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Bis(4-bromophenyl) ether

Bis(4-bromophenyl) ether structure

CAS No.: 2050-47-7

Chemical Name:: Bis(4-bromophenyl) ether

Synonyms: 4-BROMOPHENYL ETHER;BDE 15;pbde 15;usafdo-61;4,4'-DiBDE;USAF do-61;PBDE No. 15;PBDE 15(4.4';DIBROMODIPHENYLETHER;BDE No 15 solution

CBNumber:: CB2306780

Molecular Formula:: C12H8Br2O

Molecular Weight:: 328

MDL Number:: MFCD00000095

MOL File:: 2050-47-7.mol

Last updated:2025-07-24 18:13:47

Product description	Number	Pack Size	Price
Bis(4-bromophenyl) ether 99%	117277	100g	$580
BDE No 15 solution 50 μg/mL in isooctane, analytical standard	33662	1ml	$443
Bis(4-bromophenyl) Ether >97.0%(GC)	B0834	25g	$88
PBDE15	P215185	5g	$65
Bis(4-bromophenyl) Ether 98%	JK368577	25g	$84
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Bis(4-bromophenyl) ether Properties

Melting point	61-63 °C(lit.)
Boiling point	338-340 °C(lit.)
Density	1.6728 (rough estimate)
refractive index	1.6260 (estimate)
Flash point	338-340°C
storage temp.	2-8°C
solubility	Methanol (Slightly)
form	Crystalline
color	White
Water Solubility	Soluble in water.
InChI	InChI=1S/C12H8Br2O/c13-9-1-5-11(6-2-9)15-12-7-3-10(14)4-8-12/h1-8H
InChIKey	YAWIAFUBXXPJMQ-UHFFFAOYSA-N
SMILES	O(C1=CC=C(Br)C=C1)C1=CC=C(Br)C=C1
CAS DataBase Reference	2050-47-7(CAS DataBase Reference)
EWG's Food Scores	1
FDA UNII	OS4N55HE2E
NIST Chemistry Reference	4-Bromophenyl ether(2050-47-7)
EPA Substance Registry System	p,p'-Dibromodiphenyl ether (2050-47-7)
UNSPSC Code	41116107
NACRES	NA.24

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS02,GHS07,GHS08,GHS09

Signal word

Danger

Hazard statements

H225-H304-H315-H336-H410

Precautionary statements

P210-P261-P273-P301+P310-P331-P501

Hazard Codes

F,Xn,N

Risk Statements

33-67-65-50/53-38-11

Safety Statements

24/25-62-61-60-33-29-16-9

RIDADR

UN 1262 3/PG 2

WGK Germany

RTECS

KN0175000

TSCA

Yes

HS Code

29093090

Toxicity

LD50 ipr-mus: 125 mg/kg NTIS** AD277-689

NFPA 704

	1
0		0

Bis(4-bromophenyl) ether price More Price(31)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	117277	Bis(4-bromophenyl) ether 99%	2050-47-7	100g	$580	2025-07-31	Buy
Sigma-Aldrich	33662	BDE No 15 solution 50 μg/mL in isooctane, analytical standard	2050-47-7	1ml	$443	2022-05-15	Buy
TCI Chemical	B0834	Bis(4-bromophenyl) Ether >97.0%(GC)	2050-47-7	25g	$88	2025-07-31	Buy
TRC	P215185	PBDE15	2050-47-7	5g	$65	2021-12-16	Buy
Frontier Specialty Chemicals	JK368577	Bis(4-bromophenyl) Ether 98%	2050-47-7	25g	$84	2021-12-16	Buy

Product number	Packaging	Price	Buy
117277	100g	$580	Buy
33662	1ml	$443	Buy
B0834	25g	$88	Buy
P215185	5g	$65	Buy
JK368577	25g	$84	Buy

Bis(4-bromophenyl) ether Chemical Properties,Uses,Production

Chemical Properties

Tan or light crystalline

Uses

PBDE 15 is a polybrominated di-?Ph ether (PBDE), which is a flame retardant often incorporated into many polymers. PBDEs are an environmental pollutant that exhibit potential health risks to humans and wildlife.

Safety Profile

Poison by intraperitoneal route. When heated todecomposition it emits toxic fumes of Br-.

Synthesis

101-84-8

2050-47-7

The general procedure for the synthesis of 4,4'-dibromodiphenyl ether from diphenyl ether was as follows: in a four-necked round-bottomed flask fitted with a stirrer, condenser, dropping funnel and thermometer, diphenyl ether (170 g, 1.0 mol), 1,2-dichloroethane (EDC) (300 ml), water (200 ml) and NaBrO3 (55 g, 0.36 mol) were added. Bromine (176 g, 1.1 mol) was slowly added dropwise to the stirred mixture for 1 h at 25 °C. No significant HBr gas was released during the reaction. The reaction progress was monitored by gas chromatography (GC). After two hours of reaction, the diphenyl ether was completely converted to 4,4'-dibromodiphenyl ether. The reaction was stopped and the phases were separated to give the crude product 4,4'-dibromodiphenyl ether (324.8 g) in 99% yield and 99.5% selectivity.

References

[1] Patent: EP429975, 1991, A1
[2] Angewandte Chemie - International Edition, 2018, vol. 57, # 20, p. 5938 - 5942
[3] Angew. Chem., 2018, vol. 130, p. 6044 - 6049,6
[4] Monatshefte fuer Chemie, 1992, vol. 123, # 12, p. 1153 - 1162
[5] Patent: EP429975, 1991, A1

Bis(4-bromophenyl) ether synthesis

Synthesis of Bis(4-bromophenyl) ether from 4-Bromophenol

Bis(4-bromophenyl) ether Preparation Products And Raw materials

Raw materials

Diphenyl ether 4-Bromophenol 1,2-Dichloroethane Water

Preparation Products

4,4'-Oxydiphenol 4-PHENOXYPHENYLBORONIC ACID

Bis(4-bromophenyl) ether Suppliers

Global( 308)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Hebei Yanxi Chemical Co., Ltd.	+8618531123677	faithe@yan-xi.com	China	5853	58
Hebei Chuanghai Biotechnology Co,.LTD	+86-13131129325	sales1@chuanghaibio.com	China	5251	58
Hebei Chuanghai Biotechnology Co., Ltd	+8615531151365	mina@chuanghaibio.com	China	18126	58
Shanghai Daken Advanced Materials Co.,Ltd	+86-2158073036	info@dakenam.com	China	13469	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21620	55
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	33024	60
Speranza Chemical Co., Ltd.	+86-86-075521030354 +8618688942810	sophieliu@speranzachem.com	China	925	55
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29852	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49975	58
Richest Group Ltd	18017061086	oled@richest-group.com	CHINA	5600	58

Supplier	Advantage
Hebei Yanxi Chemical Co., Ltd.	58
Hebei Chuanghai Biotechnology Co,.LTD	58
Hebei Chuanghai Biotechnology Co., Ltd	58
Shanghai Daken Advanced Materials Co.,Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
ATK CHEMICAL COMPANY LIMITED	60
Speranza Chemical Co., Ltd.	55
career henan chemical co	58
CONIER CHEM AND PHARMA LIMITED	58
Richest Group Ltd	58

View Lastest Price from Bis(4-bromophenyl) ether manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2025-10-15	Bis(4-bromophenyl)ether 2050-47-7	US $45.00 / KG	1KG	98%+	300MT/year	Speranza Chemical Co., Ltd.
2025-06-27	Bis(4-bromophenyl) ether 2050-47-7	US $0.00-0.00 / KG	1KG	99%	500000kg	Hebei Chuanghai Biotechnology Co., Ltd
2025-06-20	Bis(4-bromophenyl) ether 2050-47-7	US $0.00 / kg	1kg	0.99	20 tons	Hebei Yanxi Chemical Co., Ltd.

Bis(4-bromophenyl)ether
2050-47-7
US $45.00 / KG
98%+
Speranza Chemical Co., Ltd.

Bis(4-bromophenyl) ether
2050-47-7
US $0.00-0.00 / KG
99%
Hebei Chuanghai Biotechnology Co., Ltd

Bis(4-bromophenyl) ether
2050-47-7
US $0.00 / kg
0.99
Hebei Yanxi Chemical Co., Ltd.

Bis(4-bromophenyl) ether Spectrum

Bis(4-bromophenyl) ether(2050-47-7)MS Bis(4-bromophenyl) ether(2050-47-7)¹HNMR Bis(4-bromophenyl) ether(2050-47-7)¹³CNMR Bis(4-bromophenyl) ether(2050-47-7)IR1 Bis(4-bromophenyl) ether(2050-47-7)IR2 Bis(4-bromophenyl) ether(2050-47-7)Raman

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BIS(4-BROMOPHENYL) ETHER BIS(P-BROMOPHENYL)ETHER DI-(P-BROMOPHENYL)ETHER 4,4'-Dibromodiphenyl ether 99% Bis(4-bromophenyl) ether, 1,1'-Oxybis(4-bromobenzene) PBDE 15(4.4' Benzene, 1,1'-oxybis[4-bromo- Bis-(4-bromphenyl)-ether Bis(bromophenyl) ether PARAPARADIBROMODIPHENYLETHER BIS(4-BROMOPHENY)ETHER DIBROMODIPHENYLETHER 4,4μ-DiBDE, 4,4μ-Dibromodiphenyl ether solution, PBDE 15 BDE No 15 solution BDE 15 4,4’-Dibromodiphenyl ether,50 μL/mL in Isooctane 4,4'-Dibromo-[1,1'-oxybisbenzene] 4,4'-Oxybis(1-bromobenzene) Bis(4-bromophenyl) ether, 99+% Bis(4-bromophenyl) ether,96% 4,4'-DiBDE 4,4'-Dibromodiphenyl ether solution PBDE 15 (4,4′-Dibromodiphenylether) Bis(p-bromophenyl)ether 500mg [2050-47-7] Bis(4-bromophenyl) ether,4-Bromophenyl ether Bis(4-bromophenyl) ether ,98% di(4-Bromophenyl)ether Diphenyl ether, 4,4'-dibromo Ether, bis(4-bromophenyl) Ether, bis(p-bromophenyl) ether,bis(4-bromophenyl) p,p’-Dibromodiphenylether p,p'-Dibromodiphenyl ether USAF do-61 usafdo-61 BIS-(4-BROMOPHENYL)-ETHER 98% pbde 15 4,4'-DIBROMODIPHENYL OXIDE 4,4'-DIBROMOPHENYL ETHER 4-BROMOPHENYL ETHER BIS(PARA-BROMOPHENY)ETHER 1,1’-oxybis(4-bromo-Benzene 1,1’-oxybis[4-bromo-benzen PBDE 15 100 ng/μl in Methanol 1-Bromo-4-(4-bromophenoxy)benzene 4,4'-Dibromodiphenyl ether (BDE-15) Solution Bis(4-bromophenyl) Ether > 4,4'-Dibromodiphenylether Solution in Isooctane, 100μg/mL TIANFU-CHEM - Bis(4-bromophenyl) ether 4,4'-Oxybis(bromobenzene) 4,4'-dibromodiphenyl ether PBDE 15 100 μg/ml Cyclohexane 4,4'-Dibromodiphenyl ether PBDE No. 15 100 μg/mL in Methanol PBDE 15 50 μg/mL in Nonane PBDE No. 15 2050-47-7 2050-47-4