ChemicalBook >> CAS DataBase List >>4-Bromo-2-fluorobenzylamine

4-Bromo-2-fluorobenzylamine

4-Bromo-2-fluorobenzylamine structure

CAS No.: 112734-22-2

Chemical Name:: 4-Bromo-2-fluorobenzylamine

Synonyms: (4-BroMo-2-fluorophenyl)MethanaMine;MINA-002;TIMTEC-BB SBB005778;RARECHEM AL BW 0772;4-Bromo-2-fluorobenzylamine;2-FLUORO-4-BROMOBENZYL AMINE;4-Bromo-2-fluorobenzylamine,99%;2-Fluoro-4-Bromobenzylamine HCl;4-Bromo-2-fluorobenzenemethanamine;4-BroMo-2-fluorobenzylaMine, 99% 5GR

CBNumber:: CB3443035

Molecular Formula:: C7H7BrFN

Molecular Weight:: 204.04

MDL Number:: MFCD00153076

MOL File:: 112734-22-2.mol

MSDS File:: SDS

Last updated:2026-09-12 18:52:03

Request For Quotation

4-Bromo-2-fluorobenzylamine Properties

Boiling point	244.5±25.0 °C(Predicted)
Density	1.571±0.06 g/cm3(Predicted)
storage temp.	under inert gas (nitrogen or Argon) at 2–8 °C
pka	8.43±0.10(Predicted)
form	Liquid
Specific Gravity	1.58
color	Clear colorless to slightly yellow
InChI	InChI=1S/C7H7BrFN/c8-6-2-1-5(4-10)7(9)3-6/h1-3H,4,10H2
InChIKey	RLTFBWCBGIZCDQ-UHFFFAOYSA-N
SMILES	C1(CN)=CC=C(Br)C=C1F
CAS DataBase Reference	112734-22-2(CAS DataBase Reference)
UNSPSC Code	12352116

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS05,GHS07
Signal word	Danger
Hazard statements	H302+H312+H332-H314
Precautionary statements	P501-P261-P270-P271-P264-P280-P362+P364-P303+P361+P353-P301+P330+P331-P301+P312+P330-P304+P340+P310-P305+P351+P338+P310-P405
Hazard Codes	C,Xi
Risk Statements	34-21/22-36
Safety Statements	45-36/37/39-26
RIDADR	2735
WGK Germany	WGK 3
Hazard Note	Irritant
HazardClass	8
PackingGroup	Ⅲ
HS Code	29214900
Storage Class	11 - Combustible Solids
Hazard Classifications	Eye Irrit. 2
Limited Quantities	5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid)
Excepted Quantities	Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)

4-Bromo-2-fluorobenzylamine price More Price(43)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	CDS003182	4-bromo-2-fluorobenzylamine Aldrich^CPR		1 g	$77.9	2026-04-30	Buy
Apolloscientific	PC9062	4-Bromo-2-fluorobenzylamine >98%	112734-22-2	1g	$21	2026-06-04	Buy
Apolloscientific	PC9062	4-Bromo-2-fluorobenzylamine >98%	112734-22-2	5g	$25	2026-06-04	Buy
Apolloscientific	PC9062	4-Bromo-2-fluorobenzylamine >98%	112734-22-2	25g	$81	2026-06-04	Buy
Apolloscientific	PC9062	4-Bromo-2-fluorobenzylamine >98%	112734-22-2	100g	$316	2026-06-04	Buy

Product number	Packaging	Price	Buy
CDS003182	1 g	$77.9	Buy
PC9062	1g	$21	Buy
PC9062	5g	$25	Buy
PC9062	25g	$81	Buy
PC9062	100g	$316	Buy

4-Bromo-2-fluorobenzylamine Chemical Properties, Uses, Production

Chemical Properties

Clear colorless to slightly yellow liquid

Synthesis

105942-08-3

112734-22-2

General procedure for the synthesis of (4-bromo-2-fluorophenyl)methanamine from 4-bromo-2-fluorobenzonitrile: 4-bromo-2-fluorobenzonitrile (5.00 mmol) was dissolved in tetrahydrofuran (THF, 30 mL) and the solution was cooled to 0°C. A solution of borane tetrahydrofuran complex (1 M solution of THF, 15.0 mL) was added slowly and dropwise with stirring. The reaction mixture was continued to be stirred at 0 °C for 20 min, followed by warming to room temperature and stirring for 16 hours. Upon completion of the reaction, methanol (MeOH, 30 mL) was added slowly and dropwise to quench the reaction, followed by concentration of the solution under reduced pressure. The residue was extracted by partitioning with 1 M aqueous sodium hydroxide (NaOH) and ethyl acetate (EtOAc). The organic layer was separated and post-processed to give (4-bromo-2-fluorophenyl)methylamine (5.00 mmol) as a yellow oil.1H NMR (400 MHz, CDCl3) data: δ 7.42-7.27 (m, 1H), 7.25-7.16 (m, 2H), 3.65 (t, J = 6.6 Hz, 2H).

References

[1] Journal of Organic Chemistry, 2008, vol. 73, # 5, p. 1898 - 1905
[2] Journal of Organic Chemistry, 2009, vol. 74, # 5, p. 1964 - 1970
[3] Patent: WO2017/103611, 2017, A1. Location in patent: Paragraph 00336
[4] Patent: WO2018/75871, 2018, A1. Location in patent: Page/Page column 62

4-Bromo-2-fluorobenzylamine synthesis

Synthesis of 4-Bromo-2-fluorobenzylamine from 4-Bromo-2-fluorobenzonitrile

4-Bromo-2-fluorobenzylamine Preparation Products And Raw materials

Raw materials

Ethanol 4-Bromo-2-fluorobenzonitrile Palladium Borane THF Tetrahydrofuran

Preparation Products

(3R)-2'-(4-Bromo-2-fluorobenzyl)spiro[pyrrolidine-3,4'-1'H-pyrrolo[1,2-a]pyrazine]-1',2,3',5(2'H)-tetraone

4-Bromo-2-fluorobenzylamine Suppliers

Global Suppliers ( 169)

Supplier	Tel	Email	Country	ProdList	Advantage
J & K SCIENTIFIC LTD.	18210857532 18210857532	jkinfo@jkchemical.com	China	96815	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	4006356688 18621169109	market03@meryer.com	China	40202	62
Capot Chemical Co., Ltd	+86 (0) 571 85 58 67 18		China	18187	66
JinYan Chemicals(ShangHai) Co.,Ltd.	13817811078	sales@jingyan-chemical.com	China	9963	60
Jia Xing Isenchem Co.,Ltd	0573-85285100 18627885956	isenchem@163.com	China	9389	66
Adamas Reagent, Ltd.	400-6009262 15618770481	yhx@titansci.com	China	14098	59
Shanghai Harvest Chemical Industrial Co., Ltd.	15721252604 17321035817	sales@harvest-chem.com	China	2829	64
Nanjing Chemlin Chemical Co., Ltd	025-83697070 13770331960	info@chemlin.com.cn	China	16306	64
China DongFan Chemical Co.,LTD	86-0571-85151182		China	5681	66
Syntechem Co.,Ltd		info@syntechem.com	China	12973	57

Supplier	Advantage
J & K SCIENTIFIC LTD.	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	62
Capot Chemical Co., Ltd	66
JinYan Chemicals(ShangHai) Co.,Ltd.	60
Jia Xing Isenchem Co.,Ltd	66
Adamas Reagent, Ltd.	59
Shanghai Harvest Chemical Industrial Co., Ltd.	64
Nanjing Chemlin Chemical Co., Ltd	64
China DongFan Chemical Co.,LTD	66
Syntechem Co.,Ltd	57

View Latest Price from 4-Bromo-2-fluorobenzylamine manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2021-07-13	4-BROMO-2-FLUOROBENZYLAMINE 112734-22-2	$10.00-15.00	1KG	99%+ HPLC		Zhuozhou Wenxi import and Export Co., Ltd
2021-07-10	4-BROMO-2-FLUOROBENZYLAMINE 112734-22-2	$10.00-15.00	1KG	99%+ HPLC		Zhuozhou Wenxi import and Export Co., Ltd
2020-01-01	4-BROMO-2-FLUOROBENZYLAMINE 112734-22-2	$1.00	1KG	99%	1000KG	Career Henan Chemical Co

4-BROMO-2-FLUOROBENZYLAMINE
112734-22-2
$10.00-15.00
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

4-BROMO-2-FLUOROBENZYLAMINE
112734-22-2
$10.00-15.00
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

4-BROMO-2-FLUOROBENZYLAMINE
112734-22-2
$1.00
99%
Career Henan Chemical Co

4-Bromo-2-fluorobenzylamine Spectrum

4-BROMO-2-FLUOROBENZYLAMINE(112734-22-2)¹HNMR

112734-22-2 (4-Bromo-2-fluorobenzylamine) Related Search:

5-Bromo-2-fluorobenzyl alcohol 3-BroMo-4-fluorobenzyl alcohol 2-Fluorobenzylamine 4-Bromobenzylamine 2-Bromo-5-fluorobenzylamine

4-Bromo-2-fluorobenzylamine hydrochloride Zenarestat STATIL 4-Bromo-2-fluorobenzamide 3-Bromo-4-fluorobenzamidoxime

4-Bromo-2-fluorobenzylamine Minalrestat 5-Bromo-2-fluorobenzylamine. 5-Bromo-2-fluorobenzylamine hydrochloride 4-Bromo-2-fluoro-benzamidine hydrochloride

3-Amino-3-(4-bromo-2-fluorophenyl)propanoic acid 2-Bromo-4-fluorobenzylamine hydrochloride 5-Bromo-2-fluorobenzylamine hydrochloride

1of4

RARECHEM AL BW 0772 TIMTEC-BB SBB005778 2-FLUORO-4-BROMOBENZYL AMINE 2-Fluoro-4-Bromobenzylamine HCl 4-Bromo-2-fluorobenzylamine,99% 4-BroMo-2-fluorobenzylaMine, 99% 5GR (4-broMo-2-fluorophenyl)MethanaMine hydrochloride Benzenemethanamine, 4-bromo-2-fluoro- MINA-002 4-Bromo-2-fluorobenzenemethanamine (4-BroMo-2-fluorophenyl)MethanaMine 4-Bromo-2-fluorobenzylamine 112734-22-2 Fluorine series Anilines, Aromatic Amines and Nitro Compounds Amine