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2-(4-Aminophenyl)-1H-benzimidazol-5-amine

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2-(4-Aminophenyl)-1H-benzimidazol-5-amine Basic information
Uses
Product Name:2-(4-Aminophenyl)-1H-benzimidazol-5-amine
Synonyms:2-(4-aminophenyl)-3H-benzimidazol-5-amine;2-(4-AMINOPHENYL)-1H-BENZIMIDAZOL-5-AMINE;2-(4-aminophenyl)-1h-benzimidazol-5-amin;2-(4-aminophenyl)-1H-benzimidazol-2-amine;2-(4-AMINOPHENYL)-1H-BENZIMIDAZOL-6-AMINE;1H-BenziMidazol-6-aMine,2-(4-aMinophenyl)-;5-Amino-2-(4-aminophenyl) 1H-benz-imidazole;2-(4-Aminophenyl)-3H-benzimidazole-5-amine
CAS:7621-86-5
MF:C13H12N4
MW:224.26
EINECS:231-538-6
Product Categories:API intermediates;Intermediates of Dyes and Pigments
Mol File:7621-86-5.mol
2-(4-Aminophenyl)-1H-benzimidazol-5-amine Structure
2-(4-Aminophenyl)-1H-benzimidazol-5-amine Chemical Properties
Melting point 234.0 to 238.0 °C
Boiling point 355.66°C (rough estimate)
density 1.2067 (rough estimate)
refractive index 1.5890 (estimate)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility DMSO (Slightly), Methanol (Slightly)
form Solid
pka11.15±0.10(Predicted)
color Pale Beige to Pale Brown
λmax335nm(EtOH)(lit.)
InChIInChI=1S/C13H12N4/c14-9-3-1-8(2-4-9)13-16-11-6-5-10(15)7-12(11)17-13/h1-7H,14-15H2,(H,16,17)
InChIKeyXAFOTXWPFVZQAZ-UHFFFAOYSA-N
SMILESC1(C2=CC=C(N)C=C2)NC2=CC(N)=CC=C2N=1
EPA Substance Registry System1H-Benzimidazol-5-amine, 2-(4-aminophenyl)- (7621-86-5)
Safety Information
RTECS DD5421200
TSCA TSCA listed
HS Code 2933998090
ToxicityLD50 orl-rat: 5 g/kg GISAAA 43(9),23,78
MSDS Information
2-(4-Aminophenyl)-1H-benzimidazol-5-amine Usage And Synthesis
Uses2-(4-Aminophenyl)-1H-benzimidazol-5-amine is a useful as an aerogel lithium battery separator.
Description2-(4-Aminophenyl)-1H-benzimidazol-5-amine (APBIA) is a synthetic raw material for the preparation of sulfonated polyimides containing benzimidazole (SPIBIs). The synthesised SPIBIs with polyhedral oligomeric silsesquioxane glycidyl ethers (G-POSS) can be used to prepare a number of novel organic-inorganic hybrid proton exchange membranes (PEMs). The obtained membranes exhibited good crosslink density at all gel fractions above 75%. The mechanical properties, oxidative stability and hydrolytic stability of the crosslinked membranes were significantly improved compared with those of pure SPIBI membranes.
Uses2-(4-Aminophenyl)-1H-benzimidazol-5-amine is a useful as an aerogel lithium battery separator.
Synthesis Reference(s)[1] Process for preparing 2-(4-aminophenyl)-5-amino-benzimidazole and substituted derivatives. US4417056A
Safety ProfileLow toxicity by ingestion. Whenheated to decomposition it emits toxic vapors of NOx.
SynthesisIn a process for the preparation of 2-(4-Aminophenyl)-1H-benzimidazol-5-amine and substituted derivatives thereof by cycloreduction of starting material N-(4-nitrobenzoyl)2,4-dinitroaniline or a substituted derivative thereof by means of hydrogen gas in the presence of a catalyst based on a metal belonging to Group VIII of the Periodic Classification of the elements.[1]
2-(4-Aminophenyl)-1H-benzimidazol-5-amine Preparation Products And Raw materials
Raw materials2'',4'',4-Trinitrobenzanilide-->5-nitro-2-(4-nitrophenyl)-1H-benzimidazole
Tag:2-(4-Aminophenyl)-1H-benzimidazol-5-amine(7621-86-5) Related Product Information
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