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1-bromo-4-methoxy-naphthalene

1-bromo-4-methoxy-naphthalene structure

CAS No.: 5467-58-3

Chemical Name:: 1-bromo-4-methoxy-naphthalene

Synonyms: NSC 25655;?1-Bromo-4-methoxynaphtaleme;4-Methoxy-1-broMonaphthalene;4-BroMo-1-Methoxynaphthalene;1-Methoxy-4-broMonaphthalene;1-bromo-4-methoxy-naphthalene;4-Bromo-1-naphthyl Methyl Ether;Naphthalene, 1-bromo-4-methoxy-

CBNumber:: CB21255522

Molecular Formula:: C11H9BrO

Molecular Weight:: 237.09

MDL Number:: MFCD00155144

MOL File:: 5467-58-3.mol

Last updated:2026-05-27 23:55:35

Product description	Number	Pack Size	Price
1-Bromo-4-methoxynaphthalene min. 98.0 %	B6147	5G	$61
1-Bromo-4-methoxynaphthalene min. 98.0 %	B6147	25G	$199
1-Bromo-4-methoxynaphthalene 97%	AS48621	5g	$21
1-Bromo-4-methoxynaphthalene 97%	AS48621	25g	$57
1-Bromo-4-methoxynaphthalene 97%	AS48621	100g	$170
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1-bromo-4-methoxy-naphthalene Properties

Melting point	195-196 °C
Boiling point	181 °C(Press: 18 Torr)
Density	1.447±0.06 g/cm3(Predicted)
storage temp.	Sealed in dry,Room Temperature
form	Oil
Appearance	Yellow to brown Liquid

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H315-H319-H335
Precautionary statements	P261-P305+P351+P338
Hazard Codes	Xi
Risk Statements	41
Safety Statements	26-39

1-bromo-4-methoxy-naphthalene price More Price(47)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
TCI Chemical	B6147	1-Bromo-4-methoxynaphthalene min. 98.0 %	5467-58-3	5G	$61	2026-04-30	Buy
TCI Chemical	B6147	1-Bromo-4-methoxynaphthalene min. 98.0 %	5467-58-3	25G	$199	2026-04-30	Buy
Activate Scientific	AS48621	1-Bromo-4-methoxynaphthalene 97%	5467-58-3	5g	$21	2026-06-04	Buy
Activate Scientific	AS48621	1-Bromo-4-methoxynaphthalene 97%	5467-58-3	25g	$57	2026-06-04	Buy
Activate Scientific	AS48621	1-Bromo-4-methoxynaphthalene 97%	5467-58-3	100g	$170	2026-06-04	Buy

Product number	Packaging	Price	Buy
B6147	5G	$61	Buy
B6147	25G	$199	Buy
AS48621	5g	$21	Buy
AS48621	25g	$57	Buy
AS48621	100g	$170	Buy

1-bromo-4-methoxy-naphthalene Chemical Properties,Uses,Production

Chemical Properties

Oil

Uses

Synthetic intermediate.

Synthesis Reference(s)

The Journal of Organic Chemistry, 11, p. 399, 1946 DOI: 10.1021/jo01174a017

Synthesis

2216-69-5

5467-58-3

The general procedure for the synthesis of 1-bromo-4-methoxynaphthalene from 1-methoxynaphthalene was as follows: 1-methoxy-3,5-dimethylbenzene (100 mg, 0.73 mmol), N-bromosuccinimide (NBS, 260 mg, 1.46 mmol), and a stainless steel ball (5 mm in diameter) were placed in a 10 mL stainless steel milling jar. The ball milling reaction was carried out and the progress of the reaction was monitored by thin layer chromatography (TLC) and proton nuclear magnetic resonance (1H NMR). Upon completion of the reaction, the reaction mixture was transferred to 30 mL of ethyl acetate and cooled at 0 °C. The product was separated as a filtrate by filtration through filter paper and the spent succinimide was separated as a precipitate. The resulting filtrate was concentrated under vacuum to give 250 mg (yield: 85%) of 1-bromo-4-methoxynaphthalene as a colorless powder. To test the efficiency of the large-scale reaction, monobromination of 1-methoxy-3,5-dimethylbenzene on a scale of 1.3 g was also carried out with a reaction time of 1 h. The product was isolated in 87% yield. During the reaction, the grinding equipment was suspended and a small sample was removed from the reaction tank for TLC and 1H NMR analysis. Subsequently, the reaction was restarted and the time of this operation was not included in the total reaction time.

References

[1] Bulletin of the Chemical Society of Japan, 1989, vol. 62, # 2, p. 591 - 593
[2] Journal of Chemical Research - Part S, 2003, # 9, p. 597 - 598
[3] Synthetic Communications, 2004, vol. 34, # 12, p. 2143 - 2152
[4] Tetrahedron Letters, 2001, vol. 42, # 39, p. 6941 - 6942
[5] Angewandte Chemie - International Edition, 2018, vol. 57, # 39, p. 12869 - 12873

1-bromo-4-methoxy-naphthalene Preparation Products And Raw materials

Raw materials

1-Methoxynaphthalene Anisole N-Bromosuccinimide 2-bromo-1-methoxynaphthalene

Preparation Products

4-METHOXYNAPHTHALENE-1-BORONIC ACID 4-methoxynaphthalene-1-carboxylate

1-bromo-4-methoxy-naphthalene Suppliers

Global( 141)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Shanghai Daken Advanced Materials Co.,Ltd	+86-2158073036	info@dakenam.com	China	14036	58
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	32997	60
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418679 +86-18949832763	info@tnjchem.com	China	2984	55
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29766	58
Jinan Carbotang Biotech Co.,Ltd.	+8615866703830	figo.gao@foxmail.com	China	8491	58
Accela ChemBio Inc.	+1-858-6993322 +86-18019713315	info@accelachem.com	United States	21189	58
Wuhan Chemwish Technology Co., Ltd	027-67849912	sales@chemwish.com	CHINA	10817	58
Shaanxi Dideu Medichem Co. Ltd	+86-29-87569266 +86-17392581500	1015@dideu.com	China	3861	58
Richest Group Ltd	18017061086	oled@richest-group.com	CHINA	5597	58
Zhengzhou Alfa Chemical Co.,Ltd	+86-18530059196	sale04@alfachem.cn	China	9636	58

Supplier	Advantage
Shanghai Daken Advanced Materials Co.,Ltd	58
ATK CHEMICAL COMPANY LIMITED	60
Hefei TNJ Chemical Industry Co.,Ltd.	55
career henan chemical co	58
Jinan Carbotang Biotech Co.,Ltd.	58
Accela ChemBio Inc.	58
Wuhan Chemwish Technology Co., Ltd	58
Shaanxi Dideu Medichem Co. Ltd	58
Richest Group Ltd	58
Zhengzhou Alfa Chemical Co.,Ltd	58

View Lastest Price from 1-bromo-4-methoxy-naphthalene manufacturers

Update time	Product	Min. Order	Purity	Supply Ability	Manufacturer
2026-08-13	1-bromo-4-methoxy-naphthalene 5467-58-3	1KG	98%	2000	Shenzhen Nexcon Pharmatechs Ltd.
2023-12-04	1-bromo-4-methoxy-naphthalene 5467-58-3		98%	100kg	Huida Pharmaceutical Technology (Shanghai) Co., Ltd.
2023-12-04	1-bromo-4-methoxy-naphthalene 5467-58-3		98%	100kg	Huida Pharmaceutical Technology (Shanghai) Co., Ltd.

1-bromo-4-methoxy-naphthalene
5467-58-3
98%
Shenzhen Nexcon Pharmatechs Ltd.

1-bromo-4-methoxy-naphthalene
5467-58-3
98%
Huida Pharmaceutical Technology (Shanghai) Co., Ltd.

1-bromo-4-methoxy-naphthalene
5467-58-3
98%
Huida Pharmaceutical Technology (Shanghai) Co., Ltd.

1-bromo-4-methoxy-naphthalene Spectrum

1-bromo-4-methoxy-naphthalene(5467-58-3)¹HNMR

5467-58-3(1-bromo-4-methoxy-naphthalene)Related Search:

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1-bromo-4-methoxy-naphthalene 1-Methoxy-4-broMonaphthalene 4-BroMo-1-Methoxynaphthalene 4-Methoxy-1-broMonaphthalene NSC 25655 Naphthalene, 1-bromo-4-methoxy- 4-Bromo-1-naphthyl Methyl Ether ?1-Bromo-4-methoxynaphtaleme 5467-58-3 Aromatics Intermediates & Fine Chemicals Pharmaceuticals