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metamifop

CAS No.
256412-89-2
Chemical Name:
metamifop
Synonyms
MetaMifop 90%;(±)-Metamifop;(RS)-2-[4-[(6-Chloro-2-benzoxazolyl)oxy]phenoxy]-N-(2-fluorophenyl)-N-methylpropanamide;metamifop;Tetamifop;Metamifop 90%;Metamifop [iso];Metamifop, >=95%;Metamifop Solution, 100ppm;Metamifop@100 μg/mL in Acetonitrile
CBNumber:
CB4875172
Molecular Formula:
C23H18ClFN2O4
Molecular Weight:
440.85
MDL Number:
MFCD22577272
MOL File:
256412-89-2.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-07-31 15:25:14

metamifop Properties

Melting point 77-81℃
Boiling point 589.6±60.0 °C(Predicted)
Density 1.363±0.06 g/cm3(Predicted)
storage temp. 2-8°C
solubility Soluble in methanol, chloroform and dimethyl sulfoxide.
form Solid
pka 0.16±0.50(Predicted)
color Light Beige to Brown
Henry's Law Constant 1.6×101 mol/(m3Pa) at 25℃, MacBean (2012)
InChI InChI=1S/C23H18ClFN2O4/c1-14(22(28)27(2)20-6-4-3-5-18(20)25)29-16-8-10-17(11-9-16)30-23-26-19-12-7-15(24)13-21(19)31-23/h3-14H,1-2H3
InChIKey ADDQHLREJDZPMT-UHFFFAOYSA-N
SMILES C(N(C1=CC=CC=C1F)C)(=O)C(OC1=CC=C(OC2=NC3=CC=C(Cl)C=C3O2)C=C1)C
FDA UNII 7715VQZ28E

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)Environment (GHS09)
GHS07,GHS09
Signal word  Warning
Hazard statements  H317-H332-H400-H410
Precautionary statements  P261-P280g-P304+P340-P312a-P321-P501a
Hazard Codes  Xn,N
Risk Statements  20-43-50/53
Safety Statements  36/37-60-61
HazardClass  9
NFPA 704
1
2 0

metamifop price More Price(21)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical M3467 Metamifop 256412-89-2 200MG $76 2026-04-30 Buy
TCI Chemical M3467 Metamifop 256412-89-2 1G $230 2026-04-30 Buy
TRC TRC-M258745-25MG Metamifop 90% 256412-89-2 25mg $91 2026-06-03 Buy
TRC TRC-M258745-1G Metamifop 90% 256412-89-2 1g $696 2026-06-03 Buy
TRC TRC-M258745-100MG Metamifop 90% 256412-89-2 100mg $239 2026-06-03 Buy
Product number Packaging Price Buy
M3467 200MG $76 Buy
M3467 1G $230 Buy
TRC-M258745-25MG 25mg $91 Buy
TRC-M258745-1G 1g $696 Buy
TRC-M258745-100MG 100mg $239 Buy

metamifop Chemical Properties, Uses, Production

Chemical Properties

Chloroform, DMSO, Methanol

Uses

An aryloxyphenoxypropionate (AOPP) post-emergence herbicide that shows an exclusive whole plant safety to rice with a high control efficacy to annual grass weeds, especially barnyardgrass.

Definition

ChEBI: 2-{4-[(6-chloro-1,3-benzoxazol-2-yl)oxy]phenoxy}-N-(2-fluorophenyl)-N-methylpropanamide is a member of the class of 1,3-benzoxazoles that is 6-chloro-1,3-benzoxazol-2-ol in which the hydrogen of the hydroxy group at position 2 is substituted by a 4-({1-[(2-fluorophenyl)(methyl)amino]-1-oxopropan-2-yl}oxy)phenyl group. It is a member of 1,3-benzoxazoles, an organochlorine compound, an aromatic ether, a member of monofluorobenzenes and a tertiary carboxamide.

Production Methods

Metamifop is commercially produced through a multi-step synthesis involving aryloxyphenoxypropionate chemistry, starting with the preparation of key intermediates such as 6-chlorobenzoxazole and fluorophenyl derivatives. The process includes etherification of the benzoxazole with a phenol derivative, followed by amidation with N-methylpropanamide containing a fluorinated aromatic ring. These steps are carried out under controlled conditions using organic solvents and catalysts to ensure high yield and purity.

Mechanism of action

Acetyl CoA carboxylase inhibitor (ACCase) - distrupts fatty acid biosynthesis and lipid formation. Causes chlorosis leading to growth retardation

Pesticide Type

Herbicide

94050-90-5
256412-89-2
Synthesis of metamifop from (R)-(+)-2-(4-Hydroxyphenoxy)propionic acid

metamifop Preparation Products And Raw materials

Raw materials

Preparation Products

Global Suppliers ( 160)
Supplier Tel Email Country ProdList Advantage
Wuhan Hongde Yuexin Pharmatech Co.,Ltd 027-83850116 18164090116 whhdyxchem123@sina.com China 7702 58
Anhui Enrich Biotechnology Co., Ltd 17730023384 China 40 58
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Chembest Research Laboratories Limited 021-20908456 sales@BioChemBest.com China 5996 61
Beijing HwrkChemical Technology Co., Ltd 89508211 18501085097 sales.bj@hwrkchemical.com China 9409 55
Chemsky(shanghai)International Co.,Ltd. 021-50135380 shchemsky@sina.com China 32273 50
Shanghai T&W Pharmaceutical Co., Ltd. +86 21 61551611 China 9874 58
Huainan Kedi Chemical Factory 0554-2106669 sales1@kedichem.com China 4914 55
Shanghai Worldyang Chemical Co.,Ltd. 021-56795766 sales@worldyachem.com China 9475 58
Chengdu HuaXia Chemical Reagent Co. Ltd 400-1166-196 13458535857 cdhxsj@163.com China 13323 58

View Latest Price from metamifop manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
metamifop pictures 2026-07-14 metamifop
256412-89-2
1kg 99 20tons Qingdao Trust Agri Chemical Co.,Ltd
metamifop pictures 2026-05-15 metamifop
256412-89-2
$1.50 1g 99.0% Min 10 Tons Shaanxi Didu New Materials Co. Ltd
Metamifop pictures 2021-07-13 Metamifop
256412-89-2
$10.00-15.00 1KG 99%+ HPLC Zhuozhou Wenxi import and Export Co., Ltd
  • metamifop pictures
  • metamifop
    256412-89-2
  • $0.00
  • 99
  • Qingdao Trust Agri Chemical Co.,Ltd
  • metamifop pictures
  • metamifop
    256412-89-2
  • $1.50
  • 99.0% Min
  • Shaanxi Didu New Materials Co. Ltd
  • Metamifop pictures
  • Metamifop
    256412-89-2
  • $10.00-15.00
  • 99%+ HPLC
  • Zhuozhou Wenxi import and Export Co., Ltd

metamifop Spectrum

(2R)-2-[4-[(6-chloro-2-benzoxazolyl)oxy]phenoxy]-N-(2-fluorophenyl)-N-methylpropanamide metamifop Metamifop [iso] MetaMifop 90% 2-[4-[(6-Chloro-2-benzoxazolyl)oxy]phenoxy]-N-(2-fluorophenyl)-N-MethylpropanaMide 2-{4-[(5-chloro-1,3-benzoxazol-2-yl)oxy]phenoxy}-N-(2-fluorophenyl)-N-methylpropanamide (R)-2-(4-((5-chlorobenzo[d]oxazol-2-yl)oxy)phenoxy)-N-(2-fluorophenyl)-N-MethylpropanaMide MetaMifop((2R)-2-[4-[(6-Chloro-2-benzoxazolyl)oxy]phenoxy]-N-(2-fluorophenyl)-N-MethylpropanaMide Metamifop, >=95% (RS)-2-[4-[(6-Chloro-2-benzoxazolyl)oxy]phenoxy]-N-(2-fluorophenyl)-N-methylpropanamide (R)-2-(4-((6-Chlorobenzo[d]oxazol-2-yl)oxy)phenoxy)-N-(2-fluorophenyl)-N-methylpropanamide 2-[4-(6-Chlorobenzo[d]oxazol-2-yloxy)phenoxy]-N-(2-fluorophenyl)-N-methylpropionamide Metamifop Solution, 100ppm (2R)-2-[4-[(6-chloro-1,3-benzoxazol-2-yl)oxy]phenoxy]-N-(2-fluorophenyl)-N-methylpropanamide 2-(4-((6-Chlorobenzo[d]oxazol-2-yl)oxy)phenoxy)-N-(2-fluorophenyl)-N-methylpropanamide Metamifop@100 μg/mL in Acetonitrile Metamifop@1000 μg/mL in Acetonitrile Propanamide, 2-[4-[(6-chloro-2-benzoxazolyl)oxy]phenoxy]-N-(2-fluorophenyl)-N-methyl- 2-[4-(6-Chlorobenzo[d]oxazol-2-yloxy)phenoxy]-N-(2-fluorophenyl)-N-methylpropionamide,97% Tetamifop (2S)-2-[4-[(6-chloro-1,3-benzoxazol-2-yl)oxy]phenoxy]-N-(2-fluorophenyl)-N-methylpropanamide (±)-Metamifop Metamifop 90% 256412-89-2 114411-34-2 C23H18ClFN2O4 Agro-Products Aromatics Heterocycles Intermediates & Fine Chemicals Pharmaceuticals