ChemicalBook >> CAS DataBase List >>5-Bromo-2-fluorobenzaldehyde

5-Bromo-2-fluorobenzaldehyde

CAS No.
93777-26-5
Chemical Name:
5-Bromo-2-fluorobenzaldehyde
Synonyms
3-BroMo-6-fluorobenzaldehyde;2-FLUORO-5-BROMOBENZALDEHYDE;AKOS BBS-00003261;LABOTEST-BB LT01143303;5-Bromo-2-fluorobenzaldehyd;5-BROMO-2-FLUOROBENZALDEHYDE;Benzaldehyde, 5-bromo-2-fluoro-;5-Bromo-2-fluorobenzaldehyde98%;5-Bromo-2-fluorobenzaldehyde 98%;5-Bromo-2-fluorobenzaldehyde >
CBNumber:
CB3364493
Molecular Formula:
C7H4BrFO
Molecular Weight:
203.01
MDL Number:
MFCD00070755
MOL File:
93777-26-5.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 05:32:13
Product description Number Pack Size Price
5-Bromo-2-fluorobenzaldehyde 97% 528870 25g $112
5-Bromo-2-fluorobenzaldehyde >95.0%(GC) B1789 5g $25
5-Bromo-2-fluorobenzaldehyde >95.0%(GC) B1789 25g $88
5-Bromo-2-fluorobenzaldehyde, min. 98% min.98% 09-0027 25g $73
5-Bromo-2-fluorobenzaldehyde, min. 98% min.98% 09-0027 100g $185
More product size

5-Bromo-2-fluorobenzaldehyde Properties

Melting point 58-62°C
Boiling point 230 °C (lit.)
Density 1.71 g/mL at 25 °C (lit.)
refractive index n20/D 1.57(lit.)
Flash point 229 °F
storage temp. 2-8°C
form powder to lump to clear liquid
Specific Gravity 1.710
color White or Colorless to Light yellow
Water Solubility INSOLUBLE
Sensitive Air Sensitive
BRN 7632798
InChI InChI=1S/C7H4BrFO/c8-6-1-2-7(9)5(3-6)4-10/h1-4H
InChIKey MMFGGDVQLQQQRX-UHFFFAOYSA-N
SMILES C(=O)C1=CC(Br)=CC=C1F
CAS DataBase Reference 93777-26-5(CAS DataBase Reference)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
target organs Respiratory system
PPE Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36-37/39
WGK Germany  3
HazardClass  IRRITANT
HS Code  29130000
Storage Class 10 - Combustible liquids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
NFPA 704
0
2 0

5-Bromo-2-fluorobenzaldehyde price More Price(72)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 528870 5-Bromo-2-fluorobenzaldehyde 97% 93777-26-5 25g $112 2026-04-30 Buy
TCI Chemical B1789 5-Bromo-2-fluorobenzaldehyde >95.0%(GC) 93777-26-5 5g $25 2026-04-30 Buy
TCI Chemical B1789 5-Bromo-2-fluorobenzaldehyde >95.0%(GC) 93777-26-5 25g $88 2026-04-30 Buy
Strem Chemicals 09-0027 5-Bromo-2-fluorobenzaldehyde, min. 98% min.98% 93777-26-5 25g $73 2026-04-30 Buy
Strem Chemicals 09-0027 5-Bromo-2-fluorobenzaldehyde, min. 98% min.98% 93777-26-5 100g $185 2026-04-30 Buy
Product number Packaging Price Buy
528870 25g $112 Buy
B1789 5g $25 Buy
B1789 25g $88 Buy
09-0027 25g $73 Buy
09-0027 100g $185 Buy

5-Bromo-2-fluorobenzaldehyde Chemical Properties,Uses,Production

Chemical Properties

clear yellowish liquid after melting

Uses

5-Bromo-2-fluorobenzaldehyde is used for the preparation of benzimidazole derivatives as inhibitors of leukotriene production.

Synthesis

2-Fluorobenzaldehyde

446-52-6

5-Bromo-2-fluorobenzaldehyde

93777-26-5

Example 3: In a reactor equipped with an electric stirrer, a thermometer, a dropping funnel and a condenser tube, 500 mL of aqueous sulfuric acid solution was added. Subsequently, a mixture of 167 g (1 mol) of potassium bromate and 124.1 g (1 mol) of 2-fluorobenzaldehyde was slowly added dropwise to the reaction system, the reaction temperature was maintained at 90°C, and the dropwise process continued for 2 to 3 hours. Upon completion of the reaction, 1000 mL of water was added to the system and extracted using methyl tert-butyl ether. The organic phase was subsequently washed with aqueous sodium sulfite and dried over anhydrous sodium sulfate. The dried organic phase was filtered and concentrated to remove the methyl tert-butyl ether to give a brownish red oil. Finally, the 63-65°C/3 mmHg fraction was collected by vacuum distillation to afford 178 g of the target product 5-bromo-2-fluorobenzaldehyde in 88% yield and 97% purity.

References

[1] Patent: CN105884591, 2016, A. Location in patent: Paragraph 0008; 0009; 0010; 0011

446-52-6
93777-26-5
Synthesis of 5-Bromo-2-fluorobenzaldehyde from 2-Fluorobenzaldehyde
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View Lastest Price from 5-Bromo-2-fluorobenzaldehyde manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
5-Bromo-2-fluorobenzaldehyde pictures 2026-05-28 5-Bromo-2-fluorobenzaldehyde
93777-26-5
$9.00 1KG 99.9 1 ton Hebei Chuanghai Biotechnology Co,.LTD
5-Bromo-2-fluorobenzaldehyde pictures 2026-03-20 5-Bromo-2-fluorobenzaldehyde
93777-26-5
$9.90 1KG 99% 10 mt Hebei Chuanghai Biotechnology Co., Ltd
5-Bromo-2-fluorobenzaldehyde pictures 2026-02-02 5-Bromo-2-fluorobenzaldehyde
93777-26-5
10mg 99%HPLC 2000tons Shaanxi Dideu Medichem Co. Ltd
5-BROMO-2-FLUOROBENZALDEHYDE AKOS BBS-00003261 LABOTEST-BB LT01143303 2-FLUORO-5-BROMOBENZALDEHYDE Benzaldehyde, 5-bromo-2-fluoro- 5-Bromo-2-Fluorobenzaldehyde 2-Fluoro-5-Bromobenzaldehyde 5-Bromo-2-fluorobenzaldehyde 98% 5-Bromo-2-fluorobenzaldehyde98% 3-BroMo-6-fluorobenzaldehyde Benzoic acid, 4-chloro-3-fluoro-, Methyl ester 5 - broMine - 2 - fluoro benzaldehyde 5-Bromo-2-fluorobenzaldehyde > 5-Bromo-2-fluorobenzaldehyde ISO 9001:2015 REACH 5-Bromo-2-fluorobenzaldehyd 93777-26-5 9377-26-5 Organic Building Blocks Aldehydes ALDEHYDE Building Blocks C7 Carbonyl Compounds Aromatic Aldehydes & Derivatives (substituted) Benzaldehyde API intermediates Adehydes, Acetals & Ketones Bromine Compounds Fluorine Compounds Carbonyl Compounds Halides Fluorin-contained benzaldehyde series Benzaldehyde series Aldehydes C7 Carbonyl Compounds bc0001