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(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl)

(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl) structure

CAS No.: 138517-61-0

Chemical Name:: (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl)

Synonyms: TROST LIGAND;(1R,2R)-Trost ligand;(1R,2R)-(+)-1,2-TROST LIGAND;1R,2R- DHAC-Phenyl Trost Ligand;(R,R)-DACH-phenyl Trost ligand;(R,R)-DACH-phenyl Trost ligand 95%;(R,R)-DACH-phenyl Trost ligand;(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-di-phenylphos...;N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphino)benzamide;N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphi no)benzamide]

CBNumber:: CB8153647

Molecular Formula:: C44H40N2O2P2

Molecular Weight:: 690.75

MDL Number:: MFCD01631273

MOL File:: 138517-61-0.mol

MSDS File:: SDS

TDS File:: TDS

Last updated:2026-09-12 18:55:23

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(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl) Properties

Melting point	134-136°C
alpha	+130° (c 1.0, methanol)
Boiling point	817.0±65.0 °C(Predicted)
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
form	Powder
pka	13.35±0.40(Predicted)
color	white to off-white
optical activity	[α]20/D +131°, c = 1 in methanol
InChIKey	AXMSEDAJMGFTLR-UHFFFAOYSA-N
SMILES	C1(NC(=O)C2=CC=CC=C2P(C2=CC=CC=C2)C2=CC=CC=C2)CCCCC1NC(=O)C1=CC=CC=C1P(C1=CC=CC=C1)C1=CC=CC=C1
FDA UNII	M4RRX95R5F
UNSPSC Code	12352002
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H302-H315-H319-H335
Precautionary statements	P261-P305+P351+P338
Risk Statements	36/37/38
Safety Statements	26-36/37/39
WGK Germany	3
Storage Class	11 - Combustible Solids

(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl) price More Price(45)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	692808	(R,R)-DACH-phenyl Trost ligand 95%	138517-61-0	250MG	$155	2026-04-30	Buy
Sigma-Aldrich	692808	(R,R)-DACH-phenyl Trost ligand 95%	138517-61-0	1G	$591	2026-04-30	Buy
Strem Chemicals	15-0960	(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 98% (R,R)-DACH-Phenyl Trost Ligand 98%	138517-61-0	100mg	$52	2026-04-30	Buy
Strem Chemicals	15-0960	(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 98% (R,R)-DACH-Phenyl Trost Ligand 98%	138517-61-0	500mg	$198	2026-04-30	Buy
Strem Chemicals	15-0960	(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 98% (R,R)-DACH-Phenyl Trost Ligand 98%	138517-61-0	2g	$606	2026-04-30	Buy

Product number	Packaging	Price	Buy
692808	250MG	$155	Buy
692808	1G	$591	Buy
15-0960	100mg	$52	Buy
15-0960	500mg	$198	Buy
15-0960	2g	$606	Buy

(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl) Chemical Properties, Uses, Production

Reaction

The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, sulfur, and fluorides nucleophiles. Reactions of 138517-61-0_1
Reactions of 138517-61-0_2
Reactions of 138517-61-0_3

Uses

Trost Ligands for Asymmetric Allylic Alkylation

(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl) Preparation Products And Raw materials

Raw materials

Preparation Products

(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl) Suppliers

Global Suppliers ( 118)

Supplier	Tel	Email	Country	ProdList	Advantage
Daicel Chiral Technologies (China)CO.,LTD	021-50460086-9 15921403865	han_yajun@dctc.daicel.com	China	7909	65
Shanghai Chiral bio-compound co., Ltd.	021-5068 3667/17749785980/1029026415; 17749785980	1029026415@qq.com	China	4501	58
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd.	0371-65511006 18625597674	info@kingorgchem.com;sales@kingorgchem.com	China	806	55
Shanghai Moss Medicine Technology Co., Ltd.	+86-188369842 +86-15618151133	188369842@qq.com	China	1965	58
J & K SCIENTIFIC LTD.	18210857532 18210857532	jkinfo@jkchemical.com	China	96815	76
Energy Chemical	400-0056266	sales8178@energy-chemical.com	China	44850	61
Shanghai Hanhong Scientific Co.,Ltd.	021-54306202 13764082696	info@hanhongsci.com	China	42917	64
China DongFan Chemical Co.,LTD	86-0571-85151182		China	5681	66
Innochem(Beijing) Technology Co.,Ltd.	010-56541685 13070143590	sales@innochem.cn	China	172	57
Nanjin Cynthia chemicals Technology Co.,Ltd	0550-5618439 15951861180	cynthiachem@163.com	China	291	62

Supplier	Advantage
Daicel Chiral Technologies (China)CO.,LTD	65
Shanghai Chiral bio-compound co., Ltd.	58
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd.	55
Shanghai Moss Medicine Technology Co., Ltd.	58
J & K SCIENTIFIC LTD.	76
Energy Chemical	61
Shanghai Hanhong Scientific Co.,Ltd.	64
China DongFan Chemical Co.,LTD	66
Innochem(Beijing) Technology Co.,Ltd.	57
Nanjin Cynthia chemicals Technology Co.,Ltd	62

View Latest Price from (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl) manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2021-07-02	(R,R)-DACH-phenyl Trost ligand 138517-61-0	$10.00-15.00	1KG	99%+ HPLC		Zhuozhou Wenxi import and Export Co., Ltd
	2019-08-09	(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) 138517-61-0	$1.00	1KG	98%	1kg,5kg,100kg	Career Henan Chemical Co

(R,R)-DACH-phenyl Trost ligand
138517-61-0
$10.00-15.00
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)
138517-61-0
$1.00
98%
Career Henan Chemical Co

138517-61-0 ((1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl)) Related Search:

(1R,2R)-(+)-N,N'-Di-p-tosyl-1,2-cyclohexanediamine (1R,2R)-(+)-1,2-Diphenylethylenediamine (1R,2R)-N,N'-Dimethyl-1,2-cyclohexanediamine (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl) (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl)

(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl) (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl) N-(2-Amino-cyclohexyl)-acetamide trans-N,N'-Diacetylcyclohexane-1,2-diamine 2-Diphenylphosphinobenzaldehyde

Trans-(1R,2R)N,N'-Dimethyl-cyclohexane-1,2-diamine (1R,2R)-(-)-1,2-Diaminocyclohexane N,N'-Dimethyl-1,2-cyclohexanediamine

1of3

(1R, 2R) - (+) - 1,2- hexanediaMine -N, N'- diphenyl-phosphine-benzoyl Benzamide, N,N'-(1R,2R)-1,2-cyclohexanediylbis[2-(diphenylphosphino)- N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphi no)benzamide],99%e.e. N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphi no)benzamide] (1R,2R)-(+)-1,2-TROST LIGAND "N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphino)benzamide]/ (R,R)-DACH-phenyl Trost ligand" 2-diphenylphosphanyl-n-[(1r,2r)-2-[(2-diphenylphosphanylbenzoyl)amino]cyclohexyl]benzamide (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-di-phenylphoshinobenzoyl) (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl),98%(R,R)-DACH-PhenylTrostLigand (R,R)-DACH-phenyl Trost ligand (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 98% (R,R)-DACH-Phenyl (1R,2R)-(+)-N,N'-Bis(2-diphenylphosphinobenzoyl)-1,2-diaminocyclohexane (R,R)-DACH-phenyl Trost ligand 95% (1R,2R)-N,N'-(Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)benzamide) 1R,2R- DHAC-Phenyl Trost Ligand (1R,2R)-(+)-1,2-DiaMinocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), (R,R)-DACH-Phenyl Trost Ligand (1R,2R)-N,N'-1,2-Diaminocyclohexane-bis(2'-diphenylphosphinobenzoyl) (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-di-phenylphos... (1R,2R)-Trost ligand N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphino)benzamide (1R,2R)-(+)-1,2-Diaminocyclohexane- N,N'-bis(2'-diphenylphosphinobenzoyl), (R,R)-DACH-Phenyl Trost Ligand (R,R)-DACH-phenyl Trost ligand N,N'-((1R,2R)-cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)benzamide) (1R,2R)-N,N'-(Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)benzamide) - [C88535] (1R,2R)-cyclohexyldiamine-N,N'-bis(2-diphenylphosphinoylbenzeneformyl) TROST LIGAND (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl) 138517-61-0 C44H40N2O2P2 Chiral Nitrogen DACH&Trost Series