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methyl-(naphthalen-2-ylmethyl)azanium

methyl-(naphthalen-2-ylmethyl)azanium Structure
methyl-(naphthalen-2-ylmethyl)azanium structure
CAS No.
76532-33-7
Chemical Name:
methyl-(naphthalen-2-ylmethyl)azanium
Synonyms
Terbinafine Impurity 13;N-methyl-1-(naphthalen-2-yl);Terbinafine Related Compound 2;Methyl-2-naphthaleneMethylaMine;N-Methylnaphthalene-2-methanamine;2-Naphthalenemethanamine, N-methyl-;N-Methyl(naphthalen-2-yl)MethanaMine;methyl-(naphthalen-2-ylmethyl)azanium;N-Methyl-1-(naphthalen-2-yl)MethanaMine
CBNumber:
CB61456631
Molecular Formula:
C12H13N
Molecular Weight:
171.24
MDL Number:
MFCD06366264
MOL File:
76532-33-7.mol
MSDS File:
SDS
Last updated:2025-07-24 18:13:51
Product description Number Pack Size Price
N-methyl-1-(naphthalen-2-yl)methanamine M105510 50mg $65
N-methyl-1-(naphthalen-2-yl)methanamine 1917AC 250mg $130
N-METHYL-N-(2-NAPHTHYLMETHYL)AMINE 95.00% CHM0031507 1G $808.89
N-METHYL-N-(2-NAPHTHYLMETHYL)AMINE 95.00% CHM0031507 2.5G $1147.43
N-METHYL-N-(2-NAPHTHYLMETHYL)AMINE 95.00% CHM0031507 5G $1421.65
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methyl-(naphthalen-2-ylmethyl)azanium Properties

Melting point 232-233 °C
Boiling point 90 °C(Press: 0.02 Torr)
Density 1.036±0.06 g/cm3(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
pka 9.50±0.10(Predicted)
Appearance Colorless to light yellow Liquid

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS07,GHS05
Signal word  Danger
Hazard statements  H318-H302-H335-H315
Precautionary statements  P280-P305+P351+P338-P310-P264-P270-P301+P312-P330-P501-P264-P280-P302+P352-P321-P332+P313-P362

methyl-(naphthalen-2-ylmethyl)azanium price More Price(10)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC M105510 N-methyl-1-(naphthalen-2-yl)methanamine 76532-33-7 50mg $65 2021-12-16 Buy
AK Scientific 1917AC N-methyl-1-(naphthalen-2-yl)methanamine 76532-33-7 250mg $130 2021-12-16 Buy
American Custom Chemicals Corporation CHM0031507 N-METHYL-N-(2-NAPHTHYLMETHYL)AMINE 95.00% 76532-33-7 1G $808.89 2021-12-16 Buy
American Custom Chemicals Corporation CHM0031507 N-METHYL-N-(2-NAPHTHYLMETHYL)AMINE 95.00% 76532-33-7 2.5G $1147.43 2021-12-16 Buy
American Custom Chemicals Corporation CHM0031507 N-METHYL-N-(2-NAPHTHYLMETHYL)AMINE 95.00% 76532-33-7 5G $1421.65 2021-12-16 Buy
Product number Packaging Price Buy
M105510 50mg $65 Buy
1917AC 250mg $130 Buy
CHM0031507 1G $808.89 Buy
CHM0031507 2.5G $1147.43 Buy
CHM0031507 5G $1421.65 Buy

methyl-(naphthalen-2-ylmethyl)azanium Chemical Properties,Uses,Production

Uses

An intermediate in the preparation of detoxification inhibitors of the crucifer phytoalexin Brassinin, as potential fungicides against Leptosphaeria maculans.

Synthesis

2-(Bromomethyl)naphthalene

939-26-4

methyl-(naphthalen-2-ylmethyl)azanium

76532-33-7

General procedure for the synthesis of N-methyl-2-naphthalenemethylamine from 2-bromomethylnaphthalene: 2-bromomethylnaphthalene (10 g, 43 mmol) was added batchwise to a stirred mixture of 40 wt% aqueous methylamine solution (50 mL, 581 mmol) and THF (50 mL) at 0 °C. The reaction mixture was gradually warmed to room temperature and stirred continuously for 16 hours. Upon completion of the reaction, the mixture was concentrated under vacuum. The concentrated residue was dissolved in ether (Et2O), washed sequentially with 1.0 N NaOH solution and brine, and the organic phase was dried over anhydrous sodium sulfate (Na2SO4) and concentrated to dryness. Purification by silica gel fast column chromatography (eluent ratio from 98:2 to 9:1 CHCl3/methanol containing 5% NH4OH) afforded N-methyl-2-naphthalenemethylamine (3.95 g, 54% yield) as a clear oil. Its 1H NMR (400 MHz, CDCl3) data were as follows: δ 7.85 (m, 3H), 7.79 (s, 1H), 7.49 (m, 3H), 3.94 (s, 2H), 2.53 (s, 3H).

References

[1] Patent: EP1226138, 2004, B1

methyl-(naphthalen-2-ylmethyl)azanium synthesis

939-26-4
76532-33-7
Synthesis of methyl-(naphthalen-2-ylmethyl)azanium from 2-(Bromomethyl)naphthalene

methyl-(naphthalen-2-ylmethyl)azanium Preparation Products And Raw materials

Raw materials

2-Quinolinecarboxaldehyde N-Methyl-2-naphthaMide 2-(CHLOROMETHYL)NAPHTHALENE Methylamine Diethyl ether
2-(Bromomethyl)naphthalene Tetrahydrofuran 2-Naphthaldehyde Chloroform Water

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Preparation Products

methyl-(naphthalen-2-ylmethyl)azanium Suppliers

Global( 91)Suppliers
Supplier Tel Email Country ProdList Advantage
Hubei Jusheng Technology Co.,Ltd. 		18871490254 linda@hubeijusheng.com CHINA 28172 58
career henan chemical co 		+86-0371-86658258 +8613203830695 factory@coreychem.com China 29799 58
Jinan Honest Pharm Co., Ltd 		+8615318812076 zpy8217@163.com China 286 58
Hubei Ipure Biology Co., Ltd 		+8613367258412 ada@ipurechemical.com China 10239 58
Dayang Chem (Hangzhou) Co.,Ltd. 		+86-0571-88938639 +8617705817739 info@dycnchem.com China 52846 58
Hefei TNJ Chemical Industry Co.,Ltd. 		+86-0551-65418684 +8618949823763 sales@tnjchem.com China 25356 58
Golden Pharma Co., Limited 		+undefined18958062155 sales@zjgoldpharm.com China 5899 58
Hangzhou MolCore BioPharmatech Co.,Ltd. 		+86-057181025280; +8617767106207 sales@molcore.com China 49734 58
HANGZHOU LEAP CHEM CO., LTD. 		+86-571-87711850 market18@leapchem.com China 43339 58
Sichuan Biosynce Pharmatech Co., Ltd. 		+8619950309693 diane@biosynce.com China 4871 58
Supplier Advantage
Hubei Jusheng Technology Co.,Ltd. 		58
career henan chemical co 		58
Jinan Honest Pharm Co., Ltd 		58
Hubei Ipure Biology Co., Ltd 		58
Dayang Chem (Hangzhou) Co.,Ltd. 		58
Hefei TNJ Chemical Industry Co.,Ltd. 		58
Golden Pharma Co., Limited 		58
Hangzhou MolCore BioPharmatech Co.,Ltd. 		58
HANGZHOU LEAP CHEM CO., LTD. 		58
Sichuan Biosynce Pharmatech Co., Ltd. 		58

View Lastest Price from methyl-(naphthalen-2-ylmethyl)azanium manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
methyl-(naphthalen-2-ylmethyl)azanium pictures 2019-12-25 methyl-(naphthalen-2-ylmethyl)azanium
76532-33-7
 US $0.10 / KG 1KG 95%-99% 1kg; 100kg; 1000kg Career Henan Chemical Co

methyl-(naphthalen-2-ylmethyl)azanium Spectrum

methyl-(naphthalen-2-ylmethyl)azanium(76532-33-7)1HNMR

76532-33-7(methyl-(naphthalen-2-ylmethyl)azanium)Related Search:

[2-(4-CHLORO-PHENYL)-ETHYL]-METHYL-AMINE N-(2-CHLOROBENZYL)-N-METHYLAMINE 1-CHLORO-6,6-DIMETHYL-2-HEPTEN-4-YNE (E)-1-Bromo-6,6-dimethyl-2-hepten-4-yne cis-Terbinafine Hydrochloride
N-[(2E)-6,6-DiMethyl-2-hepten-4-yn-1-yl]-N-Methyl-2-naphthaleneMethanaMine Hydrochloride Terbinafine (E)-N,6,6-triMethyl-N-(naphthalen-2-ylMethyl)hept-2-en-4-yn-1-aMine 1-Chloro-6,6-dimethyl-2-heptene-4-yne (Z)-N,6,6-triMethyl-N-(naphthalen-1-ylMethyl)hept-2-en-4-yn-1-aMine
1-Methyl-aminomethyl naphthalene N-Methyl-2-naphthaMide 3,3-Dimethyl-1-butyne 1-CHLORO-6,6-DIMETHYL-2-HEPTENE-4-YNE 6,6-Dimethyl-1-hepten-4-yn-3-ol
Terbinafine Hydrochloride Naphthol AS-E N-(2,3-Dihydro-2-oxo-1H-benzimidazol-5-yl)-3-hydroxy-2-naphthalenecarboxamide

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methyl-(naphthalen-2-ylmethyl)azanium Methyl-2-naphthaleneMethylaMine N-Methylnaphthalene-2-methanamine N-Methyl-1-(naphthalen-2-yl)MethanaMine N-Methyl(naphthalen-2-yl)MethanaMine Terbinafine Related Compound 2 N-methyl-1-(naphthalen-2-yl) 2-Naphthalenemethanamine, N-methyl- Terbinafine Impurity 13 76532-33-7 C12H14N Amines Aromatics