Diethyl dibutylmalonate
- CAS No.
- 596-75-8
- Chemical Name:
- Diethyl dibutylmalonate
- Synonyms
- Diethyl 2,2-dibutylmalonate;DEDNBM;DIETHYL DIBUTYL MALONATE;DIETHYL DI-N-BUTYLMALONATE;Diethyl Dibutylmalonate >Diethyl di-n-butyllmalonate;Diethyldi-n-butylmalonate,98+%;diethyl 2,2-dibutylpropanedioate;dibutyl-propanedioicacidiethylester;DI-N-BUTYLMALONIC ACID DIETHYL ESTER
- CBNumber:
- CB0742650
- Molecular Formula:
- C15H28O4
- Molecular Weight:
- 272.38
- MDL Number:
- MFCD00026842
- MOL File:
- 596-75-8.mol
- MSDS File:
- SDS
| Boiling point | 150 °C12 mm Hg(lit.) |
|---|---|
| Density | 0.945 g/mL at 25 °C(lit.) |
| refractive index |
n |
| Flash point | >230 °F |
| storage temp. | Sealed in dry,Room Temperature |
| form | clear liquid |
| color | Colorless to Almost colorless |
| BRN | 518421 |
| Stability | Stable. Incompatible with bases, strong oxidizing agents. Combustible. |
| InChI | InChI=1S/C15H28O4/c1-5-9-11-15(12-10-6-2,13(16)18-7-3)14(17)19-8-4/h5-12H2,1-4H3 |
| InChIKey | WHKKUUPZLWUOIW-UHFFFAOYSA-N |
| SMILES | C(OCC)(=O)C(CCCC)(CCCC)C(OCC)=O |
| CAS DataBase Reference | 596-75-8(CAS DataBase Reference) |
| FDA UNII | 8M1UZO3IFC |
| NIST Chemistry Reference | Propanedioic acid, dibutyl-, diethyl ester(596-75-8) |
| EPA Substance Registry System | Propanedioic acid, dibutyl-, diethyl ester (596-75-8) |
Diethyl dibutylmalonate price More Price(10)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | S383503 | DIETHYL DIBUTYLMALONATE AldrichCPR | 596-75-8 | 1 unit | $30.7 | 2025-07-31 | Buy |
| Sigma-Aldrich | S383503 | DIETHYL DIBUTYLMALONATE AldrichCPR | 596-75-8 | 250MG | $29.8 | 2024-03-01 | Buy |
| TCI Chemical | D1184 | Diethyl Dibutylmalonate >98.0%(GC) | 596-75-8 | 25mL | $70 | 2025-07-31 | Buy |
| American Custom Chemicals Corporation | CHM0029224 | DIETHYL DIBUTYLMALONATE 95.00% | 596-75-8 | 100G | $2715.73 | 2021-12-16 | Buy |
| American Custom Chemicals Corporation | CHM0029224 | DIETHYL DIBUTYLMALONATE 95.00% | 596-75-8 | 250G | $4890.53 | 2021-12-16 | Buy |
Diethyl dibutylmalonate Chemical Properties,Uses,Production
Chemical Properties
colourless liquid
Application
Diethyl dibutylmalonate can be used to prepare Guerbet acid. Guerbet acid is a fatty acid with a long branched alkane at the α position of the carboxylic acid. Compared with straight-chain fatty acids with the same carbon number, it has the characteristics of being colorless and odorless, having almost no adverse effects on the human body, having a low freezing point, and having low irritation. It is widely used in industrial lubricants, metalworking fluids, cosmetics, surfactants and additives.
Synthesis
109-65-9
105-53-3
596-75-8
Under nitrogen protection, 100 g of diethyl malonate and 300 ml of anhydrous ethanol were added to a 1000 ml three-necked round bottom flask. 40.5 g of sodium methanol was slowly added at room temperature followed by dropwise addition of 102.8 g of n-bromobutane. The reaction mixture was heated to reflux for 3 hours. Upon completion of the reaction, the reaction was cooled to room temperature, 40.5 g of sodium methanol was added again and 102.8 g of n-bromobutane was added slowly dropwise and the reaction was continued to be heated and refluxed for 3 hours. At the end of the reaction, cooled to room temperature and removed the solvent under reduced pressure. The pH of the reaction system was adjusted to 7 with 1 mol/L aqueous sulfuric acid, and the organic phase was separated and washed with appropriate amount of water. Finally, diethyl di-n-butylmalonate was purified by distillation under reduced pressure to yield 154 g (90.6% yield).
References
[1] Patent: CN106748724, 2017, A. Location in patent: Paragraph 0024
[2] Journal of Organic Chemistry, 1995, vol. 60, # 20, p. 6379 - 6388
[3] Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1992, # 18, p. 2679 - 2684
Diethyl dibutylmalonate Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
Diethyl dibutylmalonate Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22963 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29800 | 58 |
| SIMAGCHEM CORP | +86-5922680277 +86-13806087780 | sale@simagchem.com | China | 17346 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34563 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 | info@dycnchem.com | China | 52846 | 58 |
| CR Corporation Limited | +8613062833949 | fred.wen@crcorporation.cn | China | 8647 | 58 |
| Shaanxi Didu New Materials Co. Ltd | +86-89586680 +86-13289823923 | 1026@dideu.com | China | 9015 | 58 |
| Henan Aochuang Chemical Co.,Ltd. | +86-0371-63689365 +8618638391208 | sales@aochuangchem.com | China | 9297 | 58 |
| Hebei Chuanghai Biotechnology Co., Ltd | +8615531151365 | mina@chuanghaibio.com | China | 18126 | 58 |
| GIHI CHEMICALS CO.,LIMITED | +8618058761490 | info@gihichemicals.com | China | 49977 | 58 |
View Lastest Price from Diethyl dibutylmalonate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2025-04-04 | Diethyl dibutylmalonate
596-75-8
|
US $0.00-0.00 / KG | 1KG | 98% | 1Ton | Henan Aochuang Chemical Co.,Ltd. | |
 |
2021-08-12 | Diethyl dibutylmalonate
596-75-8
|
US $15.00-10.00 / KG | 1KG | 99%+ HPLC | Monthly supply of 1 ton | Zhuozhou Wenxi import and Export Co., Ltd | |
 |
2020-01-08 | Diethyl dibutylmalonate
596-75-8
|
US $3.00 / KG | 1KG | 98% | 200KG | Career Henan Chemical Co |
-
- Diethyl dibutylmalonate
596-75-8
- US $0.00-0.00 / KG
- 98%
- Henan Aochuang Chemical Co.,Ltd.
-
- Diethyl dibutylmalonate
596-75-8
- US $15.00-10.00 / KG
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
-
- Diethyl dibutylmalonate
596-75-8
- US $3.00 / KG
- 98%
- Career Henan Chemical Co
