methyl 3-bromopicolinate
- CAS No.
- 53636-56-9
- Chemical Name:
- methyl 3-bromopicolinate
- Synonyms
- Methyl 3-broMopyridine-2-carboxylate;Methyl 3-bromo-2-pyridinecarboxylate;methyl 3-bromopicolinate;3-Bromopyridine-2-carboxylic acid methy ester;3-Bromo-2-pyridinecarboxylic acid methyl ester;3-Bromopyridine-2-carboxylic acid methyl ester;2-Pyridinecarboxylic acid, 3-bromo-, methyl ester;Methyl 3-bromopicolinate, 3-Bromo-2-(methoxycarbonyl)pyridine
- CBNumber:
- CB32106158
- Molecular Formula:
- C7H6BrNO2
- Molecular Weight:
- 216.03
- MDL Number:
- MFCD12025946
- MOL File:
- 53636-56-9.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Boiling point | 267.4±20.0 °C(Predicted) |
|---|---|
| Density | 1.579±0.06 g/cm3(Predicted) |
| storage temp. | Keep in dark place,Inert atmosphere,2-8°C |
| pka | -0.91±0.10(Predicted) |
| form | solid |
| color | Pale yellow |
| InChI | InChI=1S/C7H6BrNO2/c1-11-7(10)6-5(8)3-2-4-9-6/h2-4H,1H3 |
| InChIKey | GSTYLUGZSCVBTJ-UHFFFAOYSA-N |
| SMILES | C1(C(OC)=O)=NC=CC=C1Br |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302-H315-H319-H332-H335 |
| Precautionary statements | P261-P280-P305+P351+P338 |
| Hazard Codes | Xi |
| Risk Statements | 41 |
| Safety Statements | 26-39 |
| HazardClass | IRRITANT |
| HS Code | 2933399990 |
methyl 3-bromopicolinate price More Price(36)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| AstaTech | CL0157 | 3-BROMOPYRIDINE-2-CARBOXYLICACIDMETHYLESTER 97% | 53636-56-9 | 1G | $10 | 2026-04-30 | Buy |
| AstaTech | CL0157 | 3-BROMOPYRIDINE-2-CARBOXYLICACIDMETHYLESTER 97% | 53636-56-9 | 5G | $24 | 2026-04-30 | Buy |
| AstaTech | CL0157 | 3-BROMOPYRIDINE-2-CARBOXYLICACIDMETHYLESTER 97% | 53636-56-9 | 25G | $127 | 2026-04-30 | Buy |
| Apolloscientific | OR16874 | Methyl 3-bromopyridine-2-carboxylate 98% | 53636-56-9 | 1g | $21 | 2026-06-04 | Buy |
| Apolloscientific | OR16874 | Methyl 3-bromopyridine-2-carboxylate 98% | 53636-56-9 | 5g | $41 | 2026-06-04 | Buy |
methyl 3-bromopicolinate Chemical Properties, Uses, Production
Synthesis
30683-23-9
53636-56-9
a) To a methanolic solution of 3-bromo-2-pyridinecarboxylic acid (1 g, 4.9 mmol), a few drops of concentrated sulfuric acid were slowly added as a catalyst at room temperature. The reaction mixture was stirred at room temperature for 12 hours to ensure complete reaction. Upon completion of the reaction, methanol was removed by rotary evaporation to give the crude product. The crude product was purified by a CombiFlash fast chromatography system on a silica gel column with the eluent being a hexane solution of 20-50% ethyl acetate, resulting in methyl 3-bromopyridinecarboxylate (450 mg, 41% yield). Subsequently, compound 17 (82% yield) was synthesized in a series of reaction steps according to the method described in Example 1 using methyl 3-bromopyridinecarboxylate as starting material, and compound 4 was finally prepared.
References
[1] Patent: US2011/136833, 2011, A1. Location in patent: Page/Page column 27
[2] Journal of Medicinal Chemistry, 2011, vol. 54, # 2, p. 635 - 654
[3] Patent: US3963733, 1976, A
methyl 3-bromopicolinate Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shandong Bailong Pharmaceutical Co., Ltd. | 15562090112 | 3131095341@qq.com | China | 146 | 58 |
| Jinan LuoHe PharmaTech Co., Ltd. | 86-0531-68658065 15726150375 | 1071018499@qq.com | China | 525 | 58 |
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Shijiazhuang Sdyano Fine Chemical Co., Ltd. | 0311-89250318 13582355795 | master@sjzsdyn.com | China | 2776 | 65 |
| Wuhan Chemwish Technology Co., Ltd | 86-027-67849912 | sales@chemwish.com | China | 35884 | 56 |
| Pure Chemistry Scientific Inc. | 001-857-928-2050 or 1-888-588-9418 | sales@chemreagents.com | United States | 10174 | 62 |
| Accela ChemBio Co.,Ltd. | 021-50795510 4000665055 | marketing@accelachem.com | China | 10972 | 64 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
| Jiangsu Aikon Biopharmaceutical R&D co.,Ltd. | 025-66113011 13913916777 | cfzhang@aikonchem.com | China | 19902 | 55 |
View Latest Price from methyl 3-bromopicolinate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-09-02 | methyl 3-bromopicolinate
53636-56-9
|
$5.00 | 1KG | 98% | Henan Fengda Chemical Co., Ltd | ||
 |
2026-06-30 | methyl 3-bromopicolinate
53636-56-9
|
1KG | 98.0% | 10000KGS | Shaanxi Dideu New Materials Co. Ltd | ||
 |
2022-09-12 | methyl 3-bromopicolinate
53636-56-9
|
1G | 98%minHPLC | 50kg/month | Shanghai Rlavie Technology Co ltd |
-
- methyl 3-bromopicolinate
53636-56-9
- $5.00
- 98%
- Henan Fengda Chemical Co., Ltd
-
- methyl 3-bromopicolinate
53636-56-9
- 98.0%
- Shaanxi Dideu New Materials Co. Ltd
-
- methyl 3-bromopicolinate
53636-56-9
- 98%minHPLC
- Shanghai Rlavie Technology Co ltd
