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3'-Bromo-4'-fluoroacetophenone

3'-Bromo-4'-fluoroacetophenone structure

CAS No.: 1007-15-4

Chemical Name:: 3'-Bromo-4'-fluoroacetophenone

Synonyms: 1-(3-bromo-4-fluorophenyl)ethan-1-one;3-Bromo-4-fluoroacetphenone;3-BROMO-4-FLUOROACETOPHENONE;1-(3-BROMO-4-FLUOROPHENYL)ETHANONE;3'-Bromo-4'-fluoroacetophone;3'-Bromo-4'-fluoroacetophenone;4-Acetyl-2-bromo-1-fluorobenzene;3'-Bromo-4'-fluoroacetophenone97%;3'-Bromo-4'-fluoroacetophenone >3- BROMO-4-FLUOROACETOPHENONE 98+%

CBNumber:: CB1160958

Molecular Formula:: C8H6BrFO

Molecular Weight:: 217.04

MDL Number:: MFCD00042466

MOL File:: 1007-15-4.mol

MSDS File:: SDS

TDS File:: TDS

Last updated:2026-05-27 23:10:44

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3'-Bromo-4'-fluoroacetophenone Properties

Melting point	52-57 °C(lit.)
Boiling point	150°C 12mm
Density	1.5728 (rough estimate)
refractive index	1.5450 (estimate)
Flash point	>230 °F
storage temp.	Sealed in dry,Room Temperature
form	powder to crystal
color	White to Orange to Green
BRN	3088698
InChI	1S/C8H6BrFO/c1-5(11)6-2-3-8(10)7(9)4-6/h2-4H,1H3
InChIKey	SZDWTGAORQQQGY-UHFFFAOYSA-N
SMILES	CC(=O)c1ccc(F)c(Br)c1
CAS DataBase Reference	1007-15-4(CAS DataBase Reference)
UNSPSC Code	12352100
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P261-P264-P271-P280-P302+P352-P305+P351+P338

target organs

Respiratory system

PPE

dust mask type N95 (US), Eyeshields, Gloves

Hazard Codes

Risk Statements

36/37/38

Safety Statements

26-37/39

WGK Germany

HazardClass

IRRITANT

HS Code

29147000

Storage Class

11 - Combustible Solids

Hazard Classifications

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

NFPA 704

	1
2		0

3'-Bromo-4'-fluoroacetophenone price More Price(47)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	339679	3′-Bromo-4′-fluoroacetophenone 96%	1007-15-4	25g	$349	2023-06-20	Buy
TCI Chemical	B2014	3'-Bromo-4'-fluoroacetophenone >96.0%(GC)	1007-15-4	5g	$90	2026-04-30	Buy
TCI Chemical	B2014	3'-Bromo-4'-fluoroacetophenone >96.0%(GC)	1007-15-4	25g	$357	2026-04-30	Buy
Activate Scientific	AS20864	3`-Bromo-4`-fluoroacetophenone 98%	1007-15-4	5g	$22	2026-06-04	Buy
Activate Scientific	AS20864	3`-Bromo-4`-fluoroacetophenone 98%	1007-15-4	25g	$33	2026-06-04	Buy

Product number	Packaging	Price	Buy
339679	25g	$349	Buy
B2014	5g	$90	Buy
B2014	25g	$357	Buy
AS20864	5g	$22	Buy
AS20864	25g	$33	Buy

3'-Bromo-4'-fluoroacetophenone Chemical Properties,Uses,Production

Chemical Properties

White to yellowish low melting soli

Uses

3′-Bromo-4′-fluoroacetophenone is also referred as 3-bromo-4-fluoro-acetophenone. Palladium-catalyzed amination of 3-bromo-4-fluoro-acetophenone has been reported.

General Description

3′-Bromo-4′-fluoroacetophenone is also referred as 3-bromo-4-fluoro-acetophenone. Palladium-catalyzed amination of 3-bromo-4-fluoro-acetophenone has been reported.

Synthesis

403-42-9

Ethanone, 1-(3,5-dibromo-4-fluorophenyl)-

176548-69-9

1007-15-4

Example A5: Synthesis of 1-(3,5-dibromo-4-fluorophenyl)ethan-1-one and 1-(3-bromo-4-fluorophenyl)ethan-1-one 69 g (0.5 mol) of 4-fluoroacetophenone was slowly added dropwise to 200.0 g (1.5 mol) of finely powdered aluminum and heated to 70 °C with stirring. The reaction temperature was maintained at 75-80 °C for 20 min, followed by the slow addition of 184 g (1.15 mol) of bromine at the same temperature over a period of 2.5 hours. After completion of the reaction, the mixture was heated to 90 °C and maintained for 3 hours. After cooling, decolorization was carried out and then the mixture was partitioned between water and tert-butyl methyl ether. The organic phase was separated to give 130 g of brownish black oil. The oily substance was separated by column chromatography on toluene, using toluene as eluent, to give a two-part product: a) 41.2 g (28% of theoretical yield) of colorless crystals with a melting point of 59-62 °C and an Rf = 0.53 (toluene). Identified by spectral analysis as 1-(3,5-dibromo-4-fluorophenyl)-1-ethanone. IR (KBr): 1685 (C=O) cm1; MS: M = 294/296/298 (Br). b) 41.2 g (28% of the theoretical yield) colorless crystals, melting point 59-62 °C, Rf = 0.53 (toluene). b) 46.0 g (42% of theoretical yield) colorless crystals, melting point 52-55 °C, Rf = 0.41 (toluene). Identified by spectral analysis as 1-(3-bromo-4-fluorophenyl)-1-ethanone. IR (KBr): 1682 (C=O) cm1; MS: M = 216/218 (Br). c) 46.0 g (42% of theoretical yield) colorless crystals, melting point 52-55 °C, Rf = 0.41 (toluene).

References

[1] Patent: US7230001, 2007, B1. Location in patent: Page/Page column 67-68

3'-Bromo-4'-fluoroacetophenone Preparation Products And Raw materials

Raw materials

4-Fluoroacetophenone tert-Butyl methyl ether

Preparation Products

Benzenepropanal, 3-bromo-4-fluoro-β-oxo- 3-Bromo-4-fluorophenol 2,3'-Dibromo-4'-fluoroacetophenone, 97%

3'-Bromo-4'-fluoroacetophenone Suppliers

Global( 269)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
J & K SCIENTIFIC LTD.	18210857532 18210857532	jkinfo@jkchemical.com	China	96815	76
Alfa Aesar	400-6106006	saleschina@alfa-asia.com	China	30103	84
TCI (Shanghai) Development Co., Ltd.	021-67121386	Sales-CN@TCIchemicals.com	China	24512	81
Energy Chemical	400-0056266	sales8178@energy-chemical.com	China	44850	61
Wuhan Chemwish Technology Co., Ltd	86-027-67849912	sales@chemwish.com	China	35884	56
Capot Chemical Co., Ltd	+86 (0) 571 85 58 67 18		China	18187	66
Beijing Ouhe Technology Co., Ltd	13552068683 13522913783	2355560935@qq.com	China	11777	60
JinYan Chemicals(ShangHai) Co.,Ltd.	13817811078	sales@jingyan-chemical.com	China	9963	60
Shanghai Sinch Parmaceuticals Tech. Co. Ltd.	+86-21-54098501	sales@sinch.com.cn	China	11592	64
Jia Xing Isenchem Co.,Ltd	0573-85285100 18627885956	isenchem@163.com	China	9389	66

Supplier	Advantage
J & K SCIENTIFIC LTD.	76
Alfa Aesar	84
TCI (Shanghai) Development Co., Ltd.	81
Energy Chemical	61
Wuhan Chemwish Technology Co., Ltd	56
Capot Chemical Co., Ltd	66
Beijing Ouhe Technology Co., Ltd	60
JinYan Chemicals(ShangHai) Co.,Ltd.	60
Shanghai Sinch Parmaceuticals Tech. Co. Ltd.	64
Jia Xing Isenchem Co.,Ltd	66

View Lastest Price from 3'-Bromo-4'-fluoroacetophenone manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2026-03-20	3'-Bromo-4'-fluoroacetophenone 1007-15-4		1KG	99%	20 mt	Hebei Chuanghai Biotechnology Co., Ltd
2025-12-24	3'-Bromo-4'-fluoroacetophenone 1007-15-4		1KG	99.0%	1000KG	Shaanxi Dideu Medichem Co. Ltd
2021-08-12	3"-Bromo-4"-fluoroacetophenone 1007-15-4	$10.00-15.00	1KG	99%+ HPLC		Zhuozhou Wenxi import and Export Co., Ltd

3'-Bromo-4'-fluoroacetophenone
1007-15-4
99%
Hebei Chuanghai Biotechnology Co., Ltd

3'-Bromo-4'-fluoroacetophenone
1007-15-4
99.0%
Shaanxi Dideu Medichem Co. Ltd

3"-Bromo-4"-fluoroacetophenone
1007-15-4
$10.00-15.00
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

3'-Bromo-4'-fluoroacetophenone Spectrum

3'-Bromo-4'-fluoroacetophenone(1007-15-4)MS 3'-Bromo-4'-fluoroacetophenone(1007-15-4)¹HNMR 3'-Bromo-4'-fluoroacetophenone(1007-15-4)¹³CNMR 3'-Bromo-4'-fluoroacetophenone(1007-15-4)IR1 3'-Bromo-4'-fluoroacetophenone(1007-15-4)IR2

1007-15-4(3'-Bromo-4'-fluoroacetophenone)Related Search:

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1-(3-BROMO-4-FLUOROPHENYL)ETHANONE 3- BROMO-4-FLUOROACETOPHENONE 98+% 3'-Bromo-4'-fluoroacetophenone97% Ethanone, 1-(3-bromo-4-fluorophenyl)- 3-Bromo-4-fluorophenyl(methyl) ketone 3'-Bromo-4'-fluoroacetophone 4-Acetyl-2-bromo-1-fluorobenzene 3'-Bromo-4'-fluoroacetophenone > 3'-Bromo-4'-fluoroacetophenone 3′-Bromo-4′-fluoroacetophenone, CAS 1007-15-4 1-(3-bromo-4-fluorophenyl)ethan-1-one 3-BROMO-4-FLUOROACETOPHENONE 3-Bromo-4-fluoroacetphenone 1007-15-4 BrC6H3FCOCH3 ARYL HALIDE Building Blocks C7 to C8 Carbonyl Compounds Organic Building Blocks Ketones Aryl Fluorinated Building Blocks Building Blocks C7 to C8 C7-C8 Carbonyl Compounds Chemical Synthesis Fluorinated Building Blocks Organic Building Blocks Organic Fluorinated Building Blocks Other Fluorinated Organic Building Blocks Fluorine series C7 to C8 Carbonyl Compounds Ketones Adehydes, Acetals & Ketones Bromine Compounds Fluorine Compounds Aromatic Halides (substituted)