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(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl)

(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl) structure

CAS No.: 174810-09-4

Chemical Name:: (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl)

Synonyms: CAS:174810-09-4;(R,R)-TROST LIGAND(NAPHTHYL);(R,R)-DACH-naphthyl Trost ligand;(R,R)-DACH-naphthyl Trost ligand 95%;(R,R)-DACH-naphthyl Trost ligand;(1R,2R)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosph...;N,N'-((1R,2R)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthamide);(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl);(1R,2R)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),94%;N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphino)-1-naphthalenecarboxamide

CBNumber:: CB0725802

Molecular Formula:: C52H44N2O2P2

Molecular Weight:: 790.87

MDL Number:: MFCD02684551

MOL File:: 174810-09-4.mol

MSDS File:: SDS

Last updated:2026-09-12 18:48:28

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(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl) Properties

Melting point	224-231 °C
alpha	69o (C=1 IN METHANOL)
storage temp.	2-8°C, protect from light, stored under nitrogen
form	Powder
pka	13.43±0.40(Predicted)
color	off-white
optical activity	[α]20/D +69.0°, c = 1 in methanol
InChIKey	VXFKMKXTPXVEMU-AWSIMMLFSA-N
SMILES	C1(NC(C2=C3C(C=CC=C3)=CC=C2P(C2=CC=CC=C2)C2=CC=CC=C2)=O)CCCCC1NC(C1=C2C(C=CC=C2)=CC=C1P(C1=CC=CC=C1)C1=CC=CC=C1)=O
CAS DataBase Reference	174810-09-4
UNSPSC Code	12352005
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS05,GHS07,GHS08
Signal word	Danger
Hazard statements	H302-H315-H318-H361-H370-H372-H317-H402
Precautionary statements	P501-P273-P272-P260-P270-P202-P201-P264-P280-P302+P352-P308+P311-P362+P364-P333+P313-P301+P312+P330-P305+P351+P338+P310-P405
Risk Statements	36/37/38
Safety Statements	26-36/37/39
WGK Germany	3
HS Code	2931499090
Storage Class	11 - Combustible Solids

(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl) price More Price(27)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	692778	(R,R)-DACH-naphthyl Trost ligand 95%	174810-09-4	250mg	$147	2026-04-30	Buy
Sigma-Aldrich	692778	(R,R)-DACH-naphthyl Trost ligand 95%	174810-09-4	1g	$561	2026-04-30	Buy
Strem Chemicals	15-0963	(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl), min. 94% (R,R)-DACH-Naphthyl Trost Ligand min.94%	174810-09-4	100mg	$54	2026-04-30	Buy
Strem Chemicals	15-0963	(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl), min. 94% (R,R)-DACH-Naphthyl Trost Ligand min.94%	174810-09-4	500mg	$194	2026-04-30	Buy
Strem Chemicals	15-0963	(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl), min. 94% (R,R)-DACH-Naphthyl Trost Ligand min.94%	174810-09-4	2g	$612	2026-04-30	Buy

Product number	Packaging	Price	Buy
692778	250mg	$147	Buy
692778	1g	$561	Buy
15-0963	100mg	$54	Buy
15-0963	500mg	$194	Buy
15-0963	2g	$612	Buy

(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl) Chemical Properties, Uses, Production

Reactions

The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, and fluorides nucleophiles. Reactions of 174810-09-4_1
Reactions of 174810-09-4_2

Chemical Properties

white to off-white powder

Uses

Trost Ligands for Asymmetric Allylic Alkylation

(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl) synthesis

Synthesis of (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl) from Methyl 2-hydroxy-1-naphthoate

(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl) Preparation Products And Raw materials

Raw materials

2-Diphenylphosphino-1-naphthoic acid Methyl 2-diphenylphosphino-1-n Methyl 2-hydroxy-1-naphthoate Methyl 2-trifluoromethanesulfonyloxy-1-naphthoate (1R,2R)-(-)-1,2-Diaminocyclohexane

Preparation Products

(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl) Suppliers

Global Suppliers ( 92)

Supplier	Tel	Email	Country	ProdList	Advantage
LaaJoo	021-60702684 18516024827	huang.jiayi@sinocompound.com	China	2280	58
J & K SCIENTIFIC LTD.	18210857532 18210857532	jkinfo@jkchemical.com	China	96815	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	4006356688 18621169109	market03@meryer.com	China	40202	62
Energy Chemical	400-0056266	sales8178@energy-chemical.com	China	44850	61
Jia Xing Isenchem Co.,Ltd	0573-85285100 18627885956	isenchem@163.com	China	9389	66
China DongFan Chemical Co.,LTD	86-0571-85151182		China	5681	66
Nanjin Cynthia chemicals Technology Co.,Ltd	0550-5618439 15951861180	cynthiachem@163.com	China	291	62
Tianjin Derchemist Science & Technology Co., Ltd.	22-58627059 13920586291	zdcomcon@126.com	China	4094	50
Shanghai Jian Chao Chemical Technology Co., Ltd.	150-2103-5486 18017383231	983544897@qq.com	China	9336	55
Shanghai Incat Chemtech Co.,Ltd.	021-57603038 13601791340;13818007232	307593986@qq.com	China	475	58

Supplier	Advantage
LaaJoo	58
J & K SCIENTIFIC LTD.	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	62
Energy Chemical	61
Jia Xing Isenchem Co.,Ltd	66
China DongFan Chemical Co.,LTD	66
Nanjin Cynthia chemicals Technology Co.,Ltd	62
Tianjin Derchemist Science & Technology Co., Ltd.	50
Shanghai Jian Chao Chemical Technology Co., Ltd.	55
Shanghai Incat Chemtech Co.,Ltd.	58

View Latest Price from (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl) manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2026-08-07	(1R,2R)-(+)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl) 174810-09-4	$1.00	1KG	99%	20 tons	Shaanxi Dideu Medichem Co. Ltd
	2019-08-09	(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) 174810-09-4	$1.00	1KG	98%	1kg,5kg,100kg	Career Henan Chemical Co

(1R,2R)-(+)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl)
174810-09-4
$1.00
99%
Shaanxi Dideu Medichem Co. Ltd

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)
174810-09-4
$1.00
98%
Career Henan Chemical Co

174810-09-4 ((1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl)) Related Search:

(1R,2R)-(+)-1,2-Diphenylethylenediamine (1R,2R)-N,N'-Dimethyl-1,2-cyclohexanediamine (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl) (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl) (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl)

(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl) trans-N,N'-Diacetylcyclohexane-1,2-diamine 1,2-Diaminocyclohexane N,N'-Dimethyl-1,2-cyclohexanediamine Trans-(1R,2R)N,N'-Dimethyl-cyclohexane-1,2-diamine

2-Diphenylphosphinobenzaldehyde

1of3

(R,R)-TROST LIGAND(NAPHTHYL) (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),min.94%(R,R)-DACH-NaphthylTrostLigand (R,R)-DACH-naphthyl Trost ligand (1R,2R)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),94% (1R,2R)-(+)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),94% (R,R)-DACH-Naphthyl Trost Ligand (1R,2R)-(+)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),(R,R)-DACH-Naphthyl Trost Ligand 1-NaphthalenecarboxaMide,N,N'-(1R,2R)-1,2-cyclohexanediylbis[2-(diphenylphosphino)- (R,R)-DACH-naphthyl Trost ligand 95% N,N'-(1R,2R)-Cyclohexane-1,2-diylbis[2-(diphenylphosphanyl)naphthalene-1-carboxamide] 2-diphenylphosphanyl-N-[(1R,2R)-2-[(2-diphenylphosphanylnaphthalene-1-carbonyl)amino]cyclohexyl]naphthalene-1-carboxamide (1R,2R)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosph... N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphino)-1-naphthalenecarboxamide N,N'-((1R,2R)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthamide) (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),94% ?(R,R)-DACH-Naphthyl Trost Ligand CAS:174810-09-4 (R,R)-DACH-naphthyl Trost ligand (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl) 174810-09-4 Chiral Nitrogen DACH&Trost Series