2-Chloro-6-methoxyisonicotinic acid
- CAS No.
- 15855-06-8
- Chemical Name:
- 2-Chloro-6-methoxyisonicotinic acid
- Synonyms
- BUTTPARK 43\57-34;TIMTEC-BB SBB005427;2-Chloro-6-methoxypyridine-4-c;2-Chloro-6-methoxyisonicotinicaci;2-CHLORO-6-METHOXYISONICOTINIC ACID;2-Chloro-6-methoxy-4-pyridinecarboxylic acid;2-CHLORO-6-METHOXYPYRIDINE-4-CARBOXYLIC ACID;4-Pyridinecarboxylic acid, 2-chloro-6-methoxy-;2-Chloro-6-methoxyisonicotinic acid ISO 9001：2015 REACH;2-Chloro-6-methoxypyridine-4-carboxylic acid, 4-Carboxy-2-chloro-6-methoxypyridine
- CBNumber:
- CB5255740
- Molecular Formula:
- C7H6ClNO3
- Molecular Weight:
- 187.58
- MDL Number:
- MFCD00173928
- MOL File:
- 15855-06-8.mol
- MSDS File:
- SDS
| Melting point | 214 °C |
|---|---|
| Boiling point | 209-213℃ |
| Density | 1.430±0.06 g/cm3(Predicted) |
| storage temp. | Store at room temperature |
| pka | 2.88±0.10(Predicted) |
| form | powder |
| color | White |
| InChI | 1S/C7H6ClNO3/c1-12-6-3-4(7(10)11)2-5(8)9-6/h2-3H,1H3,(H,10,11) |
| InChIKey | PJQBTHQTVJMCFX-UHFFFAOYSA-N |
| SMILES | COc1cc(cc(Cl)n1)C(O)=O |
| CAS DataBase Reference | 15855-06-8(CAS DataBase Reference) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P305+P351+P338 | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Gloves | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-36/37/39-37/39-36/37 | |||||||||
| WGK Germany | 3 | |||||||||
| HazardClass | IRRITANT | |||||||||
| HS Code | 2933399990 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
|||||||||
| NFPA 704 |
|
2-Chloro-6-methoxyisonicotinic acid price More Price(62)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 700614 | 2-Chloro-6-methoxypyridine-4-carboxylic acid | 15855-06-8 | 1g | $107 | 2023-01-07 | Buy |
| AstaTech | 57243 | 2-CHLORO-6-METHOXYISONICOTINIC ACID 97% | 15855-06-8 | 1G | $55 | 2026-04-30 | Buy |
| AstaTech | 57243 | 2-CHLORO-6-METHOXYISONICOTINIC ACID 97% | 15855-06-8 | 5G | $165 | 2026-04-30 | Buy |
| AstaTech | 57243 | 2-CHLORO-6-METHOXYISONICOTINIC ACID 97% | 15855-06-8 | 25G | $495 | 2026-04-30 | Buy |
| Matrix Scientific | 024693 | 2-Chloro-6-methoxyisonicotinic acid | 15855-06-8 | 5.00g | $89 | 2026-05-18 | Buy |
2-Chloro-6-methoxyisonicotinic acid Chemical Properties, Uses, Production
Synthesis
67-56-1
5398-44-7
15855-06-8
a) 2,6-Dichloroisonicotinic acid (200 g, 1.04 mol) was dissolved in methanol (3 L) and 32% aqueous sodium hydroxide solution (770 mL) was added. The stirred mixture was heated to 34°C, then warmed to 70°C and kept at this temperature for 4 hours of reaction. After the reaction was completed, it was cooled to room temperature. The reaction mixture was neutralized with 32% aqueous hydrochloric acid solution (100 mL) and 25% aqueous hydrochloric acid solution (700 mL). The mixture was stirred at room temperature overnight. The white precipitate formed was collected by filtration, washed with methanol and dried. The filtrate was evaporated and the residue was suspended in water (200 mL). The resulting mixture was heated to 60 °C and the solid product was collected, washed with water and dried. All products were combined to give 2-chloro-6-methoxyisonicotinic acid (183 g) as a white solid; LC-MS: t R = 0.80 min, [M + 1] + = 187.93.
References
[1] Tetrahedron, 2002, vol. 58, # 34, p. 6951 - 6963
[2] Organic Letters, 2000, vol. 2, # 22, p. 3421 - 3423
[3] Patent: WO2011/7324, 2011, A1. Location in patent: Page/Page column 20
[4] Patent: US2012/108638, 2012, A1. Location in patent: Page/Page column 8
[5] Patent: US2013/303514, 2013, A1. Location in patent: Paragraph 0192
2-Chloro-6-methoxyisonicotinic acid Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Wuhan Chemwish Technology Co., Ltd | 86-027-67849912 | sales@chemwish.com | China | 35884 | 56 |
| Jia Xing Isenchem Co.,Ltd | 0573-85285100 18627885956 | isenchem@163.com | China | 9389 | 66 |
| Adamas Reagent, Ltd. | 400-6009262 15618770481 | yhx@titansci.com | China | 14098 | 59 |
| Accela ChemBio Co.,Ltd. | 021-50795510 4000665055 | marketing@accelachem.com | China | 10972 | 64 |
| Record Tech (Shanghai) Co., LTD | 13761627472 | 183009664@qq.com | China | 659 | 62 |
| China Langchem Inc. | 0086-21-58956006 | China | 7798 | 57 | |
| Hunan Hui Bai Shi Biotechnology Co., Ltd. | 0731-85526065 13308475853 | ivy@hnhbsj.com | China | 7236 | 62 |
View Latest Price from 2-Chloro-6-methoxyisonicotinic acid manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-08-20 | 2-Chloro-6-methoxyisonicotinic acid
15855-06-8
|
$1.10 | 1g | 99.00% | 100 Tons Min | Dideu Industries Group Limited | |
 |
2020-01-01 | 2-Chloro-6-methoxyisonicotinic acid
15855-06-8
|
$1.00 | 1KG | 99% | 100KG | Career Henan Chemical Co |
-
- 2-Chloro-6-methoxyisonicotinic acid
15855-06-8
- $1.10
- 99.00%
- Dideu Industries Group Limited
-
- 2-Chloro-6-methoxyisonicotinic acid
15855-06-8
- $1.00
- 99%
- Career Henan Chemical Co
15855-06-8 (2-Chloro-6-methoxyisonicotinic acid) Related Search:
1of4
