ChemicalBook >> CAS DataBase List >>1-Bromo-2-nitrobenzene
1-Bromo-2-nitrobenzene
- CAS No.
- 577-19-5
- Chemical Name:
- 1-Bromo-2-nitrobenzene
- Synonyms
- 2-BROMONITROBENZENE;O-NITROBROMOBENZENE;1-BroMo-2-;2-Nitrobromobenzene;2-Nitrophenyl bromide;1-Bromo-2-Nitrobenene;Benzene,1-bromo-2-nitro-;AURORA KA-1883;O-BROMONITROBENZENE;Sucrose Impurity 10
- CBNumber:
- CB5379602
- Molecular Formula:
- C6H4BrNO2
- Molecular Weight:
- 202.01
- MDL Number:
- MFCD00007045
- MOL File:
- 577-19-5.mol
- MSDS File:
- SDS
- TDS File:
- TDS
Last updated:2026-06-04 16:00:12
| Melting point | 40-42 °C (lit.) |
|---|---|
| Boiling point | 261 °C (lit.) |
| Density | 1.7 g/cm3 (20℃) |
| refractive index | 1.6060 (estimate) |
| Flash point | >230 °F |
| storage temp. | 2-8°C |
| solubility | Chloroform (Slightly), Methanol (Slightly) |
| form | powder to crystal |
| color | Light yellow to Amber to Dark green |
| Water Solubility | insoluble |
| BRN | 2044109 |
| Stability | Stable. Combustible. Incompatible with strong bases, strong oxidizing agents. |
| InChI | 1S/C6H4BrNO2/c7-5-3-1-2-4-6(5)8(9)10/h1-4H |
| InChIKey | ORPVVAKYSXQCJI-UHFFFAOYSA-N |
| SMILES | [O-][N+](=O)c1ccccc1Br |
| CAS DataBase Reference | 577-19-5(CAS DataBase Reference) |
| FDA UNII | QP2NF456XV |
| NIST Chemistry Reference | Benzene, 1-bromo-2-nitro-(577-19-5) |
| EPA Substance Registry System | o-Bromonitrobenzene (577-19-5) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS06,GHS07,GHS08 |
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|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H301+H311+H331-H312-H331-H373-H302-H315-H319-H335 | |||||||||
| Precautionary statements | P261-P264-P270-P271-P280-P301+P310+P330-P302+P352+P312+P361+P364-P304+P340+P311-P305+P351+P338+P337+P313-P403+P233-P405-P501-P301+P312+P330-P305+P351+P338-P260-P304+P340-P501a | |||||||||
| target organs | Respiratory system | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Gloves | |||||||||
| Hazard Codes | Xn,Xi | |||||||||
| Risk Statements | 20/21/22-36/37/38-22 | |||||||||
| Safety Statements | 36/37-36/37/39-26-22 | |||||||||
| RIDADR | UN 3459 6.1/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | CY9040450 | |||||||||
| Hazard Note | Irritant | |||||||||
| TSCA | TSCA listed | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29049085 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Acute Tox. 4 Oral Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
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| Limited Quantities | 5.0 kg (11 lbs) (solid) | |||||||||
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L) | |||||||||
| NFPA 704 |
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1-Bromo-2-nitrobenzene price More Price(61)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 365424 | 1-Bromo-2-nitrobenzene 98% | 577-19-5 | 25g | $358 | 2026-04-30 | Buy |
| Sigma-Aldrich | 365424 | 1-Bromo-2-nitrobenzene 98% | 577-19-5 | 100g | $560 | 2026-04-30 | Buy |
| TCI Chemical | B0622 | 1-Bromo-2-nitrobenzene >99.0%(GC) | 577-19-5 | 25g | $72 | 2026-04-30 | Buy |
| TCI Chemical | B0622 | 1-Bromo-2-nitrobenzene >99.0%(GC) | 577-19-5 | 100g | $227 | 2026-04-30 | Buy |
| Usbiological | 266337 | 1-Bromo-2-nitrobenzene Asreported | 577-19-5 | 100g | $350 | 2026-06-03 | Buy |
1-Bromo-2-nitrobenzene Chemical Properties, Uses, Production
Chemical Properties
white to light yellow crystal powder
Uses
1-Bromo-2-nitrobenzene may be used in the preparation of:
- 4-methoxy-2′-nitrodiphenyl ether
- 1-methoxy-3,5-bis-(2-nitro-phenoxy)benzene
- 5-hydroxy-3-methoxy-2′-nitrodiphenyl ether
Uses
1-Bromo-2-nitrobenzene is used in organic synthesis. It also can react with 2-methylamino-benzoic acid to get N-methyl-N-(2-nitro-phenyl)-anthranilic acid. And it is also used in the preparation of 4-methoxy-2-nitrodiphenyl ether, 1-methoxy-3,5-bis-(2-nitro-phenoxy)benzene.
General Description
1-Bromo-2-nitrobenzene undergoes palladium[0]-mediated Ullmann cross-coupling reaction with a range of β-halo-enals, -enones or -esters to afford the corresponding β-aryl derivatives. Palladium[0]-mediated Ullmann cross-coupling reaction of 1-bromo-2-nitrobenzene with β-bromo-α,β-unsaturated aldehydes is reported.
Purification Methods
Crystallise it twice from pet ether, using charcoal before the first crystallisation. [Beilstein 5 III 618, 5 IV 728.]
1-Bromo-2-nitrobenzene Preparation Products And Raw materials
Raw materials
Preparation Products
1-(2-Nitrophenyl)piperidine
2-Aminodiphenylamine
2-Bromo-6-nitrophenol
5,11-dihydro-5-phenylindolo[3,2-b]carbazole
10-Bromo-7-phenyl-7H-benzo[c]carbazole
1of3
1-Bromo-2-nitrobenzene Suppliers
Global Suppliers ( 49)
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Hao Yun Chemical Science Co.,Ltd. | 021-68367562 | sales@haoyunchem.com | China | 493 | 55 |
| Shanghai Macklin Biochemical Co.,Ltd. | 15221275939 15221275939 | shenlinxing@macklin.cn | China | 15775 | 55 |
| Hangzhou J&H Chemical Co., Ltd. | 0571-87396432 | sales@jhechem.com | China | 14905 | 59 |
| Shanghai YuanYe Biotechnology Co., Ltd. | 15026964105 | 2881489226@qq.com | China | 89667 | 60 |
| Shanghai SuperLan Chemcial Technique Centre | 0-2022843681 15618226720 | chaolaichem@foxmail.com | China | 9996 | 58 |
| Shijiazhuang Yesheng Chemical Technology Co., Ltd | 18031147013 18031147013; | yeshengchemical@163.com | China | 2673 | 58 |
| Xi'an Kaixiang Photoelectric Technology Co., Ltd. | 18592059708 | sales@kxmaterials.com | China | 987 | 55 |
| Shanghai Jizhi Biochemical Technology Co. Ltd. | 021-4009004166/18616739031 18616739031 | 3007523370@qq.com | China | 40000 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | +86-29-81139210 +86-17392587031 | 1059@dideu.com | China | 9789 | 58 |
| CD Chemical Group Limited | +86-13651442114 | info@codchem.com | China | 17253 | 58 |
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2-BROMONITROBENZENE
2-Nitrobromobenzene
577-19-5
BrC6H4NO2
ARYL HALIDE
Nitro Compounds
Organic Building Blocks
Nitrogen Compounds
Building Blocks
Aromatic Hydrocarbons (substituted) & Derivatives
Benzene derivates
Miscellaneous
Bromine Compounds
Nitro Compounds
Nitro Compounds
Nitrogen Compounds
Organic Building Blocks
