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Methyl 4-trifluoromethylbenzoate

Methyl 4-trifluoromethylbenzoate Structure
Methyl 4-trifluoromethylbenzoate structure
CAS No.
2967-66-0
Chemical Name:
Methyl 4-trifluoromethylbenzoate
Synonyms
METHYL 4-(TRIFLUOROMETHYL)BENZOATE;RARECHEM AL BF 0111;Methyl 4-trifluorome;4-Trifluoromethylbenzoate methyl;Methyl 4-(Trifluoromethyl)Benoate;METHYL P-(TRIFLUOROMETHYL)BENZOATE;Methyl-4-(trifluoroMethyl)benzonate;Methyl4-(trifluoromethyl)benzoate98%;Methyl4-(Trifluoromethyl)benzoate>n-Methyl-4-(Trifluoromethyl) Benzoate
CBNumber:
CB2164034
Molecular Formula:
C9H7F3O2
Molecular Weight:
204.15
MDL Number:
MFCD00042324
MOL File:
2967-66-0.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-27 23:59:34
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Methyl 4-trifluoromethylbenzoate Properties

Melting point 13-14 °C (lit.)
Boiling point 94-95 °C/21 mmHg (lit.)
Density 1.268 g/mL at 25 °C (lit.)
refractive index n20/D 1.451(lit.)
Flash point 180 °F
storage temp. Sealed in dry,Room Temperature
solubility Chloroform (Slightly), Methanol (Slightly)
form Liquid
Specific Gravity 1.268
color Clear colorless to very pale yellow
BRN 1963288
InChI InChI=1S/C9H7F3O2/c1-14-8(13)6-2-4-7(5-3-6)9(10,11)12/h2-5H,1H3
InChIKey VAZWXPJOOFSNLB-UHFFFAOYSA-N
SMILES C(OC)(=O)C1=CC=C(C(F)(F)F)C=C1
CAS DataBase Reference 2967-66-0(CAS DataBase Reference)
NIST Chemistry Reference 3-CF3-C6H4-COOCH3(2967-66-0)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
target organs Respiratory system
PPE Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-37/39
WGK Germany  3
HazardClass  IRRITANT
HS Code  29163990
Storage Class 10 - Combustible liquids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
NFPA 704
2
2 0

Methyl 4-trifluoromethylbenzoate price More Price(57)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 333441 Methyl 4-(trifluoromethyl)benzoate 99% 2967-66-0 5g $77.3 2026-04-30 Buy
TCI Chemical M1498 Methyl 4-(Trifluoromethyl)benzoate >98.0%(GC) 2967-66-0 5g $35 2026-04-30 Buy
TCI Chemical M1498 Methyl 4-(Trifluoromethyl)benzoate >98.0%(GC) 2967-66-0 25g $98 2026-04-30 Buy
TRC TRC-M332118-500MG Methyl 4-(trifluoromethyl)benzoate 2967-66-0 500mg $73 2026-06-03 Buy
Apolloscientific PC5172 Methyl 4-(trifluoromethyl)benzoate 95% 2967-66-0 100g $35 2026-06-04 Buy
Product number Packaging Price Buy
333441 5g $77.3 Buy
M1498 5g $35 Buy
M1498 25g $98 Buy
TRC-M332118-500MG 500mg $73 Buy
PC5172 100g $35 Buy

Methyl 4-trifluoromethylbenzoate Chemical Properties,Uses,Production

Application

Methyl 4-(trifluoromethyl)benzoate can be used as a pharmaceutical chemical and organic synthesis intermediate. In organic synthesis transformations, the ester group in methyl 4-(trifluoromethyl)benzoate is a powerful functional group transformation intermediate.

Chemical Properties

clear colorless to very pale yellow liquid

Uses

Methyl 4-(trifluoromethyl)benzoate is an ester. The reduction of methyl (4-trifluoromethyl)benzoate catalyzed by MoO2Cl2 was reported.

General Description

Methyl 4-(trifluoromethyl)benzoate is an ester. The reduction of methyl (4-trifluoromethyl)benzoate catalyzed by MoO2Cl2 was reported.

Synthesis

To a two-necked round-bottomed flask equipped with a magnetic stirring bar and a reflux condenser were added aryl alkyl ketones (1 mmol, 1 equiv.), ammonium iodide (10 mol%) and methanol (5 ml) and the reaction mixture was stirred for some time. Then 3 equivalents of potassium peroxymonosulfate was slowly added to the mixture and the resulting solution was allowed to stir the reaction at 60 degrees Celsius for 30 h. The reaction was then quenched with aqueous sodium thiosulfate and the mixture was vigorously stirred for a few minutes. The reaction mixture was extracted with EtOAc (3x15 mL), the organic phase was washed with water (2x5 mL), then the organic phase was dried with anhydrous Na2SO4, filtered and the solvent was evaporated under reduced pressure, and the residue was purified by column chromatography (silica gel, hexane/ethyl acetate mixture) to give methyl 4-(trifluoromethyl)benzoate.

Methyl 4-trifluoromethylbenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

5-Methoxy-1-[4-(trifluoromethyl)phenyl]-1-pentanone

Methyl 4-trifluoromethylbenzoate Suppliers

Global( 342)Suppliers
Supplier Tel Email Country ProdList Advantage
CHANGZHOU FLUORIDE CHEMICAL CO.,LTD 0086-519-89892883 15995021858 info@fluoridechem.com China 79 58
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
INTATRADE GmbH +49 3493/605464 sales@intatrade.de Germany 3563 66
future industrial shanghai co., ltd 400-0066400 13621662912 sales@jonln.com China 1989 65
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
Beijing HwrkChemical Technology Co., Ltd 89508211 18501085097 sales.bj@hwrkchemical.com China 9407 55
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Shijiazhuang Sdyano Fine Chemical Co., Ltd. 0311-89250318 13582355795 master@sjzsdyn.com China 2776 65
Supplier Advantage
CHANGZHOU FLUORIDE CHEMICAL CO.,LTD 58
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
INTATRADE GmbH 66
future industrial shanghai co., ltd 65
Alfa Aesar 84
TCI (Shanghai) Development Co., Ltd. 81
Beijing HwrkChemical Technology Co., Ltd 55
Energy Chemical 61
Shijiazhuang Sdyano Fine Chemical Co., Ltd. 65

View Lastest Price from Methyl 4-trifluoromethylbenzoate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Methyl 4-trifluoromethylbenzoate pictures 2026-08-25 Methyl 4-trifluoromethylbenzoate
2967-66-0
 $2.00-5.00 1kg 99% 100kg ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Methyl 4-trifluoromethylbenzoate pictures 2026-03-20 Methyl 4-trifluoromethylbenzoate
2967-66-0
 1KG 99% 20 mt Hebei Chuanghai Biotechnology Co., Ltd
Methyl 4-trifluoromethylbenzoate pictures 2025-06-20 Methyl 4-trifluoromethylbenzoate
2967-66-0
 1kg 99.50% 20tons Hebei Yanxi Chemical Co., Ltd.

Methyl 4-trifluoromethylbenzoate Spectrum

Methyl 4-trifluoromethylbenzoate(2967-66-0)1HNMRMethyl 4-trifluoromethylbenzoate(2967-66-0)IRMethyl 4-trifluoromethylbenzoate(2967-66-0)RamanMethyl 4-trifluoromethylbenzoate(2967-66-0)FT-IR

2967-66-0(Methyl 4-trifluoromethylbenzoate)Related Search:

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Kresoxim-methyl Acetonitrile o-Toluic acid

1of4

The three fluorinated Methyl benzoic acid Methyl ester RARECHEM AL BF 0111 n-Methyl-4-(Trifluoromethyl) Benzoate Methyl 4-(Trifluoromethyl)Benoate 4-(TRIFLUOROMETHYL)BENZOIC ACID METHYL ESTER METHYL ALPHA,ALPHA,ALPHA-TRIFLUORO-P-TOLUATE METHYL P-(TRIFLUOROMETHYL)BENZOATE Methyl 4-(trifluoromethyl)benzoate 98% Methyl4-(trifluoromethyl)benzoate98% Methyl 4-trifluorome TrifluoroMethyl-benzoic acid Methyl ester Methyl-4-(trifluoroMethyl)benzonate Methyl alpha,alpha,alpha-Trifluoro-p-toluate 4-(Trifluoromethyl)benzoic Acid Methyl Ester Methyl 4-(trifluoromethyl)benzoate,99% 4-(Methoxycarbonyl)benzotrifluoride, Methyl alpha,alpha,alpha-trifluoro-p-toluate Threefluorine Methyl benzoic acidMethyl ester On thethree fluorineMethylbenzoic acid Methyl ester Methyl4-(Trifluoromethyl)benzoate> Benzoic acid, 4-(trifluoromethyl)-, methyl ester Methyl 4-(Trifluoromethyl)Benzoate in Acetonitrile 4-Trifluoromethylbenzoate methyl METHYL 4-(TRIFLUOROMETHYL)BENZOATE 2967-66-0 CF3C6H4CO2CH3 Esters Organic Building Blocks C8 to C9 Carbonyl Compounds Building Blocks Carbonyl Compounds Esters C8 to C9 Benzotrifluoride Series Boronic Acid series Aromatic Esters