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[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Structure
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) structure
CAS No.
72287-26-4
Chemical Name:
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
Synonyms
PDCL2(DPPF);pddppfcl2;Pd（dppf）;Pd(dppf)Cl;dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2;(DPPF)PdCl2;(dppf)2PdCl2;dichloropalladiuM;1,1-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II);1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
CBNumber:
CB3276259
Molecular Formula:
C34H28Cl2FeP2Pd
Molecular Weight:
731.7
MDL Number:
MFCD00015757
MOL File:
72287-26-4.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-06-17 08:00:12
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[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Properties

Melting point 275-280 °C(lit.)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility Soluble in dichloromethane.
form powder
color red to very dark red
Stability Hygroscopic
InChI InChI=1S/2C17H11P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-6,9-12,18H;2*1H;;/q;;;;+2;/p-2
InChIKey LMSWLYFMTLONFK-UHFFFAOYSA-L
SMILES [Cl-][Pd+2]1(P(C2C=CC=CC=2)(C2C=CC=CC=2)[C-]23C4=C5C6=C2[Fe+2]27893456C3C2=C7[C-]8(C9=3)P1(C1C=CC=CC=1)C1C=CC=CC=1)[Cl-]
UNSPSC Code 12352103
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Hazard Codes  Xn,Xi
Risk Statements  20/21/22-36/37/38-40
Safety Statements  23-24/25-26-36/37
WGK Germany  3
TSCA  No
HazardClass  IRRITANT
HS Code  28439000
Storage Class 6.1D - Non-combustible acute toxic Cat.3
toxic hazardous materials or hazardous materials causing chronic effects
Hazard Classifications Carc. 1B Inhalation
REACH Registrations Inactive

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) price More Price(83)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 697230 [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 72287-26-4 1g $81.5 2026-04-30 Buy
Sigma-Aldrich 697230 [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 72287-26-4 5g $250 2026-04-30 Buy
Sigma-Aldrich 697230 [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 72287-26-4 25 g $1040 2026-04-30 Buy
Sigma-Aldrich 697230 [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 72287-26-4 1 unit $981 2025-07-31 Buy
Usbiological 262019 [1,1'-Bis(diphenylphosphino)ferrocene]-dichloropalladium (II) 72287-26-4 1g $326 2026-06-03 Buy
Product number Packaging Price Buy
697230 1g $81.5 Buy
697230 5g $250 Buy
697230 25 g $1040 Buy
697230 1 unit $981 Buy
262019 1g $326 Buy

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Chemical Properties, Uses, Production

Uses

[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), is a palladium catalyst used in chemical synthesis of various compounds. Is used in preparation of Nucleosides as Ectonucleotidase inhibitors.

Chemical Properties

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) is Red solid

Uses

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) is used as a catalyst for Suzuki and Stile couplings.

Uses

Catalyst for C-C and C-N coupling reaction.

Uses

suzuki reaction

Application

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) may be used as an effective palladium catalyst in the following reactions:
Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.
Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives.
Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

Mechanism of action

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (pd(dppf)cl2) catalysis has gained widespread use in industrial and academic synthetic chemistry laboratories as a powerful methodology for the formation of C-C and C-Heteroatom bonds.
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) uses
R = usually sp2 hybridised carbon
X = usually I, Br, Cl or OTf
The nature of R' and M are dependant upon
the specic coupling being performed

Synthesis

A method for the preparation of 1,1'-bis(diphenylphosphino)ferrocene palladium dichloride II (dppfPdCl2) comprising the steps of:

(a) adding palladium chloride to concentrated hydrochloric acid, heating to 40-80C to dissolve, the amount of hydrochloric acid is 0.2-1.0 times the mass of palladium chloride, diluting with ethanol, the amount of ethanol is 10-50 times the mass of palladium chloride;

(b) bis-diphenylphosphinoferrocene (dppf) 3.0-5.0 times the mass of palladium chloride is added to a solution of tetrahydrofuran and heated to 40-80C until dissolved, and the amount of tetrahydrofuran is 20-30 times the mass of palladium chloride;

(c) the solution obtained in step (a) was added dropwise to the solution obtained in step (b), and after the dropwise addition was completed, it was held at 45-80C for 0.5-3h, and then cooled, filtered, washed, and dried in vacuum, to obtain 1,1'-bis(diphenylphosphino)ferrocene palladium dichloride II red crystals.

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) synthesis

12150-46-8
90243-59-7
72287-26-4
Synthesis of [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) from 1,1'-Bis(diphenylphosphino)ferrocene and Palladium, bis(acetonitrile)dichloro-, (SP-4-2)-

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Preparation Products And Raw materials

Raw materials

Acetonitrile Ethanol 1,1'-Bis(diphenylphosphino)ferrocene Toluene Palladium chloride
Dichloromethane Methanol Lithium chloride

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Preparation Products

Vanadyl acetylacetonate 4-Amino-3-methoxyphenylboronic acid, pinacol ester 4-Nitrophenylboronic acid 3-Morpholinophenylboronic acid pinacol ester 2-Ethoxycarbonylphenylboronic acid pinacol ester

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Suppliers

Global Suppliers ( 543)
Supplier Tel Email Country ProdList Advantage
Wuhan Taiyu New Materials Co., Ltd. 18627786697 tyxcchem@163.com China 92 58
Wuhan Tuochuangda Technology Co., LTD 18627850571 tuochuangda@163.com China 89 58
Shaanxi Rock New Materials Co., Ltd. 0917-8888777 18691786767 liuwei@bjrock.com China 309 62
WuHan Taiyukaishang Chemical Co., Ltd. 027-027-87680032 18963957250 taiyuchem@163.com China 180 55
Beijing Guofang Dingsheng Technology Co., Ltd. 18610472091 gfdskj@163.com China 496 58
Wuhan Huahan Dingcheng New Material Technology Co., Ltd 18963961905 huahandingcheng@sina.com China 484 58
Tianjin heowns Biochemical Technology Co., Ltd. 400-6387771-6039 18920764717 sales@heowns.com China 24636 60
Wuhan Jiade Ruifeng New Materials Co., Ltd 18271874579 / 18971104330 18971104330 Xiaowei@JDchem.com.cn China 268 58
Luoyang Heyi New Materials Co., Ltd 13674998441 18203623319 12409005@qq.com China 17 58
Anhui Weihe Chemical Technology Co., Ltd. 13505592528 13505592528 49141484@qq.com China 2671 58
Supplier Advantage
Wuhan Taiyu New Materials Co., Ltd. 58
Wuhan Tuochuangda Technology Co., LTD 58
Shaanxi Rock New Materials Co., Ltd. 62
WuHan Taiyukaishang Chemical Co., Ltd. 55
Beijing Guofang Dingsheng Technology Co., Ltd. 58
Wuhan Huahan Dingcheng New Material Technology Co., Ltd 58
Tianjin heowns Biochemical Technology Co., Ltd. 60
Wuhan Jiade Ruifeng New Materials Co., Ltd 58
Luoyang Heyi New Materials Co., Ltd 58
Anhui Weihe Chemical Technology Co., Ltd. 58

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View Latest Price from [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) manufacturers

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[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) pictures 2026-09-02 [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
72287-26-4
 $1.00-100.00 1KG 99% Henan Fengda Chemical Co., Ltd
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) pictures 2026-08-21 [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
72287-26-4
 $80.00 10kilograms 99 10 Hebei Dangtong Import and export Co LTD
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) pictures 2026-06-30 [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
72287-26-4
 1KG 98 10000KGS Shaanxi Dideu New Materials Co. Ltd

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Spectrum

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)(72287-26-4)1HNMR[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)(72287-26-4)31PNMR[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)(72287-26-4)FT-IR

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Dichloro(1,1'-bis(diphenylphosphino)ferrocene)palladium (II) dichloromethane add 1,1'-Bis(diphenylphosphino)ferroceneüpalladium(II) chloride, 1:1 complex with dichloromethane 1,1'-Bis(diphenylphosphino)ferrocene palladium dichloride ,99% [1,1'-Bis(diphenylphosphino)ferrocene]dichloropall 1,1'-Bis(diphenylphosphino)ferrocene-palladium dichloride,98% 1,1'-Bis(diphenylphosphino)ferrocene palladium(II)dichloride [Pd(dppf)Cl2] 1'-Bis(diphenylphosphino)ferrocene-palladiuM(II) dichloride 1,1'-Bis(diphenylphosphino)ferrocene palladium dichloride ,99.9% [1,1′-Bis(diphenylph JACS-72287-26-4 dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(ii) dichloromethane complex (1:1) -Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 1,1-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II): 99.9% (II)dichloromethane adduct 1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane Palladium, 1,1-bis(diphenylphosphino-.kappa.P)ferrocenedichloro-, (SP-4-2)- [1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(ii) dichloromethane complex (1:1) [1,1'-bis(diphenylphosphino)ferrocene]palladium(ii) dichloride dichloromethane complex (1:1) (1,1'-Bis(diphenylphosphimoferrocene)dichloropalladium (II)-CH2CL2 [1,1-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADI Palladium(II) chloride-1,1’-bis(diphenylphosphino)ferrocene,complex with CH2Cl2 [1,1''-Bis-(diphenylphosphino)-ferrocene]-palladous dichloride [1,1''-Bis(diphenyphosphino)ferrocene]dichloropalladium(II) [1,1’-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) PdCl2(dppf) 1,1''-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADIUM() COMPLEX WITH DICHLOROMETHANE (1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE)-P ALLADIUM(II) CHLORIDE CH2CL2 COMPL DICHLORO-((BIS-DIPHENYLPHOSPHINO)FERROCENYL)-PALLADIUM(II) 1,1'-Bis(diphenylphosphino)ferrocenepalladiuM( II) dichloride Pd DICHLORO-((BIS-DIPHENYLPHOSPHINO)FERROCENYL)-PALLADIUM(II) DICHLOROMETHANE ADDUCT [1,1'-Bis(diphenylphosphino)ferrocen]dichloropalladiuM(II), coMplex with dichloroMethane -Bis(diphenylphosphino)ferrocene-palladiuM(II)dichloride dichloroMethane coMplex 1,1'-Bis(diphenylphosphiNA)ferrocene palladiuM(II)dichloride Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladiuM(II), (DPPF)PdCl2 [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(Ⅱ) [1,1'-Bis(diphenylphosphino)ferrocene]Pd(II)Cl2 CHEMWISH IC30255 1,1'-Bis(diphenylphosphino)ferrocene palladiuM(II)dichlorid (Diphenylphosphino)Ferrocene PalladiuM Dichlorid 1,1'-BIS(DIPHENYLPHOSPHINO) 1,1'-BIS(DIPHENYLPHOSP [1,1&prime 1'1-Bis(diphenylphosphino)fewocene palladium(Ⅱ)chloride [1,1’-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (Pd(dppf)Cl2) [1,1'-Bis(diphenyL oropaL phosphino)ferrocene]dichL 1,1 '- bis (diphenylphosphino) ferrocene palladium dichloride (II) 1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)，Pd 14.5% Diphenylphosphinoferrocene dichloropalladium 1’1-Bis(diphenylphosphino)fewocene Palladium(Ⅱ)chloride [1,1 '- bis (diphenylphosphonyl) ferrocene] palladium dichloride [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Basic information 1,1'-Bis(diphenylphosphino)ferrocene - dichloropalladium (1:1) Palladium, [1,?1'-?bis(diphenylphosphin?o-?κP)?ferrocene]?dichloro-?, (SP-?4-?2)?- Pd(DPPF) Dichloride [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)(72287-26-4) DICHLORO [ (1,1 - BIS DIPHENYLPHOSPHINO FERROCENE) ] PALLADIUM - (II) For Synthesis Dichloro[1,1'-ferrocenylbis- (diphenylphosphane)]palladium(II)