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1-Naphthylacetonitrile

1-Naphthylacetonitrile structure

CAS No.: 132-75-2

Chemical Name:: 1-Naphthylacetonitrile

Synonyms: ANNAFOMINA;1-NAPHTHALENEACETO;1-Naphthyl acetonitr;1-Naphtylacetonitrile;1-phthyl acetonitrile;LABOTEST-BB LTBB001326;a-naphthylacetonitrile;1-NAPHTHYLACETONITRILE;Naphazoline Impurity C;Naphazoline Impurity 3

CBNumber:: CB4416463

Molecular Formula:: C12H9N

Molecular Weight:: 167.21

MDL Number:: MFCD00004041

MOL File:: 132-75-2.mol

MSDS File:: SDS

Last updated:2026-05-28 02:46:29

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1-Naphthylacetonitrile Properties

Melting point	33-35 °C(lit.)
Boiling point	191-194 °C18 mm Hg(lit.)
Density	1.1110 (rough estimate)
refractive index	n20/D 1.6192(lit.)
Flash point	>230 °F
storage temp.	Sealed in dry,Room Temperature
solubility	Chloroform (Sparingly), Dichloromethane (Slightly), Methanol (Slightly)
form	Liquid After Melting
color	Clear yellow to brown
BRN	1101012
InChI	InChI=1S/C12H9N/c13-9-8-11-6-3-5-10-4-1-2-7-12(10)11/h1-7H,8H2
InChIKey	OQRMWUNUKVUHQO-UHFFFAOYSA-N
SMILES	C1(CC#N)=C2C(C=CC=C2)=CC=C1
CAS DataBase Reference	132-75-2(CAS DataBase Reference)
EWG's Food Scores	1
FDA UNII	OV0P82P2R0
NIST Chemistry Reference	1-Naphthaleneacetonitrile(132-75-2)
EPA Substance Registry System	1-Naphthaleneacetonitrile (132-75-2)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS06,GHS07

Signal word

Warning

Hazard statements

H302-H312-H315-H319-H332-H335-H331

Precautionary statements

P261-P280-P305+P351+P338-P304+P340-P405-P501a

Hazard Codes

Risk Statements

20/21/22-36/37/38-22

Safety Statements

26-37/39-24/25-37-36

RIDADR

3276

WGK Germany

RTECS

AM1240000

TSCA

TSCA listed

HazardClass

6.1

PackingGroup

III

HS Code

29269090

Toxicity

mouse,LD50,intravenous,180mg/kg (180mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#03835,

REACH Registrations

Inactive

NFPA 704

	1
2		0

1-Naphthylacetonitrile price More Price(41)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
TCI Chemical	N0366	1-Naphthylacetonitrile >98.0%(GC)	132-75-2	25g	$87	2026-04-30	Buy
TCI Chemical	N0366	1-Naphthylacetonitrile >98.0%(GC)	132-75-2	500g	$691	2026-04-30	Buy
TRC	TRC-N377635-50G	2-(Naphthalen-1-yl)acetonitrile	132-75-2	50g	$101	2026-06-03	Buy
TRC	TRC-N377635-25G	2-(Naphthalen-1-yl)acetonitrile	132-75-2	25g	$90	2026-06-03	Buy
TRC	TRC-N377635-10G	2-(Naphthalen-1-yl)acetonitrile	132-75-2	10g	$70	2026-06-03	Buy

Product number	Packaging	Price	Buy
N0366	25g	$87	Buy
N0366	500g	$691	Buy
TRC-N377635-50G	50g	$101	Buy
TRC-N377635-25G	25g	$90	Buy
TRC-N377635-10G	10g	$70	Buy

1-Naphthylacetonitrile Chemical Properties,Uses,Production

Chemical Properties

White to yellow solid or melt. Insoluble in water.

Uses

2-(Naphthalen-1-yl)acetonitrile is useful for the preparation of tert-Bu benzoates.

Preparation

Synthesis of 1-naphthylacetonitrile: 695g of 1-chloromethyl naphthalene, 1500ml of methanol and 475ml of water, 350g of sodium cyanide mixture boiling reflux, stirring the reaction for 2h. 1300ml of methanol was evaporated, cooled, and the reactants were washed with water to neutral to obtain 670-680g of 1-naphthylacetonitrile.

Application

1-Naphthylacetonitrile is an organic synthesis intermediate. It is used in the synthesis of 1-naphthylacetate.

Synthesis Reference(s)

Chemical and Pharmaceutical Bulletin, 39, p. 3030, 1991 DOI: 10.1248/cpb.39.3030

1-Naphthylacetonitrile Preparation Products And Raw materials

Raw materials

Sodium cyanide

Preparation Products

1-Naphthaleneacetamide Naphazoline 1-Naphthaleneacethydrazide propyl 2-naphthalen-1-ylacetate ethyl 2-(naphthalen-1-yl)ethanecarboximidate hydrochloride

2-(1-Naphthyl)acetamidoxime Naphazoline nitrate

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1-Naphthylacetonitrile Suppliers

Global( 328)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Shanghai Boyle Chemical Co., Ltd.	021-50182298 021-50180596	sales@boylechem.com	China	2202	55
J & K SCIENTIFIC LTD.	18210857532 18210857532	jkinfo@jkchemical.com	China	96815	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	4006356688 18621169109	market03@meryer.com	China	40202	62
Alfa Aesar	400-6106006	saleschina@alfa-asia.com	China	30103	84
TCI (Shanghai) Development Co., Ltd.	021-67121386	Sales-CN@TCIchemicals.com	China	24512	81
Energy Chemical	400-0056266	sales8178@energy-chemical.com	China	44850	61
Capot Chemical Co., Ltd	+86 (0) 571 85 58 67 18		China	18187	66
JinYan Chemicals(ShangHai) Co.,Ltd.	13817811078	sales@jingyan-chemical.com	China	9963	60
Jia Xing Isenchem Co.,Ltd	0573-85285100 18627885956	isenchem@163.com	China	9389	66
Shandong Xiya Chemical Co., Ltd	13355009207 13355009207	3007715519@qq.com	China	18722	57

Supplier	Advantage
Shanghai Boyle Chemical Co., Ltd.	55
J & K SCIENTIFIC LTD.	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	62
Alfa Aesar	84
TCI (Shanghai) Development Co., Ltd.	81
Energy Chemical	61
Capot Chemical Co., Ltd	66
JinYan Chemicals(ShangHai) Co.,Ltd.	60
Jia Xing Isenchem Co.,Ltd	66
Shandong Xiya Chemical Co., Ltd	57

View Lastest Price from 1-Naphthylacetonitrile manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2026-09-11	1-Naphthylacetonitrile 132-75-2		1KG	98%min	30tons/month	WUHAN FORTUNA CHEMICAL CO., LTD
2026-09-02	1-Naphthylacetonitrile 132-75-2	$1.00-122.00	1KG	99%		Henan Fengda Chemical Co., Ltd
2025-06-27	1-Naphthylacetonitrile 132-75-2		1KG	99%	500000kg	Hebei Chuanghai Biotechnology Co., Ltd

1-Naphthylacetonitrile
132-75-2
$0.00
98%min
WUHAN FORTUNA CHEMICAL CO., LTD

1-Naphthylacetonitrile
132-75-2
$1.00-122.00
99%
Henan Fengda Chemical Co., Ltd

1-Naphthylacetonitrile
132-75-2
$0.00
99%
Hebei Chuanghai Biotechnology Co., Ltd

1-Naphthylacetonitrile Spectrum

1-Naphthyl acetonitrile(132-75-2)MS 1-Naphthyl acetonitrile(132-75-2)¹HNMR 1-Naphthyl acetonitrile(132-75-2)IR1 1-Naphthyl acetonitrile(132-75-2)IR2

132-75-2(1-Naphthylacetonitrile )Related Search:

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1-Anthroyl cyanide 1-Naphthylmalononitrile 1-Naphthylacetonitrile 1-NAPHTHALENEACETONITRILE, alpha-(2-(N-ETHYL-N-METHYLAMINO)ETHYL)- 1-NAPHTHALENEACETONITRILE, alpha-(2-(DIMETHYLAMINO)ETHYL)-alpha-METHYL -

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(1-naphthyl)-acetonitril Acetonitrile, (1-naphthyl)- alpha-(1-naphthyl)acetonitrile a-naphthylacetonitrile ALPHA-NAPHTHYLACETONITRILE LABOTEST-BB LTBB001326 1-Naphthylene Acetonitrile 1-Naphtylacetonitrile 1-Naphthylacetonitrile97% 1-NAPHTHYLACETONITRILE 1-NAPHTHYLMETHYLCYANIDE 1-NAPHTHALENEACETONITRILE 45) 1-NAPHTHYL ACETONITILE A-NAPHTHALENEACETONITRILE (SEE 5049) 1-NAPHTHYLACETONITIRILE pure 1-Cyanomethylnaphthalene 2-(1-Naphthyl)acetonitrile Naphthalene-1-acetonitrile naphthalenyl-acetonitrile 1-Naphthyl acetonitr Naphazoline IMpurity C (1-Naphthyl Acetonitrile) 1-Naphthylacetonitrile, 97% 5GR naphthalen-1-ylacetonitrile 1-phthyl acetonitrile 1-NAPHTHALENEACETO Naphazoline Impurity 3(Naphazoline EP Impurity C) Naphazoline EP Impurity C ANNAFOMINA 1-Naphthylacetonitrile, 97.5% (Naphthalen-1-yl)acetonitrile (1-Na 1-Naphthylacetonitrile> Naphazoline EP Impurity C (1-Naphthyl Acetonitrile) 1-Naphthaleneacetonitrile(NAN) Naphazoline Impurity C 1-Naphthylacetonitrile pure Naphazoline Hydrochloride Impurity C Naphazoline Nitrate Impurity C Naphazoline Hydrochloride EP Impurity C Naphazoline Nitrate EP Impurity C (naphthalen-1-yl)acetonitrile (1-naphthylacetonitrile) Naphazoline Impurity 3 132-75-2 132-75-3 C10H7CH2CN C10 to C27 Building Blocks Cyanides/Nitriles Nitrogen Compounds Organic Building Blocks Naphthalene series intermediates Aromatic Nitriles Intermediates of Dyes and Pigments