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2-(4-Aminophenyl)-1H-benzimidazol-5-amine

CAS No.
7621-86-5
Chemical Name:
2-(4-Aminophenyl)-1H-benzimidazol-5-amine
Synonyms
APBIA;2-(4-AMINOPHENYL)-5-AMINOBENZIMIDAZOLE;5-Amino-2-(4-aminophenyl)benzimidazole;2-(4-aMinophenyl)-1H-benzo[d]iMidazol-5-aMine;5-amino-2-(4-aminophenyl)benzodiazol;5-Amino-2-(p-aminophenyl)benzimidazole;4-(5-Amino-1H-benzimidazole-2-yl)aniline;2-(4-aminophenyl)-1h-benzimidazol-5-amin;5-Amino-2-(4-aminophenyl)-benzimidazolee;2-(4-AMINOPHENYL)-1H-BENZIMIDAZOL-6-AMINE
CBNumber:
CB4674036
Molecular Formula:
C13H12N4
Molecular Weight:
224.26
MDL Number:
MFCD00451475
MOL File:
7621-86-5.mol
MSDS File:
SDS
Last updated:2026-05-28 01:13:46

2-(4-Aminophenyl)-1H-benzimidazol-5-amine Properties

Melting point 234.0 to 238.0 °C
Boiling point 355.66°C (rough estimate)
Density 1.2067 (rough estimate)
refractive index 1.5890 (estimate)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility DMSO (Slightly), Methanol (Slightly)
form Solid
pka 11.15±0.10(Predicted)
color Pale Beige to Pale Brown
λmax 335nm(EtOH)(lit.)
InChI InChI=1S/C13H12N4/c14-9-3-1-8(2-4-9)13-16-11-6-5-10(15)7-12(11)17-13/h1-7H,14-15H2,(H,16,17)
InChIKey XAFOTXWPFVZQAZ-UHFFFAOYSA-N
SMILES C1(C2=CC=C(N)C=C2)NC2=CC(N)=CC=C2N=1
EPA Substance Registry System 1H-Benzimidazol-5-amine, 2-(4-aminophenyl)- (7621-86-5)

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)Health Hazard (GHS08)
GHS07,GHS08
Signal word  Warning
Hazard statements  H315-H319-H335-H341
Precautionary statements  P280-P302+P352-P305+P351+P338
RTECS  DD5421200
TSCA  TSCA listed
HS Code  2933998090
Toxicity LD50 orl-rat: 5 g/kg GISAAA 43(9),23,78
NFPA 704
0
2 0

2-(4-Aminophenyl)-1H-benzimidazol-5-amine price More Price(32)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical A2759 5-Amino-2-(4-aminophenyl)benzimidazole >98.0%(HPLC) 7621-86-5 1g $40 2026-04-30 Buy
TCI Chemical A2759 5-Amino-2-(4-aminophenyl)benzimidazole >98.0%(HPLC) 7621-86-5 5g $161 2026-04-30 Buy
Biosynth HAA62186 5-Amino-2-(4-aminophenyl)benzimidazole 7621-86-5 0.25g $250 2026-06-04 Buy
Biosynth HAA62186 5-Amino-2-(4-aminophenyl)benzimidazole 7621-86-5 2.5g $855.5 2026-06-04 Buy
Apolloscientific OR323128 5-Amino-2-(p-aminophenyl)benzimidazole >98% 7621-86-5 5g $21 2026-06-04 Buy
Product number Packaging Price Buy
A2759 1g $40 Buy
A2759 5g $161 Buy
HAA62186 0.25g $250 Buy
HAA62186 2.5g $855.5 Buy
OR323128 5g $21 Buy

2-(4-Aminophenyl)-1H-benzimidazol-5-amine Chemical Properties,Uses,Production

Uses

2-(4-Aminophenyl)-1H-benzimidazol-5-amine is a useful as an aerogel lithium battery separator.

Description

2-(4-Aminophenyl)-1H-benzimidazol-5-amine (APBIA) is a synthetic raw material for the preparation of sulfonated polyimides containing benzimidazole (SPIBIs). The synthesised SPIBIs with polyhedral oligomeric silsesquioxane glycidyl ethers (G-POSS) can be used to prepare a number of novel organic-inorganic hybrid proton exchange membranes (PEMs). The obtained membranes exhibited good crosslink density at all gel fractions above 75%. The mechanical properties, oxidative stability and hydrolytic stability of the crosslinked membranes were significantly improved compared with those of pure SPIBI membranes.

Uses

2-(4-Aminophenyl)-1H-benzimidazol-5-amine is a useful as an aerogel lithium battery separator.

Synthesis Reference(s)

[1] Process for preparing 2-(4-aminophenyl)-5-amino-benzimidazole and substituted derivatives. US4417056A

Safety Profile

Low toxicity by ingestion. Whenheated to decomposition it emits toxic vapors of NOx.

Synthesis

In a process for the preparation of 2-(4-Aminophenyl)-1H-benzimidazol-5-amine and substituted derivatives thereof by cycloreduction of starting material N-(4-nitrobenzoyl)2,4-dinitroaniline or a substituted derivative thereof by means of hydrogen gas in the presence of a catalyst based on a metal belonging to Group VIII of the Periodic Classification of the elements.[1]

1772-39-0
7621-86-5
Synthesis of 2-(4-Aminophenyl)-1H-benzimidazol-5-amine from 5-nitro-2-(4-nitrophenyl)-1H-benzimidazole

2-(4-Aminophenyl)-1H-benzimidazol-5-amine Preparation Products And Raw materials

Global( 225)Suppliers
Supplier Tel Email Country ProdList Advantage
Nantong Root King Import&Export Co.,Ltd 13951333918 visonzou@hotmail.com China 207 58
CHINATECH(TIANJIN) CHEMICAL CO.,LTD. 18222205756 sales6@chinatechem.com China 100 58
Henan Vocas Biotechnology Co., Ltd 18537671377 vocas@foxmail.com China 5000 58
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Jia Xing Isenchem Co.,Ltd 0573-85285100 18627885956 isenchem@163.com China 9389 66
Shanghai Longsheng chemical Co.,Ltd. 58099637 13585536065 sales@shlschem.com China 9880 59
Nanjing Chemlin Chemical Co., Ltd 025-83697070 13770331960 info@chemlin.com.cn China 16305 64
TOKYO CHEMICAL INDUSTRY CO., LTD. 03-36680489 Sales-JP@TCIchemicals.com Japan 28364 80
TCI Europe 320-37350700 sales@tcieurope.eu Europe 23654 75
TCI AMERICA 800-4238616 sales@tciamerica.com Americas 23636 75

View Lastest Price from 2-(4-Aminophenyl)-1H-benzimidazol-5-amine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-(4-Aminophenyl)-1H-benzimidazol-5-amine pictures 2026-09-11 2-(4-Aminophenyl)-1H-benzimidazol-5-amine
7621-86-5
1KG 98%min 30tons/month WUHAN FORTUNA CHEMICAL CO., LTD
2-(4-aminophenyl)-3H-benzimidazol-5-amine pictures 2026-09-02 2-(4-aminophenyl)-3H-benzimidazol-5-amine
7621-86-5
$1.00-111.00 1KG 99% Henan Fengda Chemical Co., Ltd
2-(4-Aminophenyl)-1H- benzimidazol-5-amine (APBIA) pictures 2026-08-03 2-(4-Aminophenyl)-1H- benzimidazol-5-amine (APBIA)
7621-86-5
1Kg ≥99% 10TM CHINATECH(TIANJIN) CHEMICAL CO.,LTD.

2-(4-Aminophenyl)-1H-benzimidazol-5-amine Spectrum

2-(4-aminophenyl)-3H-benzimidazol-5-amine 2-(4-AMINOPHENYL)-1H-BENZIMIDAZOL-5-AMINE 2-(4-aminophenyl)-1h-benzimidazol-5-amin 2-(4-aminophenyl)-1H-benzimidazol-2-amine 2-(4-AMINOPHENYL)-1H-BENZIMIDAZOL-6-AMINE 1H-BenziMidazol-6-aMine,2-(4-aMinophenyl)- 5-Amino-2-(4-aminophenyl) 1H-benz-imidazole 2-(4-Aminophenyl)-3H-benzimidazole-5-amine 2-(4-Aminophenyl)-5-amino-1H-benzimidazole 4-(5-Amino-1H-benzimidazole-2-yl)aniline 6-Amino-2-(4-aminophenyl)-1H-benzimidazole 5-Amino-2-(p-aminophenyl)benzimidazole 2-(4-aMinophenyl)-1H-benzo[d]iMidazol-5-aMine 2-(4-aminophenyl)-1H-benzo[d]imidazol-6-amine 5-Amino-2-(4-aminophenyl)-benzimidazolee 5-Amino-2-(4-aminophenyl)benzimidazole > 2-(4-Aminophenyl)-1H- benzimidazol-5-amine (APBIA) TIANFU 7621-86-5 2-(4-Aminophenyl)-1H-benzimidazol-5-amine 2- (4-aminophenyl) -5-aminobenzimidazole (APBIA) 2-(4-minophenyl)-1,3-benzoxazo1-5- amine(APBIA) 2-(4-Aminophenyl)-1H- benzimidazol-5-amine(APBOA) 5-amino-2-(4-aminophenyl)benzodiazol 2-(4-Aminophenyl)-5-aminobenzo[d]imidazole 5-Amino-2-(4-aminophenyl)benzimidazole (APBIA) 2-(4-AMINOPHENYL)-5-AMINOBENZIMIDAZOLE 5-Amino-2-(4-aminophenyl)benzimidazole APBIA 7621-86-5 13766-47-6 API intermediates Intermediates of Dyes and Pigments