METHYL 2-FORMYL-3-OXO-PROPIONATE
- CAS No.
- 50427-65-1
- Chemical Name:
- METHYL 2-FORMYL-3-OXO-PROPIONATE
- Synonyms
- Methyl Diformylacetate;Regadenoson Impurity 30;Methyl 2-formyl-3-oxo-propiote;Methyl 2-forMyl-3-oxopropanoate;METHYL 2-FORMYL-3-OXO-PROPIONATE;Propanoic acid, 2-formyl-3-oxo-, methyl ester;2-formyl-3-oxo-Propanoic acid methyl ester (9CI ACI);Propanoic acid, 2-formyl-3-oxo-, methyl ester (9CI, ACI)
- CBNumber:
- CB42458959
- Molecular Formula:
- C5H6O4
- Molecular Weight:
- 130.1
- MDL Number:
- MFCD00015921
- MOL File:
- 50427-65-1.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| methyl2-formyl-3-oxopropanoate | M328320 | 10mg | $45 |
| methyl2-formyl-3-oxopropanoate | M328320 | 50mg | $155 |
| METHYL DIFORMYLACETATE 95.00% | CHM0310266 | 5MG | $503.54 |
| Methyl2-formyl-3-oxo-propionate 96% | 05R0326 | 500mg | $199 |
| Methyl2-formyl-3-oxopropanoate 95+% | CD13012173 | 1g | $402 |
| Boiling point | 167.0±35.0 °C(Predicted) |
|---|---|
| Density | 1.187±0.06 g/cm3(Predicted) |
| storage temp. | Inert atmosphere,Store in freezer, under -20°C |
| solubility | slightly sol water; sol aqueous alkali and diethyl ether |
| pka | 0.54±0.10(Predicted) |
| FDA UNII | 8M9K5LZ8K4 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302-H315-H319-H335 |
| Precautionary statements | P261-P305+P351+P338 |
METHYL 2-FORMYL-3-OXO-PROPIONATE price
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TRC | M328320 | methyl2-formyl-3-oxopropanoate | 50427-65-1 | 10mg | $45 | 2021-12-16 | Buy |
| TRC | M328320 | methyl2-formyl-3-oxopropanoate | 50427-65-1 | 50mg | $155 | 2021-12-16 | Buy |
| American Custom Chemicals Corporation | CHM0310266 | METHYL DIFORMYLACETATE 95.00% | 50427-65-1 | 5MG | $503.54 | 2021-12-16 | Buy |
| J&W Pharmlab | 05R0326 | Methyl2-formyl-3-oxo-propionate 96% | 50427-65-1 | 500mg | $199 | 2021-12-16 | Buy |
| Crysdot | CD13012173 | Methyl2-formyl-3-oxopropanoate 95+% | 50427-65-1 | 1g | $402 | 2021-12-16 | Buy |
METHYL 2-FORMYL-3-OXO-PROPIONATE Chemical Properties,Uses,Production
Uses
Methyl 2-formyl-3-oxo-propanoate is used for [2 + 2] cycloaddition (de Mayo reaction); [4 + 2]cycloaddition (hetero-Diels-Alder reaction with inverse electron demand); transformation to enamino aldehydes and their photochemical and thermal cycloadditions; Wittig reaction.
Preparation
Methyl 2-formyl-3-oxo-propanoate is prepared by Panizzi's formylation procedure of commercially available methyl 3,3- dimethoxypropanoate with methyl formate, by diformylation of potassium monomethyl malonate with dimethyl formamide and phosphorus oxychloride followed by decarboxylation, and by ozonolysis of dimethyl 2,5-cyclohexadiene-1,4-dicarboxylate.
storage
Methyl 2-formyl-3-oxo-propanoate is stable for at least 6 months if stored at -20 °C; it is a highly acidic compound. Use in a fume hood.
Purification Methods
Fractional vacuum distillation.
METHYL 2-FORMYL-3-OXO-PROPIONATE Preparation Products And Raw materials
METHYL 2-FORMYL-3-OXO-PROPIONATE Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Career Henan Chemica Co | +86-0371-86658258 +8613203830695 | laboratory@coreychem.com | China | 30229 | 58 |
| HANGZHOU LEAP CHEM CO., LTD. | +86-571-87711850 | market18@leapchem.com | China | 43339 | 58 |
| Amadis Chemical Company Limited | 571-89925085 | sales@amadischem.com | China | 131957 | 58 |
| Nanjing Chemlin Chemical Co., Ltd | 025-83697070 | info@chemlin.com.cn | China | 14831 | 64 |
| S.Z. PhyStandard Bio-Tech. Co., Ltd. | 0755-4000505016 13380397412 | 3001272453@qq.com | China | 5158 | 50 |
| Shanghai Sheepchem Co., Ltd. | +86 (21) 6715-7650 | sheepchem@163.com | China | 994 | 60 |
| Shanghai ChriChem Co., Ltd. | 021-54880687 | China | 511 | 55 | |
| Shanghai Carlow Chemicals Co., Ltd. | 21-33526724 18930996265 | info@carlowchem.com | China | 1922 | 58 |
| Jiangsu Aikon Biopharmaceutical R&D co.,Ltd. | 025-66028182 18626450290 | yftan@aikonchem.com | China | 16679 | 50 |
| JW & Y Pharmlab Co., Ltd. | 021-64340559 13651849907; | xinyu_shi@jwypharmlab.com.cn | China | 11956 | 58 |
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