Fmoc-hydrazide HCl
- CAS No.
- 35661-51-9
- Chemical Name:
- Fmoc-hydrazide HCl
- Synonyms
- FMOC-NHNH2;(9H-fluoren-9-yl)Methyl hydrazinecarboxylate;9-Fluorenylmethyl carbazate;9-fluorenylmethylchloroformatehydrazine;N-(9-Fluorenylmethoxycarbonyl) hydrazine (FMOC hydrazine);FMOC-NHNH2 HCL;Fmoc-hydrazide HCl;9-FluorenylmethylCarbazate>9-Fluorenylmethyl carbazate, >=99%;Carbazic Acid 9-Fluorenylmethyl Ester
- CBNumber:
- CB1210174
- Molecular Formula:
- C15H14N2O2
- Molecular Weight:
- 254.28
- MDL Number:
- MFCD00239419
- MOL File:
- 35661-51-9.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | ~170 °C (dec.) |
|---|---|
| Boiling point | 485.8±14.0 °C(Predicted) |
| Density | 1.259±0.06 g/cm3(Predicted) |
| storage temp. | Inert atmosphere,2-8°C |
| pka | 10.21±0.20(Predicted) |
| form | powder to crystal |
| color | White to Almost white |
| BRN | 2470262 |
| InChI | InChI=1S/C15H14N2O2/c16-17-15(18)19-9-14-12-7-3-1-5-10(12)11-6-2-4-8-13(11)14/h1-8,14H,9,16H2,(H,17,18) |
| InChIKey | YGCGPEUVGHDMLO-UHFFFAOYSA-N |
| SMILES | N(C(OCC1C2=C(C=CC=C2)C2=C1C=CC=C2)=O)N |
| CAS DataBase Reference | 35661-51-9 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H315-H319-H335 |
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38-38-37-36 |
| Safety Statements | 26-36 |
| WGK Germany | 3 |
| F | 3-10 |
| HS Code | 29280000 |
Fmoc-hydrazide HCl price More Price(51)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 46917 | 9-Fluorenylmethyl carbazate for HPLC derivatization, LiChropur?, ≥99.0% | 35661-51-9 | 250MG | $101 | 2022-05-15 | Buy |
| TCI Chemical | F0872 | 9-Fluorenylmethyl Carbazate >98.0%(HPLC)(T) | 35661-51-9 | 5g | $55 | 2026-04-30 | Buy |
| TCI Chemical | F0872 | 9-Fluorenylmethyl Carbazate >98.0%(HPLC)(T) | 35661-51-9 | 25g | $144 | 2026-04-30 | Buy |
| Biosynth | FF140266 | Fmoc-hydrazide | 35661-51-9 | 0.025kg | $219.31 | 2026-06-04 | Buy |
| Biosynth | FF140266 | Fmoc-hydrazide | 35661-51-9 | 0.05kg | $350.9 | 2026-06-04 | Buy |
Fmoc-hydrazide HCl Chemical Properties, Uses, Production
Chemical Properties
white powder
Uses
9-Fluorenylmethyl Carbazate is a reagent for the sensitive fluorogenic derivatization of carbohydrates.
Synthesis
28920-43-6
35661-51-9
General procedure for the synthesis of 9-fluorenylmethylhydrazinyl formate from 9-fluorenylmethylhydrazinyl formate as chloroformic acid methyl ester (FmocCl): to a well-stirred solution of hydrazine hydrate (19 g, 386 mmol) dissolved in 150 mL of CH3CN/H2O (1:1, v/v) at 0 °C, FmocCl (10 g, 38.65 mmol) dissolved in a solution of 600 mL of CH3CN. The reaction mixture was then warmed to room temperature and stirring was continued for 12 hours. Upon completion of the reaction, the mixture was concentrated in vacuum to about 150 mL and filtered to give the white solid product 9-fluorenylmethylhydrazinyl formate. The product was washed sequentially with water and hexane, dried to constant weight, and finally obtained under vacuum as 9.74 g (99% yield) of a pure product with a melting point of 172-173 °C. The structure of the product was confirmed by 1H NMR and 13C NMR: 1H NMR (DMSO) δ 4.08 (brs, 2H), 4.21 (t, J = 7.2 Hz, 1H), 4.28 (d, J = 7.2 Hz, 2H), 7.32 (t, J = 7.4 Hz, 2H), 7.42 (t, J = 7.4 Hz, 2H), 7.69 ( d, J = 7.4 Hz, 2H), 7.89 (d, J = 7.4 Hz, 2H), 8.36 (brs, 1H); 13C NMR (DMSO) δ 47.7, 66.7, 121.1 (2C), 126.3 (2C), 128.1 (2C), 128.7 (2C), 141.7 (2C), 144.9 (2C), 159.2. 159.2.
References
[1] Journal of Organic Chemistry, 2012, vol. 77, # 12, p. 5271 - 5278
[2] Patent: US9115171, 2015, B2. Location in patent: Page/Page column 43
[3] Patent: EP2182974, 2015, B1. Location in patent: Paragraph 0093
[4] Patent: CN108178739, 2018, A. Location in patent: Paragraph 0032; 0033; 0034
[5] Tetrahedron, 2011, vol. 67, # 42, p. 8187 - 8194
Fmoc-hydrazide HCl Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Suzhou Highfine Biotech Co., Ltd | 0512-69209928 18796809688 | zhouyingxiang@highfine.com | China | 1846 | 58 |
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| ShangHai DEMO Chemical Co.,Ltd | 400-021-7337 2355568890 | sales@demochem.com | China | 2569 | 57 |
| Beijing HwrkChemical Technology Co., Ltd | 89508211 18501085097 | sales.bj@hwrkchemical.com | China | 9407 | 55 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Beijing Ouhe Technology Co., Ltd | 13552068683 13522913783 | 2355560935@qq.com | China | 11777 | 60 |
| Accela ChemBio Co.,Ltd. | 021-50795510 4000665055 | marketing@accelachem.com | China | 10972 | 64 |
| Nanjing Chemlin Chemical Co., Ltd | 025-83697070 13770331960 | info@chemlin.com.cn | China | 16305 | 64 |
View Latest Price from Fmoc-hydrazide HCl manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2025-04-04 | FMOC-HYDRAZIDE HCL
35661-51-9
|
1KG | 98% | 1ton | Henan Aochuang Chemical Co.,Ltd. | ||
 |
2021-07-13 | FMOC-HYDRAZIDE HCL
35661-51-9
|
$10.00-15.00 | 1KG | 99%+ HPLC | Zhuozhou Wenxi import and Export Co., Ltd | ||
 |
2021-07-09 | FMOC-HYDRAZIDE HCL
35661-51-9
|
$10.00-15.00 | 1KG | 99%+ HPLC | Zhuozhou Wenxi import and Export Co., Ltd |
-
- FMOC-HYDRAZIDE HCL
35661-51-9
- 98%
- Henan Aochuang Chemical Co.,Ltd.
-
- FMOC-HYDRAZIDE HCL
35661-51-9
- $10.00-15.00
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
-
- FMOC-HYDRAZIDE HCL
35661-51-9
- $10.00-15.00
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
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