5-CHLORO-2-HYDROXYBENZONITRILE
- CAS No.
- 13589-72-5
- Chemical Name:
- 5-CHLORO-2-HYDROXYBENZONITRILE
- Synonyms
- AKOS B029245;4-Chloro-2-cyanophenol;5-Chlorosalicylonitrile;5-CHLORO-2-HYDROXYBENZONITRILE;2-Hydroxy-5-chlorobenzonitrile;Benzonitrile, 5-chloro-2-hydroxy-;5- Chloro-2- hydroxy benzonitrite;5-Chloro-2-hydroxybenzonitrile 95+%;5-Chloro-2-hydroxybenzonitrile, tech;4-Chloro-2-cyanophenol, 5-Chlorosalicylonitrile
- CBNumber:
- CB2299875
- Molecular Formula:
- C7H4ClNO
- Molecular Weight:
- 153.57
- MDL Number:
- MFCD00219003
- MOL File:
- 13589-72-5.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 5-Chloro-2-hydroxybenzonitrile | C585780 | 50mg | $45 |
| 5-Chloro-2-hydroxybenzonitrile | C585780 | 500mg | $90 |
| 5-Chloro-2-hydroxybenzonitrile 95+% | OR24196 | 5g | $103 |
| 5-Chloro-2-hydroxybenzonitrile | FC67694 | 5G | $105 |
| 5-Chloro-2-hydroxybenzonitrile | 4637-5-Z0 | 5G | $152 |
| More product size | |||
| Melting point | 152-154°C |
|---|---|
| Boiling point | 269.4±25.0 °C(Predicted) |
| Density | 1.41±0.1 g/cm3(Predicted) |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| pka | 6.72±0.18(Predicted) |
| Appearance | Light brown to off-white Solid |
| CAS DataBase Reference | 13589-72-5(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS06 |
|---|---|
| Signal word | Danger |
| Hazard statements | H301+H311+H331-H315-H319 |
| Precautionary statements | P501-P261-P270-P271-P264-P280-P337+P313-P305+P351+P338-P361+P364-P332+P313-P301+P310+P330-P302+P352+P312-P304+P340+P311-P403+P233-P405 |
| Hazard Codes | Xi |
| Risk Statements | 20/21/22-36/37/38-36 |
| Safety Statements | 26-36/37/39 |
| RIDADR | 3276 |
| HS Code | 2926907090 |
5-CHLORO-2-HYDROXYBENZONITRILE price
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TRC | C585780 | 5-Chloro-2-hydroxybenzonitrile | 13589-72-5 | 50mg | $45 | 2021-12-16 | Buy |
| TRC | C585780 | 5-Chloro-2-hydroxybenzonitrile | 13589-72-5 | 500mg | $90 | 2021-12-16 | Buy |
| Apolloscientific | OR24196 | 5-Chloro-2-hydroxybenzonitrile 95+% | 13589-72-5 | 5g | $103 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FC67694 | 5-Chloro-2-hydroxybenzonitrile | 13589-72-5 | 5G | $105 | 2021-12-16 | Buy |
| SynQuest Laboratories | 4637-5-Z0 | 5-Chloro-2-hydroxybenzonitrile | 13589-72-5 | 5G | $152 | 2021-12-16 | Buy |
5-CHLORO-2-HYDROXYBENZONITRILE Chemical Properties,Uses,Production
Synthesis
635-93-8
13589-72-5
The general procedure for the synthesis of 5-chloro-2-hydroxybenzonitrile from 5-chlorosalicylaldehyde is as follows: 1. 5-Chloro-2-hydroxybenzaldehyde (300 g, 1.92 mol) was suspended in water (4.5 L) with hydroxylamine-O-sulfonic acid (260 g, 2.30 mol) at room temperature. 2. The reaction mixture was stirred at 60 °C for 7 hours. 3. Upon completion of the reaction, water (3 L) was added to the mixture, which was subsequently chilled with ice. 4. The precipitated crystals were collected by filtration and washed with 1.5 L of water. 5. The resulting crystals were re-suspended in 1.5 L of water, filtered and washed with water. 6. 6. Finally, the crystals were tray dried at 50 °C for 22 h to give 272 g of 5-chloro-2-hydroxybenzonitrile (white crystals, yield: 93%). The structure of the product was confirmed by 1H-NMR (CDCl3): δ 6.94 (1H, d, J = 8.8 Hz), 7.42 (1H, dd, J = 8.8,2.9 Hz), 7.47 (1H, d, J = 2.9 Hz).
References
[1] Patent: WO2006/115130, 2006, A1. Location in patent: Page/Page column 53-54
[2] Patent: US2007/117866, 2007, A1
[3] Gazzetta Chimica Italiana, 1959, vol. 89, p. 1009,1013
[4] Journal of Molecular Recognition, 2012, vol. 25, # 6, p. 352 - 360
[5] Journal of Organic Chemistry, 2015, vol. 80, # 2, p. 1229 - 1234
5-CHLORO-2-HYDROXYBENZONITRILE Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Daken Advanced Materials Co.,Ltd | +86-2158073036 | info@dakenam.com | China | 13815 | 58 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29821 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49977 | 58 |
| Fuxin Pharmaceutical | +86-021-021-50872116 +8613122107989 | contact@fuxinpharm.com | China | 10000 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34563 | 58 |
| Win-Win chemical CO., Limited | +86-0086-577-64498589 +86-15355981851 | sales@win-winchemical.com | China | 14304 | 58 |
| Shanghai UCHEM Inc. | +862156762820 +86-13564624040 | sales@myuchem.com | China | 8793 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 | info@dycnchem.com | China | 52705 | 58 |
View Lastest Price from 5-CHLORO-2-HYDROXYBENZONITRILE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2019-07-06 | 5-CHLORO-2-HYDROXYBENZONITRILE
13589-72-5
|
US $1.00 / KG | 1KG | 98% | 100KG | Career Henan Chemical Co |
-
- 5-CHLORO-2-HYDROXYBENZONITRILE
13589-72-5
- US $1.00 / KG
- 98%
- Career Henan Chemical Co
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