METHYL 2-CHLORO-3-NITROBENZOATE
- CAS No.
- 53553-14-3
- Chemical Name:
- METHYL 2-CHLORO-3-NITROBENZOATE
- Synonyms
- METHYL 2-CHLORO-3-NITROBENZOATE;Benzoic acid, 2-chloro-3-nitro-, methyl ester
- CBNumber:
- CB1382976
- Molecular Formula:
- C8H6ClNO4
- Molecular Weight:
- 215.59
- MDL Number:
- MFCD00482383
- MOL File:
- 53553-14-3.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Product description | Number | Pack Size | Price |
| 2-Chloro-3-nitrobenzoic acid methyl ester | FC55358 | 1g | $172.34 |
| 2-Chloro-3-nitrobenzoic acid methyl ester | FC55358 | 2g | $272.1 |
| 2-Chloro-3-nitrobenzoic acid methyl ester | FC55358 | 5g | $544.2 |
| 2-Chloro-3-nitrobenzoic acid methyl ester | FC55358 | 10g | $907.1 |
| 2-Chloro-3-nitrobenzoic acid methyl ester | FC55358 | 25g | $1814 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H315-H319 |
| Precautionary statements | P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313 |
| HS Code | 2916399090 |
METHYL 2-CHLORO-3-NITROBENZOATE price More Price(60)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Biosynth | FC55358 | 2-Chloro-3-nitrobenzoic acid methyl ester | 53553-14-3 | 1g | $172.34 | 2026-06-04 | Buy |
| Biosynth | FC55358 | 2-Chloro-3-nitrobenzoic acid methyl ester | 53553-14-3 | 2g | $272.1 | 2026-06-04 | Buy |
| Biosynth | FC55358 | 2-Chloro-3-nitrobenzoic acid methyl ester | 53553-14-3 | 5g | $544.2 | 2026-06-04 | Buy |
| Biosynth | FC55358 | 2-Chloro-3-nitrobenzoic acid methyl ester | 53553-14-3 | 10g | $907.1 | 2026-06-04 | Buy |
| Biosynth | FC55358 | 2-Chloro-3-nitrobenzoic acid methyl ester | 53553-14-3 | 25g | $1814 | 2026-06-04 | Buy |
METHYL 2-CHLORO-3-NITROBENZOATE Chemical Properties,Uses,Production
Uses
Methyl 2-Chloro-3-nitrobenzoate is a useful research chemical used in the preparation of benzothiadiazole derivatives as agrochemical microbicides.
Synthesis
67-56-1
3970-35-2
53553-14-3
General procedure for the synthesis of methyl 2-chloro-3-nitrobenzoate from methanol and 2-chloro-3-nitrobenzoic acid: 1. to a solution of 2-chloro-3-nitrobenzoic acid (10.0 g, 49.6 mmol) in methanol (80 mL) was added concentrated sulfuric acid (2.0 mL). 2. The reaction mixture was stirred overnight under reflux conditions. 3. Upon completion of the reaction, the methanol was removed by vacuum concentration. 4. Water was added to the residue and extracted with ethyl acetate. 5. The organic phase was washed sequentially with water, saturated sodium bicarbonate solution and saturated brine. 6. 6. The organic phase was dried with magnesium sulfate. 7. The target compound, methyl 2-chloro-3-nitrobenzoate (10.6 g, 99% yield), was obtained as a white solid by vacuum concentration. 8. The product was characterized by 1H NMR (CDCl3) and HPLC: 1H NMR (CDCl3) δ (ppm): 7.95 (dd, 1H), 7.84 (dd, 1H), 7.48 (t, 1H), 3.98 (s, 3H). HPLC Rt = 11.88 min. 150 × 6.0 mm); mobile phase: 0-20 min, acetonitrile/water = 10/90 to 100/0 (gradient), 20-30 min, acetonitrile/water = 100/0 (isocratic); flow rate: 1 mL/min.
References
[1] Patent: WO2008/51533, 2008, A2. Location in patent: Page/Page column 95
[2] Pesticide Science, 1997, vol. 50, # 4, p. 275 - 282
[3] Patent: EP1982982, 2008, A1. Location in patent: Page/Page column 197
[4] Patent: EP2141150, 2010, A1. Location in patent: Page/Page column 109-110
[5] Patent: KR101511396, 2015, B1. Location in patent: Paragraph 2881-2885
METHYL 2-CHLORO-3-NITROBENZOATE Preparation Products And Raw materials
METHYL 2-CHLORO-3-NITROBENZOATE Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Accela ChemBio Inc. | +1-858-6993322 | info@accelachem.com | United States | 21193 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| Chemsigma International Co., Ltd. | +86-2558742998 +86-19951791336 | info@chemsigma.com | China | 1807 | 58 |
| Changzhou Anxuan Chemical Co., Ltd | +86-0519-89882563 +86-18961279162 | andy@anxuanchem.com | China | 4327 | 58 |
| Aladdin Scientific | tp@aladdinsci.com | United States | 57505 | 58 | |
| Shaanxi Dideu New Materials Co. Ltd | +86-18192503167 18192503167 | 1036@dideu.com | China | 7915 | 58 |
| Amadis Chemical Company Limited | 571-89925085 | sales@amadischem.com | China | 131957 | 58 |
| Beijing Ouhe Technology Co., Ltd | 13552068683 13522913783 | 2355560935@qq.com | China | 11780 | 60 |
| NOTA Chemical (Shanghai) Co.,Ltd | 021-50189163 | sales@notachem.com | China | 209 | 64 |
| Hunan Hui Bai Shi Biotechnology Co., Ltd. | 0731-85526065 13308475853 | ivy@hnhbsj.com | China | 7241 | 62 |
View Lastest Price from METHYL 2-CHLORO-3-NITROBENZOATE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2025-12-01 | METHYL 2-CHLORO-3-NITROBENZOATE
53553-14-3
|
1KG | 97.0% | 10000KGS | Shaanxi Dideu New Materials Co. Ltd |
-
- METHYL 2-CHLORO-3-NITROBENZOATE
53553-14-3
- 97.0%
- Shaanxi Dideu New Materials Co. Ltd
