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3-Amino-5-bromopyridine

3-Amino-5-bromopyridine Structure
3-Amino-5-bromopyridine structure
CAS No.
13535-01-8
Chemical Name:
3-Amino-5-bromopyridine
Synonyms
5-BROMOPYRIDIN-3-AMINE;3-amino-5-bronopyridine;5-BROMO-PYRIDIN-3-YLAMINE;CHEMBRDG-BB 4006048;5-brompyridin-3-amin;3-AMino-5-broMopyridi;5-BROMO-3-PYRIDINAMINE;3-Amino-5-Bromopyridie;5-BROMO-3-AMINOPYRIDINE;3-AMINO-5-BROMOPYRIDINE
CBNumber:
CB8426565
Molecular Formula:
C5H5BrN2
Molecular Weight:
173.01
MDL Number:
MFCD01646060
MOL File:
13535-01-8.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 05:14:42
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3-Amino-5-bromopyridine Properties

Melting point 65-69 °C
Boiling point 149-150 °C(Press: 12 Torr)
Density 1.710±0.06 g/cm3(Predicted)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
pka 3.81±0.20(Predicted)
form Powder
color White to yellow to brown
InChI InChI=1S/C5H5BrN2/c6-4-1-5(7)3-8-2-4/h1-3H,7H2
InChIKey MDQXGHBCDCOOSM-UHFFFAOYSA-N
SMILES C1=NC=C(Br)C=C1N
CAS DataBase Reference 13535-01-8(CAS DataBase Reference)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P264-P270-P301+P312-P302+P352-P305+P351+P338
target organs Respiratory system
PPE dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes  Xn,Xi,O
Risk Statements  22-36/37/38
Safety Statements  26-36/37
RIDADR  Cool, dry,tightly closed
WGK Germany  3
Hazard Note  Harmful
HazardClass  IRRITANT
HS Code  29339900
Storage Class 11 - Combustible Solids
Hazard Classifications Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
NFPA 704
1
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3-Amino-5-bromopyridine price More Price(97)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 667129 3-Amino-5-bromopyridine 97% 13535-01-8 10g $165 2026-04-30 Buy
Sigma-Aldrich 667129 3-Amino-5-bromopyridine 97% 13535-01-8 1g $39.8 2023-06-20 Buy
Usbiological 260438 3-Amino-5-bromopyridine Asreported 13535-01-8 5g $333 2026-06-03 Buy
Usbiological 260438 3-Amino-5-bromopyridine Asreported 13535-01-8 10g $432 2026-06-03 Buy
Usbiological 260438 3-Amino-5-bromopyridine Asreported 13535-01-8 25g $573 2026-06-03 Buy
Product number Packaging Price Buy
667129 10g $165 Buy
667129 1g $39.8 Buy
260438 5g $333 Buy
260438 10g $432 Buy
260438 25g $573 Buy

3-Amino-5-bromopyridine Chemical Properties,Uses,Production

Chemical Properties

Light yellow Cryst

Uses

3-Amino-5-bromopyridine is used in green preparation of tryptamine salicylic acid compounds as antitumor agent.

Synthesis

5-Bromonicotinamide

28733-43-9

3-Amino-5-bromopyridine

13535-01-8

General procedure for the synthesis of 5-bromo-3-aminopyridine from 5-bromonicotinamide: 1. To a pre-cooled 340 ml aqueous solution containing 31.8 g (0.79 mol) of sodium hydroxide and 40.7 g (0.255 mol) of bromine, 42.0 g (0.209 mol) of commercially available 5-bromonicotinamide was added. 2. The reaction mixture was gradually warmed to room temperature, followed by heating the reaction at 70 °C for 1 hour. 3. Upon completion of the reaction, the resulting brown suspension was allowed to cool to room temperature. 4. The aqueous phase was treated with saturated brine and then extracted three times with a 1:1 solvent mixture of THF and tert-butyl methyl ether. 5. The organic phases were combined, dried with magnesium sulfate, filtered and concentrated under reduced pressure. 6. 39.1 g of the dark brown residue obtained from the concentration was purified by fast chromatography (eluent: heptane/ethyl acetate 1:1) to yield 5-bromo-3-aminopyridine as a brown solid (total yield 70.2 g, 70% yield).

References

[1] ChemMedChem, 2014, vol. 9, # 1, p. 217 - 232
[2] Patent: US2006/160857, 2006, A1. Location in patent: Page/Page column 56
[3] Patent: US2006/199960, 2006, A1. Location in patent: Page/Page column 21
[4] Patent: US2006/217387, 2006, A1. Location in patent: Page/Page column 31
[5] Patent: US2003/199511, 2003, A1. Location in patent: Page/Page column 23

3-Amino-5-bromopyridine synthesis

15862-30-3
13535-01-8
Synthesis of 3-Amino-5-bromopyridine from 3-Bromo-5-nitropyridine

3-Amino-5-bromopyridine Preparation Products And Raw materials

Raw materials

3,5-Dibromopyridine 5-Bromonicotinoyl chloride 3-Bromo-5-nitropyridine 5-Bromonicotinamide 3-Pyridyl bromide
Sodium hydroxide 5-Bromonicotinic acid

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Preparation Products

3-Bromo-1,5-naphthyridine 5-(4-Methoxyphenyl)pyridin-3-aMine (5-Bromo-pyridin-3-yl)-hydrazine 3-Aminopyridine-5-boronic acid N-(5-bromopyridin-3-yl)propionamide
5-(3-Methoxyphenyl)pyridin-3-aMine 5-Bromo-N-phenylpyridin-3-amine 7-Bromo-1,5-naphthyridine-4-oxo-3-carboxylic acid ethyl ester

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3-Amino-5-bromopyridine Suppliers

Global( 479)Suppliers
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
INTATRADE GmbH +49 3493/605464 sales@intatrade.de Germany 3563 66
future industrial shanghai co., ltd 400-0066400 13621662912 sales@jonln.com China 1989 65
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
Beijing dtftchem Technology Co., Ltd. 010-60275820 13031183356 elainezt@sina.com China 1386 62
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Shijiazhuang Sdyano Fine Chemical Co., Ltd. 0311-89250318 13582355795 master@sjzsdyn.com China 2776 65
Wuhan Chemwish Technology Co., Ltd 86-027-67849912 sales@chemwish.com China 35884 56
Capot Chemical Co., Ltd +86 (0) 571 85 58 67 18 China 18187 66
Supplier Advantage
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
INTATRADE GmbH 66
future industrial shanghai co., ltd 65
Alfa Aesar 84
Beijing dtftchem Technology Co., Ltd. 62
Energy Chemical 61
Shijiazhuang Sdyano Fine Chemical Co., Ltd. 65
Wuhan Chemwish Technology Co., Ltd 56
Capot Chemical Co., Ltd 66

View Lastest Price from 3-Amino-5-bromopyridine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
3-Amino-5-bromopyridine pictures 2026-09-02 3-Amino-5-bromopyridine
13535-01-8
 $1.50-36.00 1kg 99% Henan Fengda Chemical Co., Ltd
3-Amino-5-bromopyridine pictures 2026-03-20 3-Amino-5-bromopyridine
13535-01-8
 $8.90 1KG 99% 10 mt Hebei Chuanghai Biotechnology Co., Ltd
3-Amino-5-bromopyridine pictures 2025-06-25 3-Amino-5-bromopyridine
13535-01-8
 $1.10 1g 99.0% min 100 tons min Shaanxi Dideu Medichem Co. Ltd

3-Amino-5-bromopyridine Spectrum

3-Amino-5-bromopyridine(13535-01-8)1HNMR

13535-01-8(3-Amino-5-bromopyridine)Related Search:

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Glycine Aminoethoxyvinyl glycine hydrochloride 2-Amino-5-bromopyridine methyl 3-bromopicolinate 3-Bromo-5-iodo-pyridine
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3-AMINO-5-BOROMOPYRIDINE 5-bromopyridin-3-amine(SALTDATA: FREE) 3-AMino-5-broMopyridi 5--3- aMinopyridinebroMide 3--5- aMinopyridinebroMide 3-Amino-5-bromopyridine 97% CHEMBRDG-BB 4006048 5-BROMO-PYRIDIN-3-YLAMINE 5-BROMO-3-AMINOPYRIDINE 5-BROMO-3-PYRIDINAMINE 3-AMINO-5-BROMOPYRIDINE 3-Pyridinamine, 5-bromo- 3-Amino-5-bromopyridine ISO 9001：2015 REACH 3-Amino-5-Bromopyridie 5-brompyridin-3-amin 3-Amino-5-bromopyridine, 95% 3-amino-5-bronopyridine 5-BROMOPYRIDIN-3-AMINE 13535-01-8 13535-01-9 Pyridines Building Blocks Heterocyclic Building Blocks Halogenated Heterocycles Building Blocks C5 C5 to C6 Chemical Synthesis Halogenated Heterocycles Heterocyclic Building Blocks Boronic Acid CHIRAL CHEMICALS Pyridine Derivertives Heterocycle-Pyridine series pharmacetical Amines Pyridines, Pyrimidines, Purines and Pteredines Thiophenes blocks Bromides Pyridines Pyridine