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2-(Trifluoromethoxy)bromobenzene

2-(Trifluoromethoxy)bromobenzene Structure
2-(Trifluoromethoxy)bromobenzene structure
CAS No.
64115-88-4
Chemical Name:
2-(Trifluoromethoxy)bromobenzene
Synonyms
1-BROMO-2-(TRIFLUOROMETHOXY)BENZENE;1-Bromo-2-(trifL;light yellow liquid,bp185;2-(TRIFLUOROMETHOXY)BENZENE;O-TRIFLUOROMETHOXYBROMOBENZENE;2-(Trifluoromethoxy)bromobenze;O-BROMO(TRIFLUOROMETHOXY)BENZENE;2-BROMO(TRIFLUOROMETHOXY)BENZENE;2-(TRIFLUOROMETHOXY)BROMOBENZENE;2-(trifluoromrthoxy)bromobenzene
CBNumber:
CB5299205
Molecular Formula:
C7H4BrF3O
Molecular Weight:
241.01
MDL Number:
MFCD00040942
MOL File:
64115-88-4.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 02:35:54
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2-(Trifluoromethoxy)bromobenzene Properties

Boiling point 158-160 °C(lit.)
Density 1.62 g/mL at 25 °C(lit.)
refractive index n20/D 1.464(lit.)
Flash point 140 °F
storage temp. Sealed in dry,Room Temperature
form clear liquid
color Colorless to Light yellow
BRN 1947768
InChI 1S/C7H4BrF3O/c8-5-3-1-2-4-6(5)12-7(9,10)11/h1-4H
InChIKey ITYCJCVRPBLODP-UHFFFAOYSA-N
SMILES FC(F)(F)Oc1ccccc1Br
CAS DataBase Reference 64115-88-4(CAS DataBase Reference)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Flame (GHS02)Exclamation Mark (GHS07)
GHS02,GHS07
Signal word  Warning
Hazard statements  H226-H315-H319-H335
Precautionary statements  P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a
PPE Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36/37/39-37
RIDADR  UN1993
WGK Germany  3
Hazard Note  Irritant
HazardClass  3
PackingGroup  III
HS Code  29093090
Storage Class 3 - Flammable liquids
Hazard Classifications Flam. Liq. 3
Limited Quantities 5.0 L (1.3 gallons) (liquid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
NFPA 704
2
2 0

2-(Trifluoromethoxy)bromobenzene price More Price(54)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 553891 1-Bromo-2-(trifluoromethoxy)benzene 97% 64115-88-4 5g $41.6 2022-05-15 Buy
TCI Chemical T2147 1-Bromo-2-(trifluoromethoxy)benzene >98.0%(GC) 64115-88-4 5g $17 2026-04-30 Buy
TCI Chemical T2147 1-Bromo-2-(trifluoromethoxy)benzene >98.0%(GC) 64115-88-4 25g $27 2026-04-30 Buy
Apolloscientific PC7438UY 1-Bromo-2-(trifluoromethoxy)benzene 99% 64115-88-4 50g $25 2026-06-04 Buy
Apolloscientific PC7438UY 1-Bromo-2-(trifluoromethoxy)benzene 99% 64115-88-4 100g $45 2026-06-04 Buy
Product number Packaging Price Buy
553891 5g $41.6 Buy
T2147 5g $17 Buy
T2147 25g $27 Buy
PC7438UY 50g $25 Buy
PC7438UY 100g $45 Buy

2-(Trifluoromethoxy)bromobenzene Chemical Properties,Uses,Production

Uses

1-Bromo-2-(trifluoromethoxy)benzene can be prepared from (trifluoromethoxy)benzene.

General Description

1-Bromo-2-(trifluoromethoxy)benzene can be prepared from (trifluoromethoxy)benzene.

Synthesis

trifluoromethyl benzoate

1035797-66-0

2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE

88284-48-4

2-(Trifluoromethoxy)bromobenzene

64115-88-4

In a glove box, KF (78.4 mg, 1.35 mmol, 4.5 eq.) was added to a 20 mL polyethylene (PE) plastic tube. Subsequently, dicyclohexane-18-crown-6 (503 mg, 1.35 mmol, 4.5 eq.) and 6. Next, ethylidene precursor (0.3 mmol, 1.0 eq.), 1-bromophenylacetylene (218 mg, 1.2 mmol, 4.0 eq.) or perfluorohexyl bromide (479 mg, 1.2 mmol, 4.0 eq.) or pentafluorophenyl bromide ( 296 mg, 1.2 mmol, 4.0 equiv) and trifluoromethyl benzoate (171 mg, 0.9 mmol, 3.0 equiv). The reaction tube was sealed and the reaction was carried out at room temperature for 12 hours. At the end of the reaction, the F-spectral yield was first determined by 19F NMR. Finally, the reaction mixture was filtered, dried and purified directly by column chromatography.

References

[1] Patent: CN108516935, 2018, A. Location in patent: Paragraph 0166; 0167; 0168; 0169; 0170; 0171
[2] Journal of the American Chemical Society, 2018, vol. 140, # 22, p. 6801 - 6805

2-(Trifluoromethoxy)bromobenzene Preparation Products And Raw materials

Raw materials

trifluoromethyl benzoate 2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE Potassium fluoride Dicyclohexano-18-crown-6 (Bromoethynyl)benzene
Bromopentafluorobenzene Ethyl acetate

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Preparation Products

2-(Trifluormethoxy)phenylboronic acid 2-(Trifluoromethoxy)aniline 3-(Trifluoromethoxy)bromobenzene 3-Bromo-4-trifluoromethoxybenzenesulfonyl chloride

2-(Trifluoromethoxy)bromobenzene Suppliers

Global( 304)Suppliers
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
TAIYUAN RHF CO.,LTD. +86 351 7031519 sales@RHFChem.com China 2334 56
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
ShangHai DEMO Chemical Co.,Ltd 400-021-7337 2355568890 sales@demochem.com China 2569 57
Shijiazhuang Sdyano Fine Chemical Co., Ltd. 0311-89250318 13582355795 master@sjzsdyn.com China 2776 65
Wuhan Chemwish Technology Co., Ltd 86-027-67849912 sales@chemwish.com China 35884 56
Capot Chemical Co., Ltd +86 (0) 571 85 58 67 18 China 18187 66
Beijing Ouhe Technology Co., Ltd 13552068683 13522913783 2355560935@qq.com China 11777 60
Supplier Advantage
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
Alfa Aesar 84
TAIYUAN RHF CO.,LTD. 56
TCI (Shanghai) Development Co., Ltd. 81
ShangHai DEMO Chemical Co.,Ltd 57
Shijiazhuang Sdyano Fine Chemical Co., Ltd. 65
Wuhan Chemwish Technology Co., Ltd 56
Capot Chemical Co., Ltd 66
Beijing Ouhe Technology Co., Ltd 60

View Lastest Price from 2-(Trifluoromethoxy)bromobenzene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-(Trifluoromethoxy)bromobenzene pictures 2026-09-02 2-(Trifluoromethoxy)bromobenzene
64115-88-4
 $1.00-100.00 1KG 99% Henan Fengda Chemical Co., Ltd
2-(Trifluoromethoxy)bromobenzene pictures 2026-02-02 2-(Trifluoromethoxy)bromobenzene
64115-88-4
 10mg 99% 2000tons Shaanxi Dideu Medichem Co. Ltd
2-(Trifluoromethoxy)bromobenzene pictures 2023-11-03 2-(Trifluoromethoxy)bromobenzene
64115-88-4
 $10.00 1kg 99% 100T Anhui Zhongda Biotechnology Co., Ltd

2-(Trifluoromethoxy)bromobenzene Spectrum

2-(Trifluoromethoxy)bromobenzene(64115-88-4)1HNMR2-(Trifluoromethoxy)bromobenzene(64115-88-4)FT-IR

64115-88-4(2-(Trifluoromethoxy)bromobenzene)Related Search:

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1-Bromo-2-(trifluoromethoxy)benzene 99% 2-Bromo-alpha,alpha,alpha-trifluoroanisole, 2-Bromophenyl trifluoromethyl ether 2-BroMo-1-(trifluoroMethoxy)benzene Dibromoethoxychlorophosphonazo Trifluoromethoxybenzene Adjacent Bromine Trifluoride Mathoxyphenyl 2-(TRIFLUOROMETHOXY)BENZENE 2-(TRIFLUOROMETHOXY)BROMOBENZENE 2-BROMO(TRIFLUOROMETHOXY)BENZENE 2-BROMO-ALPHA,ALPHA,ALPHA-TRIFLUOROANISOLE O-TRIFLUOROMETHOXYBROMOBENZENE O-BROMO(TRIFLUOROMETHOXY)BENZENE 2-(trifluoromrthoxy)bromobenzene 1-Bromo-2-(trifluoromathoxy)Benzene 2-(Trifluoromethoxy)bromobenze 2-(Trifluoromethoxy)bromobenzene 99% 2-(Trifluoromethoxy)bromobenzene99% 1-BROMO-2-(TRIFLUOROMETHOXY)BENZENE / 2-BROMO-TRIFLUOROMETHOXYBENZENE 2-(trifluoromethoxy)bromobenzene,1-bromo-2-(trifluoromethoxy)benzene 2-Bromo-6-(trifluoromethyl)anisole 1-BroMo-2-(trifluoroMethoxy)benzen1-BroMo-2-(trifluoroMethoxy)benzen 2-Bromo-alpha,alpha,alpha-trifluoroanisole, 1-Bromo-2-(trifluoromethoxy)benzene, 2-Bromophenyl trifluoromethyl ether light yellow liquid,bp185 1-Bromo-2-(trifL Benzene, 1-bromo-2-(trifluoromethoxy)- 2-(Trifluoromethoxy)bromobenzene ISO 9001：2015 REACH TIANFUCHEM--64115-88-4--2-(Trifluoromethoxy)bromobenzene Ortho bromotrifluoromethoxybenzene 1-BROMO-2-(TRIFLUOROMETHOXY)BENZENE 64115-88-4 641115-88-4 ARYL HALIDE Ethers Organic Building Blocks Oxygen Compounds Building Blocks Pyridines alkyl bromide Fluorobenzene Aromatic Halides (substituted) Trifluoroanisole series Miscellaneous Ethers Organic Building Blocks Oxygen Compounds