoicacid,anhydridewith3-chloro-n-ethoxy-2,6-dimethoxybenzimidicacid benzoxamate na-53 o-benzoyl-3-chloro-2,6-dimethoxy-n-ethyl-benzohydroxamicaci BENZOXIMATE PESTANAL ACARMATE Benzoximate@1000 μg/mL in Acetonitrile Benzoximate 10.0 μg/ml Acetonitrile C10540000 Benzoximate Benzoximate in Acetonitrile Indacaterol Impurity 62 29104-30-1 C18H18CINO5 C18H8ClNO5 A-BPesticides&Metabolites AcaricidesAlphabetic Alpha sort B BA - BH Pesticides Pesticides&Metabolites